Pervaporation performance of quaternized poly(vinyl alcohol) and its crosslinked membranes for the dehydration of ethanol

Journal of Membrane Science

Volumn 335, Issue 1-2, 2009, Pages 68-75

  Zhang, Qiu Gen ^a   Liu, Qing Lin ^a   Zhu, Ai Mei ^a   Xiong, Ying ^a   Ren, Lang ^a  

^a Ethers and Esters   (China)

Author keywords

Crosslinking; Ethanol; Pervaporation; Quaternized poly(vinyl alcohol)

Indexed keywords

AQUEOUS SOLUTIONS; CROSS LINKED MEMBRANES; CROSSLINKED; DEGREE OF CROSSLINKING; DEHYDRATION OF ETHANOLS; ETHANOL SOLUTIONS; GLUTARALDEHYDE; PERM SELECTIVITIES; PVA MEMBRANES; QUATERNARY AMMONIUM GROUPS; QUATERNIZATION; QUATERNIZED POLY(VINYL ALCOHOL); WATER CONTACT ANGLE MEASUREMENTS; WATER PERMEABILITIES; WATER PERMSELECTIVITY; X-RAY POWDER DIFFRACTIONS;

ALDEHYDES; AMINES; AMMONIUM COMPOUNDS; ANGLE MEASUREMENT; CAPILLARITY; CONTACT ANGLE; DEHYDRATION; DEWATERING; ETHANOL; EVAPORATION; PERVAPORATION; SCANNING ELECTRON MICROSCOPY;

MEMBRANES;

ALCOHOL; GLUTARALDEHYDE; POLYVINYL ALCOHOL; QUATERNARY AMMONIUM DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; CROSS LINKING; HYDROPHILICITY; PERVAPORATION; PRIORITY JOURNAL; SCANNING ELECTRON MICROSCOPY; WATER PERMEABILITY; X RAY DIFFRACTION;

EID: 64549148840     PISSN: 03767388     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.memsci.2009.02.039     Document Type: Article

References (34)

