A general method for determining the role of spectroscopically observed species in reaction mechanisms: Analysis of coverage transients (ACT)

Journal of Catalysis

Volumn 263, Issue 2, 2009, Pages 359-371

  Gott, Travis ^a   Oyama, S Ted ^a  

^a State University   (United States)

Author keywords

2,3,4,5 Tetrahydropyridine; Hydrodenitrogenation; In situ FTIR; Mechanism; Nickel phosphide; Pyridine; transient coverage analysis

Indexed keywords

2,3,4,5-TETRAHYDROPYRIDINE; ADSORBED INTERMEDIATES; ADSORPTION-DESORPTION PROCESS; CONCENTRATION OF; FOURIER TRANSFORM INFRA-RED SPECTROSCOPIES; GENERAL METHODS; HETEROGENEOUS REACTIONS; HYDRODENITROGENATION; IN SITU FTIR; IN-SITU; INERT GAS; KINETIC MEASUREMENTS; KINETIC METHODS; KINETIC STUDIES; NICKEL PHOSPHIDE; OVERALL REACTIONS; PYRIDINE HYDRODENITROGENATION; PYRIDINIUM; RATE OF REACTIONS; REACTION CONDITIONS; REACTION INTERMEDIATES; REACTION MECHANISMS; REACTIVE GAS; SURFACE COVERAGES; SURFACE INTERMEDIATES; SURFACE SPECIES; TIME RESPONSE;

ADSORPTION; ATMOSPHERIC PRESSURE; DESORPTION; FOURIER TRANSFORM INFRARED SPECTROSCOPY; FOURIER TRANSFORMS; HYDROGEN; INERT GASES; NICKEL; NICKEL ALLOYS; NICKEL COMPOUNDS; PYRIDINE; REACTION RATES; SILICA; SPECTROSCOPIC ANALYSIS; TELECOMMUNICATION NETWORKS; TRANSIENTS;

SURFACE REACTIONS;

EID: 64649097136     PISSN: 00219517     EISSN: 10902694     Source Type: Journal    
DOI: 10.1016/j.jcat.2009.02.028     Document Type: Article

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