Characterization of chemical kinetics in membrane-based liquid-liquid extraction of molybdenum(VI) from aqueous solutions

Chemical Engineering Journal

Volumn 151, Issue 1-3, 2009, Pages 333-341

  Valdes H ^a   Romero, J ^a   Sanchez, J ^b   Bocquet, S ^b   Rios, G M ^b   Valenzuela, F ^c  

^a UNIVERSIDAD DE SANTIAGO DE CHILE   (Chile)

^b UNIVERSITÉ DE MONTPELLIER   (France)

^c UNIVERSITY OF CHILE   (Chile)

Author keywords

Liquid liquid extraction; Mass transfer; Membrane contactor; Modelling; Molybdenum

Indexed keywords

ALAMINE 336; AQUEOUS SOLUTIONS; AS EXTRACTION; CHEMICAL KINETICS; COMPLEX FORMATIONS; EXPERIMENTAL DATA; EXTRACTION PROCESS; EXTRACTION SYSTEMS; HOLLOW FIBER CONTACTORS; LIQUID-LIQUID EXTRACTION; MEMBRANE CONTACTOR; MEMBRANE-BASED SOLVENT EXTRACTION; MICROPOROUS; MINE WATERS; MODELLING; N-HEXANE; RATE EXPRESSION; SCALE-UP; SEPARATION SCIENCE; SERIES MODEL; THERMODYNAMIC RELATIONSHIPS;

GROUNDWATER; HEXANE; LIQUIDS; MASS TRANSFER; MEMBRANES; MINING; MOLYBDENUM; MOLYBDENUM COMPOUNDS; REACTION RATES; SOLUTIONS; SOLVENT EXTRACTION; SOLVENTS;

PHASE INTERFACES;

VALENZUELA;

EID: 65749119996     PISSN: 13858947     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cej.2009.04.012     Document Type: Article

References (54)

