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Certain Ni(II) catalysts convert α-olefins to oligomers with degrees of polymerization of ~4-20: Möhring, V. M.; Fink, G. Angew. Chem., Int. Ed. Engl. 1985, 24, 1001–1003.
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The change in microstructure with monomer concentration (pressure) has seen precedent in the early metal systems.
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