In situ synthesis and crystal growth of copper(I) carbonyl trifluoroacetate: A dinuclear [Cu2(O2CCF3) 2(CO)2] core structure confirmed

Zeitschrift fur Kristallographie

Volumn 224, Issue 4, 2009, Pages 229-232

  Sevryugina, Yulia ^a   Petrukhina, Marina A ^a  

^a STATE UNIVERSITY OF NEW YORK   (United States)

Author keywords

Copper(I) carbonyl trifluoroacetate; Photoluminescence; Single crystal structure analysis; X ray diffraction

Indexed keywords

EID: 65949115514     PISSN: 00442968     EISSN: None     Source Type: Journal    
DOI: 10.1524/zkri.2009.1136     Document Type: Article

References (25)

1. 2 under atmospheric pressure. Catalysis Today 36 (1997) 91-97; (Pubitemid 127381353)
2. Du, J.; Okada, K.; Nomura, M.; Fujii, Y.: Carbon isotope effects in Cu(I)-CO complex systems. Phys. Chem. Chem. Phys. 2 (2000) 3181-3185;
3. +/CO system. Chem. Phys. Letters 390 (2004) 71-78;
4. 4 (M = Al and Ga) upon small-molecule binding and the competitive binding of CO and ethylene. J. Am. Chem. Soc. 128 (2006) 13463-13473.
5. Gagne, R. R.; Kreh, R. P.; Dodge, J.: The synthesis, electro-chemistry, and reactivity of binuclear copper(I) complexes as mimics of protein active sites. Adv. Chem. Ser. 201 (1982) 139-157;
6. Lee, Y.; Karlin, K. D.: Model complexes for copper-containing enzymes. In: Concepts and Models in Bioinorganic Chemistry (Eds. N. Metzler-Nolte, H.-B. Kraatz), p. 363-395. Wiley-VCH: New York 2006.
7. Fry, H. C.; Lucas, H. R.; Sarjeant, A. A. N.; Karlin, K. D.; Meyer, G. J.: Carbon monoxide coordination and reversible photodissociation in copper(I) pyridylalkylamine compounds. Inorg. Chem. 47 (2008) 241-256.
8. Rodesiler, P. F.; Amma, E. L.: Nature of the solution species of adducts of tetra-μ-trifluoroacetate copper(I). J. Inor. Nucl. Chem. 39 (1977) 1227-1229;
9. Scott, A. F.; Wilkening, L. L.; Rubin, B.: The preparation of copper(I) trifluoroacetate carbonyl. Inorg. Chem. 8 (1969) 2533-2534.
10. 2. Inorg. Chem. 39 (2000) 1735-1742.
11. 2, X = F, Cl or Br, and copper in the presence of carbon monoxide. J. Chem. Soc., Dalton Trans. (2000) 2067-2075;
12. Calderazzo, F.; Donati, N.; Englert, U.; Marchetti, F.; Pampaloni, G.; Passarelli, V.: Synthesis, reactivity and structures of mono and dihaloacetato complexes of copper(I) and copper(II). Inorg. Chim. Acta 346 (2003) 100-110.
13. Drew, M. G. B.; Edwards, D. A.; Richards, R.: Crystal and molecular structure of tetrakis [copper(I) benzoate]. J. Chem. Soc., Dalton Trans. (1977) 299-303.
14. Rodesiler, P. F.; Amma, E. L.: Preparation and X-ray molecular structure of an unusual copper(I) polynuclear species. Tetra-kis(copper(I) trifluoroacetate)dibenzene. J. Chem. Soc., Chem. Commun. (1974) 599-600.
15. Cotton, F. A.; Dikarev, E. V.; Petrukhina, M. A.: Syntheses and crystal structures of "unligated" copper(I) and copper(II) trifluoroacetates. Inorg. Chem. 39 (2000) 6072-6079.
16. Bruker: SATNT, Version 6.02, Integration Software; Bruker AXS, Madison, WI, USA (2001).
17. Bruker: SADABS, Program for Empirical Absorption Correction of Area Detector Data; Bruker AXS, Madison, WI, USA (1999).
18. Bruker: SHELXTL. Version 6.10, Program suite for solution and refinement of crystal structures; Bruker AXS, Madison, WI, USA (2001).
19. Cotton, F. A.; Dikarev, E. V.; Petrukhina, M. A.: cis-Di(μ- trifluoroacetate)dirhodium tetracarbonyl structure and chemistry. J. Chem. Soc., Dalton Trans. (2000) 4241-4243.
20. Drew, M. G. B.; Edwards, D. A.; Richards, R.: X-ray crystal structure of copper(I) acetate. J. Chem. Soc., Chem. Comm. (1973) 124-125;
21. Ogura, T.; Mounts, R. D.; Fernando, Q.: Structure of a planar four-coordinate complex of copper(I). J. Am. Chem. Soc. 95 (1973) 949-951;
22. Mounts, R. D.; Ogura, T.; Fernando, Q.: Crystal structure of copper(I) acetate. Inorg. Chem. 13 (1974) 802-805.
23. Sevryugina, Y.; Vaughn II, D. D.; Petrukhina, M. A.: X-ray structure and photoluminescence of copper(I) 2,6-bis(trifluoromethyl)benzoate. Inorg. Chim. Acta 360 (2007) 3103-3107.
24. Sevryugina, Y.; Hietsoi, O.; Petrukhina, M. A.; Tetranuclear copper(I) clusters: Impact of bridging carboxylate ligands on solid state structure and photoluminescence. Chem. Commun. 37 (2007) 3853-3855;
25. n fragments (n = 6, 4, 2). Eur. J. Inorg. Chem. 2 (2008) 191-195.