A mechanistic model of uniform hydrogen sulfide/ carbon dioxide corrosion of mild steel

Corrosion

Volumn 65, Issue 5, 2009, Pages 291-307

  Sun, W ^a,b   Nesic S ^a  

^a OHIO UNIVERSITY   (United States)

^b EXXONMOBIL UPSTREAM RESEARCH COMPANY   (United States)

Author keywords

Corrosion; Hydrogen sulfide corrosion; Kinetics; Mackinawite; Mechanism; Mechanistic model; Solid State reaction

Indexed keywords

CARBON DIOXIDE CORROSION; DAMAGE RATE; HYDRODYNAMIC EFFECT; HYDROGEN SULFIDE CORROSION; IRON SULFIDE; LAYER FORMATION; MACKINAWITE; MECHANISTIC MODEL; MECHANISTIC MODELS; MILD STEEL; MODEL PREDICTION; RATE OF CORROSIONS; SOLID-STATE REACTION; STEEL SURFACE; SURFACE LAYERS;

CARBON DIOXIDE; FLUID DYNAMICS; HYDROGEN; HYDROGEN SULFIDE; IRON; MECHANISMS; PRECIPITATION (CHEMICAL); REACTION KINETICS; STEEL; SULFUR DETERMINATION;

CORROSION RATE;

EID: 65549119379     PISSN: 00109312     EISSN: None     Source Type: Journal    
DOI: 10.5006/1.3319134     Document Type: Article

References (37)

1. D.W. Shoesmith, P. Taylor, M.G. Bailey, D.G. Owen, J. Electro- chem Soc. 125 (1980): p. 1,007-1,015.
2. D.W. Shoesmith, "Formation, Transformation, and Dissolution of Phases Formed on Surfaces," Lash Miller Award Address, Elec- trochemical Society Meeting, held Nov. 27 (Ottawa, 1981).
3. S.N. Smith, "A Proposed Mechanism for Corrosion in Slightly Sour Oil and Gas Production," 12th Int. Corros. Cong., paper no. 385, held September 19-24 (Houston, TX, 1993).
4. 2S Levels Re- quired for Slightly Sour Corrosion," CORROSION/94, paper no. 11 (Houston, TX: NACE International, 1994).
5. S.N. Smith, J.L. Pacheco, "Prediction of Corrosion in Slightly Sour Environments," CORROSION/2002, paper no. 02241 (Houston, TX: NACE, 2002).
6. 2-Containing Oilfield Environments," CORROSION/2006, paper no. 06115 (Houston, TX: NACE, 2006).
7. 2S: Using Past Operations for Designing Future Fa- cilities," CORROSION/2006, paper no. 06122 (Houston, TX: NACE, 2006).
8. W. Sun, S. Nesić, Corrosion 64, 4 (2008): p. 334.
9. W. Sun, S. Nešic, S. Papavinasam, Corrosion 64, 7 (2008): p. 586.
10. 2S" (Ph.D. diss., Ohio University, 2004).
11. F.H. Meyer, O.L. Riggs, R.L. McGlasson, J.D. Sudbury, Corrosion 14 (1958): p. 109.
12. L.G. Benning, R.T. Wilkin, H.L. Barnes, Chem. Geol 167 (2000): p. 25.
13. A. Anderko, P.J. Shuler, Comput. Geosci 23 (1997): p. 647.
14. A. Anderko, P.J. Shuler, "Modeling the Formation of Iron Sulfide Layers Using Thermodynamic Simulation," CORROSION/98, paper no. 64 (Houston, TX: NACE, 1998).
15. 2S Corrosion Using Thermodynamic and Electrochemical Models," CORROSION/99, paper no. 31 (Houston, TX: NACE, 1999).
16. 3/FeS Layer Formation Using Thermodynamic and Electrochemical Models," CORROSION/ 2000, paper no. 102 (Houston, TX: NACE, 2000).
17. P. Taylor, Am. Mineral 65 (1980): p. 1,026-1,030.
18. P. Marcus, E. Protopopoff, J. Electrochem. Soc. 137 (1990): p. 2,709.
19. J.S. Smith, J.D.A. Miller, Br. Corros. J. 10 (1975): p. 136-143.
20. 2S Corrosion," CORROSION/2006, paper no. 06644 (Houston, TX: NACE, 2006).
21. 2S Corrosion," CORROSION/2004, paper no. 04728 (Houston, TX: NACE, 2004).
22. S. Nešić, J. Postlethwaite, S. Olsen. Corrosion 52 (1996): p. 280-294.
23. M. Nordsveen, S. Nešić, R. Nyborg, A. Stangeland, Corros. Sci. 59 (2003): p. 443-457.
24. S. Nešić, K.-L.J. Lee, Corros. Sci. 59 (2003): p. 616-628.
25. M. Schulte, M. Schutz, Oxid. Met. 51 (1999): p. 55-77.
26. A. Dravnieks, C.H. Samans, J. Electrochem. Soc. 105 (1958): p. 183-191.
27. D-N. Tsipas, H. Noguera, J. Rus, Mater. Chem. Phys. 18 (1987): p. 295-303.
28. 2S," CORROSION/2004, paper no. 04736 (Houston, TX: NACE, 2004).
29. M. Schutze, Protective Oxide Layers and Their Breakdown (Chich- ester, U.K.: John Wiley and Sons, 1997).
30. 2 Corrosion in Multiphase Flow," Ohio University Advisory Board Meeting Report, internal report, 2006.
31. S. Nešić, B.F.M. Pots, J. Postlethwaite, N. Thevenot, J. Corros. Sci. Eng. (1995), ISSN 1466-8858.
32. 3 Saturation at High Temperatures and Pressures in Brine Solutions," SPE of AIME (Richardson, TX: Society of Petroleum Engineers, 1982), p. 1,583-1,590.
33. 2S Corrosion" (Ph.D. diss., Ohio University, 2006).
34. 2S, and Acetic Acid on Bottom-of-the-Line Corrosion," CORROSION/2007, paper no. 07661 (Houston, TX: NACE, 2007).
35. 2S Corrosion of Carbon Steel," CORROSION/2003, paper no. 03339 (Houston, TX: NACE, 2003).
36. 2," CORROSION/96, paper no. 26 (Houston, TX: NACE, 1996).
37. 2S Corro- sion of Carbon Steel Under Simulated Kashagan Field Condi- tions," CORROSION/2005, paper no. 05300 (Houston, TX: NACE, 2005).