1. 2+ and molybdenum(VI) from mine waters using two microporous extraction systems. Separation Science and Technology 35 (2000) 1409-1421
2. Mudre J.M., and Ney J.J. Patterns of accumulation of heavy metals in the sediment of roadside streams. Journal Archives of Environmental Contamination and Toxicology 15 (1986) 489-493
3. Sreeram K., Srinivasan R., Devi J., Nair B., and Ramasami T. Cerium molybdenum oxides for environmentally benign pigments. Dyes and Pigments 75 (2007) 687-692
4. Al-Kandari H., Al-Kharafi F., and Katrib A. Catalytic activity-surface structure correlation of molybdenum-based catalysts. Journal of Molecular Catalysis A: Chemical 287 (2008) 128-134
5. Mitchell P.C.H. The chemistry and uses of molybdenum: introductory lecture. Journal of the Less Common Metals 36 (1974) 3-11
6. Saberyan K., Maragheh M.G., Ashtari P., and Alamdari S.K. Liquid-liquid extraction of molybdenum(VI) from acidic media with Cyanex-301. Minerals Engineering 16 (2003) 391-393
7. Sastre A.M., and Alguacil F.J. Co-extraction and selective stripping of copper(II) and molybdenum(VI) using LIX 622. Chemical Engineering Journal 81 (2001) 109-112
8. Palant A.A., Iatsenko N.A., and Petrova V.A. Solvent extraction of molybdenum(VI) by diisododecylamine from sulphuric acid solution. Hydrometallurgy 48 (1998) 83-90
9. Vartak S.V., and Shinde V.M. Separation studies of molybdenum(VI) and rhenium(VII) using TPPO as an extractant. Talanta 43 (1996) 1465-1470
10. Juneja J., Singh S., and Bose D. Investigations on the extraction of molybdenum and rhenium values from low grade molybdenite concentrate. Hydrometallurgy 41 (1996) 201-209
11. Zhang P., Inoue K., Yoshizuka K., and Tsuyama H. Extraction and selective stripping of molybdenum(VI) and vanadium(IV) from sulfuric acid solution containing aluminum(III), cobalt(II), nickel(II) and iron(III) by LIX 63 in Exxsol D80. Hydrometallurgy 41 (1996) 45-53
12. Cruywagen J.J., and Draaijer A.G. Solvent extraction investigation of molybdenum(VI) equilibria. Polyhedron 11 (1992) 141-146
13. Sato T., Watanabe H., and Suzuki H. Liquid-liquid extraction of molybdenum(VI) from aqueous acid solutions by TBP and TOPO. Hydrometallurgy 23 (1990) 297-308
14. Coca J., Díez F.V., and Morís M.A. Solvent extraction of molybdenum and tungsten by Alamine 336 and DEHPA. Hydrometallurgy 25 (1990) 125-135
15. Murata K., Yamashita S., Yamamoto E., and Ikeda S. Extraction of molybdenum(VI) from aqueous solution by donor solvents. Polyhedron 9 (1990) 1717-1721
16. Basu R., and Sirkar K.K. Non-dispersive membrane solvent back extraction of phenol. AIChE Journal 36 (1990) 450-460
17. Basu R., and Sirkar K.K. Citric acid extraction with microporous hollow fibers. Solvent Extraction and Ion Exchange 10 (1992) 119-143
18. Basu R., and Sirkar K.K. Pharmaceutical product recovery using a hollow fiber contained liquid membrane: a case study. Journal Membrane Science 75 (1992) 131-149
19. 2+ from dilute feed. Hydrometallurgy 55 (2000) 113-116
20. Yang Ch.E., and Cussler L. Reaction dependent extraction of copper and nickel using hollow fibers. Journal of Membrane Science 166 (2000) 229-238
21. Juang R.-S., and Huang H.-L. Mechanistic analysis of solvent extraction of heavy metals in membrane contactors. Journal of Membrane Science 213 (2003) 125-135
22. ® 84-I. Journal of Membrane Science 268 (2006) 142-149
23. Wang Y., Luo G., Cai W., Wang Y., and Dai Y. Membrane extraction for sulfanilic acid removal from wastewater. Separation Science and Technology 37 (2002) 1163-1177
24. Kubišová L., Sabolová E., Schlosser S., Marták J., and Kertész R. Mass-transfer in membrane based solvent extraction and stripping of 5-methyl-2 pyrazinecarboxylic acid and co-transport of sulphuric acid in HF contactors. Desalination 163 (2004) 27-38
25. Souchon I., Athès V., Pierre F.-X., and Marin M. Liquid-liquid extraction and air stripping in membrane contactor: application to aroma compounds recovery. Desalination 163 (2004) 39-46
26. Vajda M., Kosuthova A., and Schlosser S. Membrane-based solvent extraction and stripping of zinc in a hollow-fibre contactor operating in a circulating mode. Desalination 163 (2004) 19-25
27. Bocquet S., Gascon F., Muvdi C., Sanchez J., Athes V., and Souchon I. Membrane-based solvent extraction of aroma compounds: choice of configuration of hollow fiber modules based on experiments and simulation. Journal of Membrane Science 281 (2006) 358-368
28. S. Kimura, S. Sourirajan, Mass transfer coefficients for use in reverse osmosis process design, National Research Council of Canada Ottawa (Ontario) Division of Applied Chemistry, 7 (October (4)), 1968.
