Influences of the chemical state of alkaline compounds and the nature of alkali metal on wood pyrolysis

Industrial and Engineering Chemistry Research

Volumn 48, Issue 7, 2009, Pages 3359-3369

  Blasi, Colomba Di ^a   Galgano, Antonio ^a   Branca, Carmen ^b  

^a UNIVERSITY OF NAPLES FEDERICO II   (Italy)

^b CNR   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

2 BUTANONES; 2-CYCLOPENTENONE; ALKALINE COMPOUNDS; AQUEOUS SOLUTIONS; CHEMICAL STATE; DECOMPOSITION PROCESS; FIR WOODS; FIXED-BED REACTORS; FURFURYL ALCOHOLS; ISOEUGENOL; TOTAL PHENOLS; TOTAL YIELDS; WOOD PYROLYSIS;

ALKALINITY; CARBON DIOXIDE; CARBON MONOXIDE; CATALYST ACTIVITY; CHEMICAL REACTIONS; CRACKING (CHEMICAL); EXTRACTION; LIGHT METALS; ORGANIC COMPOUNDS; PHENOLS; POTASSIUM HYDROXIDE; SMELTING; SODIUM CHLORIDE; SUGAR (SUCROSE); SUGARS; THERMOGRAVIMETRIC ANALYSIS; WOOD;

ALKALI METAL COMPOUNDS;

ALKALI METAL COMPOUNDS; ALKALINITY; CARBON DIOXIDE; CARBON MONOXIDE; CATALYSTS; CHEMICAL REACTIONS; EXTRACTION; LIGHT METALS; ORGANIC COMPOUNDS; PHENOLS; POTASSIUM HYDROXIDE; PYROLYSIS; SMELTING; SODIUM CHLORIDE;

EID: 65249137102     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie801468y     Document Type: Article

References (50)

