Aluminum speciation, vibrational entropy and short-range order in calcium aluminosilicate glasses

Geochimica et Cosmochimica Acta

Volumn 73, Issue 13, 2009, Pages 3894-3904

  Richet, Pascal ^a   Nidaira, Atsusi ^a   Neuville, Daniel R ^b   Atake, Tooru ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

^b INSTITUT DE PHYSIQUE DU GLOBE DE PARIS   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ALUMINOSILICATE; ALUMINUM; CALCIUM; ENTROPY; HEAT CAPACITY; OXYGEN; SPECIATION (CHEMISTRY); VIBRATION;

EID: 66149184425     PISSN: 00167037     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.gca.2009.03.041     Document Type: Article

References (31)

1. Bottinga Y., and Weill D.F. Densities of liquid silicate systems calculated from partial molar volumes of oxide components. Am. J. Sci. 269 (1970) 169-182
2. Bottinga Y., Weill D.F., and Richet P. Density calculations for silicate liquids. I Revised method for aluminosilicate compositions. Geochim. Cosmochim. Acta 46 (1983) 909-919
3. Buchenau U., Prager M., Nücker N., Dianoux A.J., Ahmad N., and Phillips W.A. Low-frequency modes in vitreous silica. Phys. Rev. B 34 (1986) 5665-5673
4. Dachs E., and Bertoldi C. Precision and accuracy of the heat-pulse calorimetric technique: low-temperature heat capacities of milligram-sized synthetic mineral samples. Eur. J. Mineral. 17 (2005) 251-259
5. de Ligny D., Westrum Jr. E. F. and Richet P. (1996-1997) Entropy of calcium and magnesium aluminosilicate glasses. Chem. Geol. 128, 113-128 & 140, 151.
6. Dubinsky E., and Stebbins J.F. Quench rate and temperature effects on framework ordering in aluminosilicate melts. Am. Mineral. 91 (2006) 753-761
7. 27Al magic angle spinning nuclear magnetic resonance. Phys. Chem. Glasses 26 (1985) 157-165
8. Flubacher P., Leadbetter A.J., Morrison J.A., and Stoicheff B.P. The low-temperature heat capacity and the Raman and Brillouin spectra of vitreous silica. J. Phys. Chem. Solids 12 (1959) 53-65
9. Hwang J.S., Lin K.J., and Tien C. Measurement of heat capacity by fitting the whole temperature response of a heat-pulse calorimeter. Rev. Sci. Instr. 68 (1997) 94-101
10. 27Al NMR study of structure and dynamics in a calcium aluminosilicate glass and melt. Geochim. Cosmochim. Acta 353 (2007) 4001-4010
11. Lacy E.D. Aluminium in glasses and melts. Phys. Chem. Glasses 4 (1963) 234-238
12. Lashley J.C., Hundley M.F., Migliori A., Sarrao J.L., Pagliuso P.G., Darling T.W., Jaime M., Cooley J.C., Hults W.L., Morales L., Thoma D.J., Smith J.L., Boerio-Goates J., Woodfield B.F., Stewart G.R., Fisher R.A., and Phillips N.E. Critical examination of heat capacity measurements made on a quantum design physical property measurement system. Cryogenics 43 (2003) 369-378
13. Mysen B.O., and Richet P. Silicate Glasses and Melts. Properties and Structure (2005), Elsevier, Amsterdam
14. 27Al MQ-MAS NMR, Raman, and XANES investigation. Geochim. Cosmochim. Acta 68 (2004) 5071-5079
15. Neuville D.R., Cormier L., Flanck A.-M., Briois V., and Massiot D. Al speciation and Ca environment in calcium aluminosilicate glasses and crystals by Al and Ca K-edge X-ray absorption spectroscopy. Chem. Geol. 213 (2004) 153-163
16. 27Al MQ-MAS NMR and Raman spectroscopy. Chem. Geol. 229 (2006) 173-185
17. Neuville D.R., Cormier L., Flank A.-M., de Ligny D., Roux J., and Lagarde P. Environment around Al, Si and Ca in aluminate and aluminosilicate melts by X-ray absorption spectroscopy at high temperature. Am. Mineral. 93 (2008) 228-234
18. Petkov V., Billinge S.J.L., Shastri S.D., and Himmel B. Polyhedral units and network connectivity in calcium aluminosilicate glasses from high-energy X-ray diffraction. Phys. Rev. Lett. 85 (2000) 3436-3439
19. Richet P. Viscosity and configurational entropy of silicate melts. Geochim. Cosmochim. Acta 48 (1984) 471-483
20. Richet P. Heat capacity of silicate glasses. Chem. Geol. 62 (1987) 111-124
21. 2: drop calorimetry measurements between 1000 and 1800 K and a review from 0 to 2000 K. Geochim. Cosmochim. Acta 46 (1982) 2639-2658
22. 6): a calorimetric test of the configurational entropy theory applied to the viscosity of liquid silicates. Geochim. Cosmochim. Acta 50 (1986) 1521-1533
23. 3 glass and liquid. Eur. J. Mineral. 3 (1991) 475-484
24. Richet P., Robie R.A., and Hemingway B.S. Entropy and structure of silicate glasses and melts. Geochim. Cosmochim. Acta 57 (1993) 2751-2766
25. Robie R.A., Hemingway B.S., and Wilson W.H. Low-temperature heat capacities and entropies of feldspar glasses and of anorthite. Am. Mineral. 63 (1978) 109-123
26. Robinson Jr. G.R., and Haas Jr. J.L. Heat capacity, relative enthalpy, and calorimetric entropy of silicate minerals: an empirical method of prediction. Am. Mineral. 68 (1983) 541-553
27. Stebbins J.F. Temperature effects on the network structure of oxide melts and their consequences for configurational heat capacity. Chem. Geol. 256 (2008) 80-91
28. Stebbins J.F., and Farnan I. Effects of high temperature on silicate liquid structure: a multinuclear NMR study. Science 255 (1992) 586-589
29. 27Al NMR spectroscopy. J. Non-Cryst. Solids 275 (2000) 1-6
30. Stebbins J.F., Dubinsky E.V., Kanehashi K., and Kelsey K.E. Temperature effects on non-bridging oxygen and aluminum coordination number in calcium aluminosilicate glasses and melts. Geochim. Cosmochim. Acta 72 (2008) 910-925
31. ième Congr. Int. Verre, Paris 39 (1956) 396-399