1. Shao P., and Huang R.Y.M. Polymeric membrane pervaporation. J. Membr. Sci. 287 (2007) 162-179
2. Chapman P.D., Oliveira T., Livingston A.G., and Li K. Membranes for the dehydration of solvents by pervaporation. J. Membr. Sci. 318 (2008) 5-37
3. Semenova S.I., Ohya H., and Soontarapa K. Hydrophilic membranes for pervaporation: an analytical review. Desalination 110 (1997) 251-286
4. Huang R.Y.M., Shao P., Feng X., and Anderson W.A. Separation of ethylene glycol-water mixtures using sulfonated poly(ether ether ketone) pervaporation membranes: membrane relaxation and separation performance analysis. Ind. Eng. Chem. Res. 41 (2002) 2957-2965
5. Uragami T., Takuno M., and Miyata T. Evapomeation characteristics of crosslinked quaternized chitosan membranes for the separation of an ethanol/water azeotrope. Macromol. Chem. Phys. 203 (2002) 1162-1170
6. Chen J.H., Liu Q.L., Zhu A.M., Fang J., and Zhang Q.G. Dehydration of acetic acid using sulfonation cardo polyetherketone (SPEK-C) membranes. J. Membr. Sci. 308 (2008) 171-179
7. Chen J.H., Liu Q.L., Zhu A.M., Zhang Q.G., and Fang J. Pervaporation separation of MeOH/DMC mixtures using STA/CS hybrid membranes. J. Membr. Sci. 315 (2008) 74-81
8. Zhang W., Li G., Fang Y., and Wang X. Maleic anhydride surface-modification of crosslinked chitosan membrane and its pervaporation performance. J. Membr. Sci. 295 (2007) 130-138
9. Tu C.-Y., Liu Y.-L., Lee K.-R., and Lai J.-Y. Hydrophilic surface-grafted poly(tetrafluoroethylene) membranes using in pervaporation dehydration processes. J. Membr. Sci. 274 (2006) 47-55
10. Yeom C.K., and Lee K.H. Pervaporation separation of water-acetic acid mixtures through poly(vinyl alcohol) membranes crosslinked with glutaraldehyde. J. Membr. Sci. 109 (1996) 257-265
11. Yeom C.K., and Huang R.Y.M. Pervaporation separation of aqueous mixtures using crosslinked poly(vinyl alcohol) (PVA). I. Characterization of the reaction between PVA and amic acid. Angew. Makromol. Chem. 184 (1991) 27-35
12. Yeom C.K., and Lee K.H. A study on permeation behavior of a liquid mixture through PVA membranes having a crosslinking gradient structure in pervaporation. J. Appl. Polym. Sci. 59 (1996) 1271-1279
13. Nuran I., and Oya S. Separation characteristics of acetic acid-water mixtures by pervaporation using poly(vinyl alcohol) membranes modified with malic acid. Chem. Eng. Process. 44 (2005) 1019-1027
14. Rhim J.W., Yeom C.K., and Kim S.W. Modification of poly (vinyl alcohol) membranes using sulfur-succinic acid and its application to pervaporation separation of water-alcohol mixtures. J. Appl. Polym. Sci. 68 (1998) 1717-1723
15. Rhim J.W., Yoon S.W., Kim S.W., and Lee K.H. Pervaporation separation and swelling measurement of acetic acid-water mixtures using crosslinked PVA membranes. J. Appl. Polym. Sci. 63 (1997) 521-527
16. Burshe M.C., Sawant S.B., Joshi J.B., and Pangarkar V.G. Sorption and permeation of binary water-alcohol systems through PVA membranes crosslinked with multifunctional crosslinking agents. Sep. Purif. Technol. 12 (1997) 145-156
17. Uragami T., Katayama T., Miyata T., Tamura H., Shiraiwa T., and Higuchi A. Dehydration of an ethanol/water azeotrope by novel organic-inorganic hybrid membranes based on quaternized chitosan and tetraethoxysilane. Biomacromolecules 5 (2004) 1567-1574
18. Uragami T., Okazaki K., Matsugi H., and Miyata T. Structure and permeation characteristics of an aqueous ethanol solution of organic-inorganic hybrid membranes composed of poly(vinyl alcohol) and tetraethoxysilane. Macromolecules 35 (2002) 9156-9163
19. Kariduraganavar M.Y., Kulkarni S.S., and Kittur A.A. Pervaporation separation of water-acetic acid mixtures through poly(vinyl alcohol)-silicone based hybrid membranes. J. Membr. Sci. 246 (2005) 83-93
20. Liu Y.-L., Su Y.-H., and Lai J.-Y. In situ crosslinking of chitosan and formation of chitosan-silica hybrid membranes with using g-glycidoxypropyltrimethoxysilane as a crosslinking agent. Polymer 45 (2004) 6831-6837
21. Zhang Q.G., Liu Q.L., Jiang Z.Y., and Chen Y. Anti-trade-off in dehydration of ethanol by novel PVA/APTEOS hybrid membranes. J. Membr. Sci. 287 (2007) 237-245
22. Zhang Q.G., Liu Q.L., Jiang Z.Y., Ye L.Y., and Zhang X.H. Effects of annealing on the physico-chemical structure and permeation performance of novel hybrid membranes of poly(vinyl alcohol)/γ-aminopropyl-triethoxysilane. Micropor. Mesopor. Mater. 110 (2008) 379-391
23. Chiang W.-Y., and Lin Y.-H. Properties of modified poly(vinyl alcohol) membranes prepared by the grafting of new polyelectrolyte copolymers for water-ethanol mixture separation. J. Appl. Polym. Sci. 86 (2002) 2854-2859
24. Huang Z., Shi Y., Wen R., Guo Y.H., Su J.F., and Matsuura T. Multilayer poly(vinyl alcohol)-zeolite 4A composite membranes for ethanol dehydration by means of pervaporation. Sep. Purif. Technol. 51 (2006) 126-136
25. Huang Z., Tan W., Qiu X., and Kulprathipanja S. Pervaporation study of aqueous ethanol solution through zeolite-incorporated multilayer poly(vinyl alcohol) membranes: effect of zeolites. J. Membr. Sci. 276 (2006) 260-271
26. Rhim J.-W., Lee S.-W., and Kim Y.-K. Pervaporation separation of water-ethanol mixtures using metal-ion-exchanged poly(vinyl alcohol) (PVA)/sulfosuccinic acid (SSA) membranes. J. Appl. Polym. Sci. 85 (2002) 1867-1873
27. Rafik M., Mas A., Guimon M.-F., Guimon C., Elharfi A., and Schué F. Plasma-modified poly(vinyl alcohol) membranes for the dehydration of ethanol. Polym. Int. 52 (2003) 1222-1229
28. Zhang Q.G., Liu Q.L., Shi F.F., and Xiong Y. Structure and permeation of organic-inorganic hybrid membranes composed of poly(vinyl alcohol) and polysilisesquioxane. J. Mater. Chem. 18 (2008) 4646-4653
29. Xiong Y., Fang J., Zeng Q.H., and Liu Q.L. Preparation and characterization of crosslinked quaternized poly(vinyl alcohol) membranes for anion exchange membrane fuel cells. J. Membr. Sci. 311 (2008) 319-325
30. Wijmans J.G. Process performance = membrane properties + operating. J. Membr. Sci. 220 (2003) 1-3
31. Singh A., and Mukherjee M. Swelling dynamics of ultrathin polymer films. Macromolecules 36 (2003) 8728-8731
32. Ye L.Y., Liu Q.L., Zhang Q.G., Zhu A.M., and Zhou G.B. Pervaporation characteristics and structure of poly(vinyl alcohol)/poly(ethylene glycol)/tetraethoxysilane hybrid membranes. J. Appl. Polym. Sci. 105 (2007) 3640-3648
33. Kim K.J., Park S.H., So W.W., and Moon S.J. Pervaporation separation of aqueous organic mixtures through sulfated zirconia-poly(vinyl alcohol) membrane. J. Appl. Polym. Sci. 79 (2001) 1450-1455
34. Yeom C.K., Lee S.H., and Lee J.M. Pervaporative permeations of homologous series of alcohol aqueous mixtures through a hydrophilic membrane. J. Appl. Polym. Sci. 79 (2001) 703-713