1. Di Blasi, C. Modeling chemical and physical processes of wood and biomass pyrolysis. Prog. Energy Combust. Sci. 2008, 34, 47.
2. Kandola, B. K.; Horrocks, A. R.; Price, D.; Coleman, G. V. Flameretardant treatments of cellulose and their influence on the mechanism of cellulose pyrolysis. J. Macromol. Sci., ReV. Macromol. Chem. Phys. 1996, C36 (4), 721.
3. Kozlowski, R.; Wladyka-Przybylank, M. Natural polymers, wood and lignocellolosic materials. In Fire Retardant Materials; Horrocks, A. R., Price, D., Eds.; Woodhead Publishing Ltd: Cambridge, UK, 2001; Chapter 9, pp 293-317.
4. Fernando, S.; Adhikari, S.; Chandrapal, C.; Murali, N. Biorefineries: current status, challenges, and future direction. Energy Fuels 2006, 20, 1727.
5. Mohan, D.; Pittman, C. U.; Steele, P. Pyrolysis of wood/biomass for bio-oil: a critical review. Energy Fuels 2006, 20, 848.
6. Piskorz, J.; Radlein, D.; Scott, D. S.; Czernik, S. Liquid products from the fast pyrolysis of wood and cellulose. In Research in Thermochemical Biomass Conversion; Bridgwater, A. V., Kuester, J. L., Eds.; Elsevier Applied Science: London, 1988; pp 557-571.
7. Antal, M. J.; Varhegyi, G. Cellulose pyrolysis kinetics: the current state of knowledge. Ind. Eng. Chem. Res. 1995, 34, 703.
8. Scott, D. S.; Paterson, L.; Piskorz, J.; Radlein, D. Pretreatment of poplar wood for fast pyrolysis: rate of cation removal. J. Anal. Appl. Pyrolysis 2000, 57, 169.
9. Beaumont, O.; Schwob, Y. Influence of physical and chemical parameters on wood pyrolysis. Ind. Eng. Chem. Process Des. DeV. 1984, 23, 637.
10. Pavlath, A.E.; Gregorski, K. S. Carbohydrate pyrolysis. II. Formation of furfural and furfuryl alcohol during the pyrolysis of selected carbohydrates with acidic and basic catalysts. In Fundamentals of Biomass Thermochemical Conversion; Overend, R. P., Milne, T. A., Mudge, L. K., Eds.; Elsevier: London, 1985; pp 155-163.
11. Zaror, C. A.; Hutchings, I. S.; Pyle, D. L.; Stiles, N.; Kandiyoti, R. Secondary char formation in the catalytic pyrolysis of biomass. Fuel 1985, 64, 990.
12. Font, R.; Marcilla, A.; Verdu, E.; Devesa, J. Fluidized-bed flash pyrolysis of almond shells. Temperature influence and catalyst screening. Ind. Eng. Prod. Res. DeV. 1986, 25, 491.
13. Antal, M. J.; Mok, W. S. L.; Varhegyi, G.; Szekely, T. Review of methods for improving the yields of charcoal from biomass. Energy Fuels 1990, 4, 221.
14. Chen, Y.; Frendi, A.; Tewari, S. S.; Sibulkin, M. Combustion properties of pure and fire-retarded cellulose. Combust. Flame 1991, 84, 121.
15. Nik-Azar, M.; Hajaligol, M. R.; Sohrabi, M.; Dabir, B. Mineral matter effects in rapid pyrolysis of beech wood. Fuel Process. Technol. 1991, 51, 7-17.
16. Krieger-Brockett, B. Microwave pyrolysis of biomass. Res. Chem. Intermed. 1994, 20, 39.
17. Ravendraan, K.; Ganesh, A.; Khilar, K. C. Influence of mineral matter on biomass pyrolysis characteristics. Fuel 1995, 74, 1812.
18. Szabo, P.; Varhegyi, G.; Till, F.; Faix, O. Thermogravimetri/mass spectrometric characterization of two energy crops, Arundo donax and Miscanthus sinensis. J. Anal. Appl. Pyrolysis 1996, 36, 179.
19. Wang, J.; Zhang, M.; Chen, M.; Min, F.; Zhang, S.; Ren, Z.; Yan, Y. Catalytic effects of six inorganic compounds on pyrolysis of three kinds of biomass. Thermochim. Acta 2006, 444, 110.
20. Nowakowski, D. J.; Jones, J. M.; Brydson, R. K.; Ross, A. B. Potassium catalysis in the pyrolysis behavior of short rotation willow coppice. Fuel 2007, 86, 2389.
21. Dobele, G.; Urbanovich, I.; Zhurin, A.; Kampars, V.; Meier, D. Application of analytical pyrolysis for wood fire protection control. J. Anal. Appl. Pyrolysis 2007, 79, 47.
22. Kleen, M.; Gellerstedt, G. Influence of inorganic species on the formation of polysaccaride and lignin degradation products in the analytical pyrolysis of pulps. J. Anal. Appl. Pyrolysis 1995, 35, 15.
23. Jakab, E.; Faix, O.; Till, F. Thermal decomposition of milled wood lignins studied by thermogravimetry/mass spectroscopy. J. Anal. Appl. Pyrolysis 1997, 40-41, 171.
