Size-controlled stabilization of the superionic phase to room temperature in polymer-coated AgInanoparticles

Nature Materials

Volumn 8, Issue 6, 2009, Pages 476-480

  Makiura, Rie ^a,b   Yonemura, Takayuki ^a   Yamada, Teppei ^a   Yamauchi, Miho ^a,e   Ikeda, Ryuichi ^a,b   Kitagawa, Hiroshi ^a,b,c,f   Kato, Kenichi ^c,d   Takata, Masaki ^c,d  

^a KYUSHU UNIVERSITY   (Japan)

^b JAPAN SCIENCE AND TECHNOLOGY AGENCY   (Japan)

^c RIKEN SPring 8 Center ^*  (Japan)

^d JAPAN SYNCHROTRON RADIATION RESEARCH INSTITUTE   (Japan)

^e HOKKAIDO UNIVERSITY   (Japan)

^f KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

IONIC CONDUCTION; IONIC CONDUCTIVITY; IONIC LIQUIDS; METAL IONS; NANOPARTICLES; ORE SINTER; SILVER HALIDES; SOLID-STATE SENSORS; SURFACE DEFECTS; SYNTHESIS (CHEMICAL);

CHARGE IMBALANCE; ELECTROCHEMICAL DEVICES; LOWER TEMPERATURES; N-VINYL-2-PYRROLIDONE; NANOPARTICLE SIZES; SOLID STATE IONICS; SUPERIONIC CONDUCTIVITY; THERMAL HYSTERESIS;

IONIC CONDUCTION IN SOLIDS;

EID: 66249098916     PISSN: 14761122     EISSN: 14764660     Source Type: Journal    
DOI: 10.1038/nmat2449     Document Type: Article

References (30)

1. Owens, B. B. Solid state electrolytes: Overview of materials and applications during the last third of the twentieth century. J. Power Sources 90, 2-8 (2000).
2. Arico, A. S., Bruce, P., Scrosati, B., Tarascon, J. M. & Schalkwijk, W. V. Nanostructured materials for advanced energy conversion and storage devices. Nature Mater. 4, 366-377 (2005).
3. Waser, R. & Aono, M. Nanoionics-based resistive switching memories. Nature Mater. 6, 833-840 (2007).
4. Guo, Y. G., Hu, J. S. & Wan, L. J. Nanostructured materials for electrochemical energy conversion and storage devices. Adv. Mater. 20, 2878-2887 (2008).
5. Rolison, D. R. et al. Multifunctional 3D nanoarchitectures for energy storage and conversion. Chem. Soc. Rev. 38, 226-252 (2009).
6. Hull, S. Superionics: Crystal structures and conduction processes. Rep. Prog. Phys. 67, 1233-1314 (2004).
7. Bradley, J. N. & Greene, P. D. Solids with high ionic conductivity in Group 1 halide systems. Trans. Faraday Soc. 63, 424-430 (1967).
8. Shahi, K. & Wagner, J. B. Jr. Fast ion transport in silver halide solid solutions and multiphase systems. Appl. Phys. Lett. 37, 757-759 (1980).
9. Noelting, J. & Bunsenges, B. Thermodynamic investigation of the silver and copper(I) halide systems. I. The AgI-CuI system. J. Phys. Chem. 68, 932-939 (1964).
10. 3-dispersed AgI. J. Electrochem. Soc. 128, 6-13 (1981).
11. 3 composite electrolytes. J. Electrochem. Soc. 147, 2407-2418 (2000).
12. Tatsumisago, M., Shinkuma, Y. & Minami, T. Stabilization of superionic α-AgI at room temperature in a glass matrix. Nature 354, 217-218 (1991).
13. Saito, T., Tatsumisago, M., Torata, N. & Minami, T. Stabilization process of α-AgI particles dispersed in glass matrices at room temperature. Solid State Ion. 19, 279-283 (1995).
14. Takagi, M. Electron-diffraction study of liquid-solid transition of thin metal films. J. Phys. Soc. Jpn 9, 359-363 (1954).
15. Blackman, M. & Sambles, J. R. Melting of very small particles during evaporation at constant temperature. Nature 226, 938-938 (1970).
16. Couchman, P. R. & Jesser, W. A. Thermodynamic theory of size dependence of melting temperature in metals. Nature 269, 481-483 (1977).
17. 3. J. Nanosci. Nanotechnol. 5, 431-435 (2005).
18. Hoshina, T., Kakemoto, H., Tsurumi, T., Wada, S. & Yashima, M. Size and temperature induced phase transition behaviors of barium titanate nanoparticles. Appl. Phys. Lett. 99, 054311 (2006).
19. Chernyshova, I. V., Hochella, M. F. Jr & Madden, A. S. Size-dependent structural transformations of hematite nanoparticles. 1. Phase transition. Phys. Chem. Chem. Phys. 9, 1736-1750 (2007).
20. Bandaranayake, R. J., Wen, G. W., Lin, J. Y., Jiang, H. X. & Sorensen, C. M. Structural phase behavior in II-VI semiconductor nanoparticles. Appl. Phys. Lett. 67, 831-833 (1995).
21. Guo, Y. G., Lee, J. S. & Maier, J. AgI nanoplates with mesoscopic superionic conductivity at room temperature. Adv. Mater. 17, 2815-2819 (2005).
22. Guo, Y. G., Lee, J. S., Hu, Y. S. & Maier, J. AgI nanoplates in unusual 7H/9R structures. Highly ionically conducting polytype heterostructures. J. Electrochem. Soc. 154, K51-K60 (2007).
23. Liang, C., Terabe, K., Hasegawa, T. & Aono, M. Anomalous phase transition and ionic conductivity of AgI nanowire grown using porous alumina template. J. Appl. Phys. 102, 124308 (2007).
24. Hanaya, M., Osawa, I. & Watanabe, K. XRD and thermal studies of AgI confined in nm-size pores by forming porous silica-AgI composites. J. Therm. Anal. Cal. 76, 529-536 (2004).
25. Baryshnikov, S. V. et al. Superionic phase transition in AgI embedded in molecular sieves. J. Phys. Condens. Matter 20, 025214 (2008).
26. 3) electrolyte. Solid State Ion. 80, 93-98 (1995).
27. Maier, J. Ionic conduction in space charge regions. Prog. Solid State Chem. 23, 171-263 (1995).
28. Agrawal, R. C. & Gupta, R. K. Superionic solid: Composite electrolyte phase - an overview. J. Mater. Sci. 34, 1131-1162 (1999).
29. 3 glasses, studied by Ag-109 NMR spectroscopy. J. Non-Cryst. Solids 324, 79-91 (2003).
30. Nishibori, E. et al. The large Debye-Scherrer camera installed at SPring-8 BL02B2 for charge density studies. Nucl. Instrum. Methods A 467-468, 1045-1048 (2001).