Selective N-alkylation of aniline with methanol over a heteropolyacid on montmorillonite K10

Applied Clay Science

Volumn 44, Issue 3-4, 2009, Pages 255-258

  Nehate, Manoj ^a   Bokade, Vijay V ^a  

^a NATIONAL CHEMICAL LABORATORY   (India)

Author keywords

Alkylation; Aniline; Heteropolyacid; Montmorillonite K10; N methylaniline

Indexed keywords

CARBON NUMBERS; COMMERCIAL CATALYSTS; HETEROPOLYACID; ISO PROPANOLS; K-10 MONTMORILLONITES; LIQUID-PHASE ALKYLATIONS; MONTMORILLONITE K10; N ALKYLATIONS; N BUTANOLS; N PROPANOLS; N-METHYLANILINE; OPERATING CONDITIONS; OPTIMIZATION OF PROCESS PARAMETERS; TEXTILE DYES;

ANILINE; CATALYSIS; CATALYSTS; CLAY MINERALS; ETHANOL; HYDROCARBONS; METHANOL; NEGATIVE IONS; ODORS; PROPANOL; SILICATE MINERALS; TEXTILE PROCESSING;

ALKYLATION;

CATALYST; CHEMICAL PROPERTY; METHANOL; METHYLATION; MONTMORILLONITE; OPTIMIZATION;

EID: 64449085914     PISSN: 01691317     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.clay.2009.02.011     Document Type: Article

References (24)

1. An Ullmann's Encyclopedia of Industrial Organic Chemicals, 1999. Wiley-VCH, Weinheim, 1, 507.
2. Anand R., Khaire S.S., Maheswari R., Gore K.U., and Chumbhale V.R. N-alkylation of aniline with ethanol over HY and dealuminated HY zeolites. Applied Catalysis A: General 242 (2003) 171-177
3. Bhattacharya A.K., and Nandi D.K. Pressure synthesis of N,N-diethylaniline. Industrial Engineering Chemistry Product Research Development 14 (1975) 162-167
4. 4) catalysts. Journal of Catalysis 172 (1997) 103-109
5. 3 catalysts. Applied Catalysis A: General 166 (1998) 39-45
6. Doraiswamy L.K., Krishnan G.R.V., and Mukherjee S.P. Chemical Engineering 88 (1981) 78
7. Garces L.J., Makwana V.D., Hincapie B., Sacco A., and Suib S.L. Selective N,N-methylation of aniline over cocrystallized zeolites RHO and zeolite X (FAU) and over Linde type L (Sr, K-LTL). Journal of Catalysis 217 (2003) 107-116
8. Ivanova I.I., Pomakhina E.B., Rebrov A.I., Hunger M., Kolyagin Y.G., and Weitkamp J. Surface species formed during aniline methylation on zeolite H-Y investigated by in situ MAS NMR spectroscopy. Journal of Catalysis 203 (2001) 375-381
9. Kim J.S., Shon O.J., Rim J.A., Ki S.K., and Yoon J. Pyrene-armed calix [4] azacrowns as new fluorescent ionophores: "molecular taekwondo process via fluorescence change. Journal of Organic Chemistry 67 (2002) 2348-2351
10. Luque R., Campelo J.M., Luna D., Marinas J.M., and Romero A.A. Catalytic performance of al-MCM-41 materials in the N-alkylation of aniline. Journal of Molecular Catalysis A: Chemical 269 (2007) 190-196
11. Negwer M. Organic-Chemical Drugs and their Synonyms. 7th ed. (1994), Akademie Verlag GmbH, Berlin (an international survey)
12. Narayanan S., and Deshpande K. Mechanism of aniline alkylation over vanadia and supported vanadia. Journal of Molecular Catalysis A: Chemical 104 (1995) L109-L113
13. Narayanan S., and Prasad B.P. Characterization and aniline alkylation activity of vanadia and silica-supported vanadia catalysts. Journal of Molecular Catalysis A: Chemical 96 (1995) 57-64
14. Narayanan S., and Deshpande K. A comparative aniline alkylation activity of montmorillonite and vanadia-montmorillonite with silica and vanadia-silica. Applied Catalysis A: General 135 (1996) 125-135
15. Narayanan S., and Sultana A. Aniline alkylation with ethanol over zeolites and vanadium modified zeolites prepared by solid state exchange method. Applied Catalysis A: General 167 (1998) 103-111
16. Narayanan S., and Deshpande K. Aniline alkylation over solid acid catalysts. Applied Catalysis A: General 199 (2000) 1-31
17. Nishamol K., Rahna K.S., and Sugunan S. Selective alkylation of aniline to N-methyl aniline using chromium manganese ferrospinels. Journal of Molecular Catalysis A: Chemical 209 (2004) 89-96
18. 4 (x = 0, 0.2, 0.5, 0.8 and 1.0)-type ferrospinels prepared via. a low temperature route for the alkylation of aniline and phenol using methanol as the alkylation agent. Applied Catalysis A: General 230 (2002) 245-251
19. Sreekumar K., Mathew T., Mirajkar S.P., Sugunan S., and Rao B.S. A comparative study on aniline alkylation activity using methanol and dimethyl carbonate as the alkylating agents over Zn-Co-Fe ternary spinel systems. Applied Catalysis A: General 201 (2000) L1-L8
20. Stauffer S.R., and Hartwig J.F. Fluorescence resonance energy transfer as a high-throughput assay for coupling reactions. Arylation of amines as a case study. Journal of American Chemical Society 125 (2003) 6977-6985
21. Sunwanprasop S., Nhujak T., Roengsumran S., and Petsom A. Petroleum marker dyes synthesized from cardanol and aniline derivatives. Industrial Engineering Chemistry Research 43 (2004) 4973-4978
22. Selva M., Tundo P., and Foccardi T. Mono-N-methylation of functionalized anilines with alkyl methyl carbonates over NaY faujasites. 4. kinetics and selectivity. Journal of Organic Chemistry 70 (2005) 2476-2485
23. 4. Applied Catalysis A: General 320 (2007) 64-68
24. Yadav G.D., and Doshi N.S. Alkylation of aniline with methyl-tert-butyl-ether (MTBE) and tert-butanol over solid acids: product distribution and kinetics. Journal of Molecular Catalysis A: Chemical 194 (2003) 195-209