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1
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While other useful aminohydroxylation reactions based on metals such as copper and palladium have emerged, it is fair to say that none can match the stereospecificity and functional group tolerance offered by osmium
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Kolb, H. C.; Sharpless, K. B. Transition Met. Org. Synth. 1998, 2, 243. While other useful aminohydroxylation reactions based on metals such as copper and palladium have emerged, it is fair to say that none can match the stereospecificity and functional group tolerance offered by osmium.
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Li, G.1
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Bruncko, M.; Schlingloff, G.; Sharpless, K. B. Angew. Chem., Int. Ed. 1997, 36, 1483.
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Bruncko, M.1
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Demko, Z. P.; Bartsch, M.; Sharpless, K. B. Org. Lett. 2000, 2, 2221.
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0037032268
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Donohoe, T. J.; Johnson, P. D.; Cowley, A.; Keenan, M. J. Am. Chem. Soc. 2002, 124, 12934.
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Donohoe, T. J.; Johnson, P. D.; Pye, R. J. Org. Biomol. Chem. 2003, 1, 2025.
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4043171449
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14
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34248375267
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15
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26844569944
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Lebel, H.1
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17
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66149163004
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The TA reaction to form 7- and 8-membered lactam rings was unsuccessful.
-
The TA reaction to form 7- and 8-membered lactam rings was unsuccessful.
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-
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18
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66149186775
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The stereochemistry of 8-10, 12, 13, 17, 20, 28, 30, 32, and 35 was determined by X-ray analysis and of 15, 25, and 34 by analogy. The stereochemistry of 22 and 23 was assigned by NMR experiments.
-
The stereochemistry of 8-10, 12, 13, 17, 20, 28, 30, 32, and 35 was determined by X-ray analysis and of 15, 25, and 34 by analogy. The stereochemistry of 22 and 23 was assigned by NMR experiments.
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21
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33746398522
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See, for example, the epiclausinamides
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See, for example, the epiclausinamides: Wu, Y.; Liu, L.; Wei, H.; Liu, G. Acta Pharmacol. Sin 2006, 27, 1024.
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37049141038
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Griffith, W. P.; Pawson, D. J. Chem. Soc., Dalton Trans. 1973, 12, 1315.
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J. Chem. Soc., Dalton Trans
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Griffith, W.P.1
Pawson, D.2
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23
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17444401788
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For example
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For example: Donohoe, T. J.; Johnson, P. D.; Pye, R. J.; Keenan, M. Org. Lett. 2005, 7, 1275-1277.
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Donohoe, T.J.1
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Pye, R.J.3
Keenan, M.4
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24
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4143087960
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Kenworthy, M. N.; McAllister, G. D.; Taylor, R. J. K. Tetrahedron Lett. 2004, 45, 6661-6664.
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Kenworthy, M.N.1
McAllister, G.D.2
Taylor, R.J.K.3
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