24. Amen-Chen, C.; Pakdel, H.; Roy, C. Production of monomeric phenols by thermochemical conversion of biomass: a review. Bioresour. Technol. 2001, 79, 277.
25. Perry's Chemical Engineering Handbook, 6th ed., International Student Edition; Perry, R. H., Green, D. W., Maloney, J. O., Eds.; McGraw- Hill Book Co.: New York, 1984; Chapter 3, pp 19-21.
26. Lillo-Rodenas, M. A.; Marco-Lozar, J. P.; Cazorla-Amoros, D.; Linares-Solano, A. Understanding chemical reactions between carbons and NaOH and KOH. An insight into the chemical activation mechanism. Carbon 2003, 41, 267.
27. Wu, X.; Radovic, L. R. Catalytic oxidation of carbon/carbon composite materials in the presence of potassium and calcium acetates. Carbon 2005, 43, 333.
28. Di Blasi, C.; Branca, C.; Galgano, A. Effects of diammonium phosphate on the yields and composition of products from fir wood pyrolysis. Ind. Eng. Chem. Res. 2007, 46, 430.
29. Di Blasi, C.; Branca, C.; Galgano, A. Flame retarding of wood by impregnation with boric acid - Pyrolysis products and char oxidation rates. Polym. Degrad. Stab. 2007, 92, 752.
30. Di Blasi, C.; Branca, C.; Galgano, A. Thermal and catalytic decomposition of wood impregnated with phosphorous- and sulfurcontaining ammonium salts. Polym. Degrad. Stab. 2008, 93, 335.
31. Di Blasi, C.; Branca, C.; Galgano, A. Products and global weight loss rates of wood decomposition catalyzed by zinc chloride. Energy Fuels 2008, 22, 663.
32. Di Blasi, C.; Branca, C.; D'Errico, G. Degradation characteristics of straw and washed straw. Thermochim. Acta 2000, 364, 133.
33. http://www.chembuddy.com.
34. Shimada, N.; Kawamoto, H.; Saka, S. Different action of alkali/ alkaline earth metal chlorides on cellulose pyrolysis. J. Anal. Appl. Pyrolysis 2008, 81, 80.
35. Mims, C. A.; Rose, K. D.; Melchior, M.T. Characterization of catalyzed carbon surfaces by derivatization and solid-state NMR. J. Am. Chem. Soc. 1982, 104, 6886.
36. Gabor, M.; Puppl, L.; Izvekov, V.; Beyer, H. Interaction of kaolinite with organic and inorganic alkali metal salts at 25-1300C. Thermochim. Acta 1989, 148, 431.
37. Ishida, M.; Toida, M.; Shimizu, T.; Takenaka, S.; Otsuka, K. Formation of hydrogen without COx from carbon, water, and alkali hydroxide. Ind. Eng. Chem. Res. 2004, 43, 7204.
38. Mok, W. S. L.; Antal, M. J. Effects of pressure on biomass pyrolysis. II. Heats of reactions of cellulose pyrolysis. Thermochim. Acta 1983, 68, 165.
39. Milosavljevic, I.; Oja, V.; Suuberg, E. M. Thermal effects in cellulose pyrolysis: relationship to char formation. Ind. Eng. Chem. Res. 1996, 35, 653.
40. Di Blasi, C. Modelling intra- and extra-particle processes of wood fast pyrolysis. AIChE J. 2002, 48, 2386.
41. Moreno-Castilla, C.; Carrasco-Marin, F.; Lopez-Ramon, M. V.; Alvarez-Merino, M. A. Chemical and physical activation of olive-mill waste water to produce activated carbons. Carbon 2001, 39, 1415.
42. Marsh, H.; Yan, D. S.; O'Grady, T. M.; Wennerberg, A. Formation of active carbons from cokes using potassium hydroxide. Carbon 1984, 22, 603.
43. http://old.iupac.org/publications/pac/1986/5806x0869.pdf.
44. http://www.leffingwell.com/burnt.htm.
45. Miller, J. A.; Pugh, A. W.; Ullah, G. M.; Welsh, G. M. Synthesis and antifungal properties of some simple cyclopentenones and derivatives. Tetrahedron Lett. 2001, 42, 955.
46. http://ref.daum.net/item/706594.
47. Chen, X.; Li, H.; Luo, H.; Qiao, M. Liquid phase hydrogenation of furfural to furfuryl alcohol over Mo-doped Co-B amorphous alloy catalysts. Appl. Catal., A 2002, 233, 13.
48. Pakdel, H.; Amen-Chen, C.; Roy, C. Phenolic compounds from vacuum pyrolysis of wood wastes. Can. J. Chem. Eng. 1997, 75, 121.
49. Murwanashyaka, J. N.; Pakdel, H.; Roy, C. Fractional vacuum pyrolysis of biomass and separation of phenolic compounds by steam distillation. In Fast Pyrolysis of Biomass: A Handbook; Bridgwater, A. V., Ed.; CPL Press: Newbury, UK, 2002; Vol. 2; pp 407-418.
50. Cerveny, L.; Krejcikova, A.; Marhaul, A.; Rozicka, V. Isomerization of eugenol to isoeugenol - Kinetic studies. React. Kinet. Catal. Lett 1987, 33, 471.