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Zeitschrift fur Anorganische und Allgemeine Chemie
Volumn 635, Issue 4-5, 2009, Pages 614-617
Synthesis and crystal structure of CaCo(H2O)[BP 2O8(OH)] · H2O
Author keywords

Borophosphate; Calcium; Cobalt; Hydrothermal growth; Layered structure
Indexed keywords

EID: 65449151907     PISSN: 00442313     EISSN: 15213749     Source Type: Journal    
DOI: 10.1002/zaac.200801376     Document Type: Article
Times cited : (9)
References (25)
  • 7
    • 65449180515 scopus 로고    scopus 로고
    • Schnelle and R. Kniep
    • in preparation
    • P. W, Menezes, S. Hoffmann, Yu. Prots, W, Schnelle and R. Kniep, (in preparation).
    • W, P.1    Menezes, S.2    Yu, H.3    Prots, W.4
  • 17
    • 65449190358 scopus 로고    scopus 로고
    • A suitable (pink platelet) single crystal of CaCo(H2O, BP2O8(OH, · H2O with the dimensions 0.030 × 0.130 × 0.130 mm3 was selected for single-crystal XRD analysis. The data (6602 measured reflections) with index ranges of -6 ≤ h ≤ 9, 10 ≤ k ≤ 10, 12 ≤ l ≤ 12 and 5° ≤ 20 ≤ 60° were collected on a Rigaku AFC7 (Mercury CCD) diffractometer equipped with graphite, monochromated Mo-K α radiation (λ, 0.71073 Å) at a temperature of 295 K. The crystal structure was solved in the space group P1̄ with the program SHELXS-97 by direct methods [G. M. Sheldrick, SHELXS-97, A program for automatic solution of crystal structures, University of Gottingen, Germany, 1997] and refined with the program SHELXL-97 [G. M. Sheldrick, SHELXL, 97, A program for crystal structure refinement, University of
    • α radiation (λ = 0.71073 Å) at a temperature of 295 K. The crystal structure was solved in the space group P1̄ with the program SHELXS-97 by direct methods [G. M. Sheldrick, SHELXS-97 - A program for automatic solution of crystal structures, University of Gottingen, Germany, 1997] and refined with the program SHELXL-97 [G. M. Sheldrick, SHELXL - 97 - A program for crystal structure refinement, University of Göttingen, Germany, 1997] ncluded in the program package WinGX [L. J. Farrugia, J. Appl. Cryst. 1999, 32, 837]. Subsequent difference Fourier analysis unequivocally located the atomic coordinates of all of the atoms. The H atoms were also located in Fourier difference maps and the O - H distances for water molecule were constrained to vary around 0.80(5) Å during the final refinement. The refinement of the atomic coordinates and anisotropic thermal parameters led to the reliability factors RI = 0.043 and wR2 = 0.107 considering 2261 independent reflections.

* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.