Trapping of a Four-Coordinate zinc salphen complex inside a crystal matrix

Chemistry - A European Journal

Volumn 15, Issue 17, 2009, Pages 4233-4237

  Escudero Adán, Eduardo C ^a   Benet Buchholz, Jordi ^a   Kleij, Arjan W ^a,b  

^a INSTITUTE OF CHEMICAL RESEARCH OF CATALONIA ICIQ   (Spain)

^b INSTITUCIÓ CATALANA DE RECERCA I ESTUDIS AVANÇATS ICREA   (Spain)

Author keywords

Coordination chemistry; Crystal matrix; N.O ligands; Supramolecular chemistry; Zinc

Indexed keywords

AXIAL POSITIONS; COORDINATE COMPLEXES; COORDINATION CHEMISTRY; CRYSTAL MATRIX; CRYSTAL TRANSITIONS; N-HETEROCYCLIC; N.O LIGANDS; REACTIVE INTERMEDIATES; SALEN COMPLEXES; SOLVENT MOLECULES; STERIC BULKS; UNIT CELL PARAMETERS;

CRYSTAL CHEMISTRY; LIGANDS; MACROMOLECULES; NUCLEAR MAGNETIC RESONANCE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SEMICONDUCTOR QUANTUM DOTS; SUPRAMOLECULAR CHEMISTRY; ZINC;

CRYSTAL STRUCTURE;

EID: 65349136380     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200900146     Document Type: Article

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53. i symmetry the methanol and the hydrogen-bonded N-heterocyclic molecule occupy two overlaying, disordered positions between two salphen units. The total occupancy is one molecule of methanol and one molecule of N-heterocyclic 2 or 3 for two molecules of [Zn(salphen)]. For further explanatory details including the disordered structure please refer to the Supporting Information.
54. 3CN that involved 2. The same holds for the crystallization experiments with 3 and 4.
55. i symmetry, results in four disordered positions between the salphen complexes. For further explanatory details including the disordered structure please refer to the Supporting Information.
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