Catalytic oxidation of calcium bisulfite in the wet limestone-gypsum flue gas desulfurization process

Chemical Engineering Science

Volumn 54, Issue 15-16, 1999, Pages 3019-3026

  Lancia, Amedeo ^a   Musmarra, Dino ^b   Prisciandaro, Marina ^c   Tammaro, Marco ^a  

^a UNIVERSITY OF NAPLES FEDERICO II   (Italy)

^b CNR   (Italy)

^c UNIVERSITY OF L'AQUILA   (Italy)

Author keywords

Calcium bisulfite; Desulfurization; Flue gas; Manganous sulfate; Oxidation; Reaction regimes

Indexed keywords

CALCIUM BISULFITE; CATALYTIC OXIDATION; MANGANOUS SULFATE;

CALCIUM COMPOUNDS; CATALYSIS; CHEMICAL REACTORS; FLUE GASES; GYPSUM; LIMESTONE; OXIDATION; PARTIAL PRESSURE; PHASE COMPOSITION; SOLUTIONS; SULFUR COMPOUNDS; TEMPERATURE;

DESULFURIZATION;

CATALYST; FLUE GAS; OXIDATION; REMOVAL; SULFUR COMPOUND;

EID: 6544243905     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0009-2509(98)00483-7     Document Type: Article

References (26)

1. Astarita, G. (1967). Mass Transfer with Chemical Reaction. Amsterdam: Elsevier.
2. Astarita, G., Sawage, D.W., & Bisio, A. (1983). Gas Treating with Chemical Solvents. New York: Wiley Interscience.
3. Bäckstrom, H.L.J. (1927). The chain-reaction theory of negative analysis. J. Amer. Chem. Soc., 49, 1460-1472.
4. Barron, C.H., & O'Hern, H.A. (1966). Reaction kinetics of the sodium sulfite oxidation by the rapid-mixing method. Chem. Engng Sci., 21, 397-404.
5. 2. Can. J. Chem. Engng, 74, 104-109.
6. Brewer, L. (1982). Thermodynamic values for desulphurization processes. In J.L. Hudson, G.T. Rochelle (Eds.), Flue Gas Desulfurization. ACS Symposium Series, Vol. 188, pp. 1-39.
7. Danckwerts, P.V. (1970). Gas-liquid Reactions. New York: McGraw-Hill.
8. Delplanq, E., Casti, P., & Vanderschuren, J. (1992). Kinetics of the oxidation of calcium sulphite slurries in areated stirred tank reactors. Trans. Ind. Chem. Engng, 70A, 91-95.
9. Dogliotti, L., & Hayon, E. (1968). Flash photolysis study of sulfite, thiocyanate, and thiosulfate ions in solution. J. Phys. Chem., 72, 1800-1807.
10. Erwin, J., Wang, C.C., & Hudson, J.L. (1982). A model of oxidation in calcium sulfite slurries. Flue Gas Desulfurization, ACS Symposium Series, Vol. 188, pp. 191-120.
11. 2(g) in water and of aqueous sulphur dioxide solutions. J. Res. Natural Bureau Standards, 90, 341-358.
12. Huss, A., Lim, P. K., & Eckert, C.A. (1982). Oxidation of aqueous sulfur dioxide. J. Phys. Chem., 86, 4224-4237.
13. Lancia, A., Musmarra D., & Pepe, F. (1996). Uncatalyzed heterogeneous oxidation of calcium bisulfite. Chem. Engg. Sci., 16, 3889-3896.
14. Lancia, A., Musmarra, D., Pepe, F., & Prisciandaro, M. (1997a). Model of oxygen absorption into calcium sulfite solutions. Chem. Engng J., 66, 123-129.
15. 2 absorption into limestone suspensions. Ind. Engng Chem. Res., 36, 197-203.
16. Lancia, A., & Musmarra, D. (1999). Calcium bisulfite oxidation rate in the wet limestone-gypsum flue, gas desulfurization process. Environ. Sci. Technol. (in press).
17. Nurmi, D.B., Overman, J.W., Erwin, J., & Hudson, J.L. (1982). Sulfite oxidation in organic acid solutions. Flue Gas Desulfurization, ACS Symposium Series, Vol. 188, pp. 173-189.
18. 4. Chem. Engng Sci., 36, 215-219.
19. Pasiuk-Bronikowska, W., & Ziajka, J. (1985). Oxygen absorption into aqueous sulphur dioxide solutions. Chem. Engng Sci., 40, 1567-1572.
20. Pasiuk-Bronikowska, W., & Bronikowski, T. (1989). Kinetic model for sulphite autoxidation under heterogeneous conditions. Chem. Engng Sci., 44, 1361-1368.
21. 2 oxidation at different rate controlling steps. Chem. Engng Sci., 44, 915-920.
22. Perry, R.H., & Chilton, H.C. (1973). Chemical Engineers' Handbook, (5th Ed.). Kogakusha Tokyo: McGraw-Hill.
23. Shah, Y.T., & Kenney, C.N. (1979). Application of the penetration theories to the catalysis of gas reactions by liquid catalysts: The oxidation of sulphur dioxide. Chem. Engng Sci., 34, 1-10.
24. Shultz, J.S., & Gaden, E.L. (1956). Sulfite oxidation as a measure of areation effectiveness. Ind. Engng Chem., 48, 2209-2212.
25. Ulrich, R.K., Rochelle, G.T., & Prada, R.E. (1986). Enhanced oxygen absorption onto bisulfite solutions containing transition metal ion catalysts. Chem. Engng Sci., 41, 2138-2191.
26. Weisnicht, W.L., Overman, J., Wang., C.C., Wang., H.J., Erwin, J., & Hudson, J.M. (1980). Calcium sulfite oxidation in a slurry reactor. Chem. Engng Science, 35, 463-468.