29. Urtiaga A., Abellán M.J., Irabien J.A., and Ortiz I. Membrane contactors for the recovery of metallic compounds modelling of copper recovery from WPO processes. Journal of Membrane Science 257 (2005) 161-170
30. Yun C.H., Prasad R., Guha A.K., and Sirkar K.K. Hollow fiber solvent extraction removal of toxic heavy metals from aqueous waste streams. Industrial and Engineering Chemistry 32 (1993) 1186-1195
31. Yang Z.-F., Guha A.K., and Sirkar K.K. Novel membrane-based synergistic metal extraction and recovery processes. Industrial and Engineering Chemistry 35 (1996) 1383-1394
32. Valenzuela F., Fonseca C., Basualto C., Correa O., Tapia C., and Sapag J. Removal of copper ions from a waste mine water by a liquid emulsion membrane method. Minerals Engineering 18 (2005) 33-40
33. Campderrós M.E., Acosta A., and Marchese J. Selective separation of copper with LIX 864 in a hollow fiber module. Talanta 47 (1998) 19-24
34. Juang R.S., and Chen L.J. Analysis of the transport rates of citric-acid through a supported liquid membrane containing tri-N-octylamine. Industrial & Engineering Chemistry Research 35 (1996) 1673
35. Juang R.S., and Jiang J.D. Rate-controlling mechanism of cobalt transport through supported liquid membranes containing di(2-ethylhexyl)phosphoric acid. Separation Science and Technology 29 (1994) 223
36. Juang R.S., and Huang I.P. Hollow-fiber membrane extraction of copper(II) from aqueous ethylenediaminetetraacetic acid-solutions with Aliquat-336. Industrial & Engineering Chemistry Research 39 (2000) 1409
37. Juang R.S., and Huang I.P. Liquid-liquid extraction of copper(II)-EDTA chelated anions with microporous hollow fibers. Journal of Chemical Technology and Biotechnology 75 (2000) 610
38. Schlosser S., Kertesz R., and Martak J. Recovery and separation of organic acids by membrane-based solvent extraction and pertraction-an overview with a case study on recovery of MPCA. Separation and Purification Technology 41 (2005) 237
39. Schlosser S., Sabolova E., Kertesz R., and Kubisova L. Factors influencing transport through liquid membranes and membrane based solvent extraction. Journal of Separation Science 24 (2001) 509
40. Kulkarni P.S., and Mahajani V.V. Application of liquid emulsion membrane (LEM) process for enrichment of molybdenum from aqueous solutions. Journal of Membrane Science 201 (2002) 123-135
41. Marchese J., Valenzuela F., Basualto C., and Acosta A. Transport of molybdenum with Alamine 336 using supported liquid membrane. Hydrometallurgy 72 (2004) 309-317
42. Basualto C., Marchese J., Valenzuela F., and Acosta A. Extraction of molybdenum by a supported liquid membrane method. Talanta 59 (2003) 999-1007
43. Valenzuela F., Pizarro F., Basualto C., Sapag J., and Tapia C. Extracción de molybdenum(VI) con aminas terciarias en un reactor de membranes liquidas de soporte sólido. Boletín de la Sociedad Chilena de Química 46 Junio (2) (2001)
44. Valenzuela F., Andrade J., Sapag J., Tapia C., and Basualto C. The solvent extraction separation of molybdenum and copper from acid leach residual solution of chilean molybdenite concentrate. Minerals Engineering 8 (1995) 893-904
45. Gabelman A., and Hwang S.-T. Hollow fiber membrane contactors. Journal of Membrane Science 159 (1999) 61-106
46. Kathios D.J., Jarvinen G.D., Yarbro S.L., and Smith B.F. A preliminary evaluation of microporous hollow fiber membrane modules for the liquid-liquid extraction of actinides. Journal of Membrane Science 97 (1994) 251-261
47. Yang M.-C., and Cussler E.L. Designing hollow-fiber contactor. AIChE Journal 32 (1986) 1910-1916
48. Prasad R., Khare S., Sengupta A., and Sirkar K.K. Novel liquid in-pore configurations in membrane solvent extraction. AIChE Journal 36 (1990) 1592-1596
49. Lee H.Y., Kim S.G., and Oh J.K. Development of kineticsequations for the extraction of copper by LIX65N based on interfacial reaction mechanism. Hydrometallurgy 34 (1994) 293-305
50. Irabien A., Ortiz I., and Pérez E. Kinetics of metal extraction: model discrimination and parameter estimation. Chemical Engineering and Processing 27 (1990) 13-18
51. Sieder E.N., and Tate G.E. Heat transfer and pressure drop of liquids in tubes. Industrial and Engineering Chemistry 28 (1936) 1429
52. Bird R., Stewart W., and Lightfoot E. Transport Phenomena. 2nd edition (2002), John Wiley & Sons Inc., USA
53. Viegas R., Rodríguez M., Luque S., Alvarez J., Coelhoso I., and Crespo J. Mass transfer correlations in membrane extraction: analysis of Wilson-plot methodology. Journal of Membrane Science 145 (1998) 129-142
54. Kendall J., and Monroe K. Journal of the American Chemical Society 39 (1917)