Chirality control in optically active polysilane aggregates

Journal of the American Chemical Society

Volumn 126, Issue 42, 2004, Pages 13822-13826

  Peng, Wenqing ^a   Motonaga, Masao ^a,b   Koe, Julian R ^a  

^a INTERNATIONAL CHRISTIAN UNIVERSITY   (Japan)

^b Tescom Co Ltd   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

COMPOSITION; ORGANIC POLYMERS; SPECTROSCOPIC ANALYSIS; SYNTHESIS (CHEMICAL);

CHIRALITY CONTROL; CIRCULAR DICHROISM (DC); POLYMER SOLUTION; SOLVENT RATIO;

POLYSILANES;

BENZENE DERIVATIVE; POLYMER; PROPANE; SILANE DERIVATIVE; SOLVENT;

ARTICLE; CHEMICAL COMPOSITION; CHEMICAL ENVIRONMENT; CHEMICAL STRUCTURE; CHIRALITY; CIRCULAR DICHROISM; CONFORMATION; EXPERIMENTAL MODEL; OPTICAL ROTATION; SUBSTITUTION REACTION; SYNTHESIS;

EID: 6444232823     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja046235i     Document Type: Article

References (18)

1. (a) Green, M. M.; Peterson, N. C.; Sato, T.; Teramoto, A.; Cook, R.; Lifson, S. Science 1995, 268, 1860-1866.
2. (b) Pu, L. Macromol. Rapid Commun. 2000, 21, 795-809.
3. (c) Okamoto, Y.; Nakano, T. Chem. Rev. 1994, 94, 349-372.
4. (d) Nolte, R. J. M. Chem. Soc. Rev. 1994, 23, 11-19.
5. Fujiki, M. Macromol. Rapid Commun. 2001, 22, 539-563.
6. Nakashima, H.; Fujiki, M.; Koe, J. R.; Motonaga, M. J. Am. Chem. Soc. 2001, 123, 1963-1969.
7. Fujiki, M.; Koe, J. R.; Terao, K.; Sato, T.; Teramoto, A.; Watanabe, J. Polymer. J. 2003, 35, 297-344.
8. (a) Koe, J. R.; Fujiki, M.; Nakashima, H. Chem. Commun. 2000, 389-390.
9. (b) Fujiki, M. J. Am. Chem. Soc. 2000, 122, 3336-3343.
10. (c) Sato, T.; Terao, K.; Teramoto, A.; Fujiki, M. Macromolecules 2002, 35, 5355-5357.
11. Hazard warning: proper precautions should be taken when handling both sodium and chlorosilanes. See also Supporting Information.
12. Fujiki, M. J. Am. Chem. Soc. 1994, 116, 11976-11981.
13. Fujiki, M.; Toyoda, S.; Yuan, C. H.; Takigawa, H. Chirality 1998, 10, 667-675.
14. Peeters, E.; Delmotte, A.; Janssen, R. A.; Meijer, E. W. Adv. Mater. 1997, 9, 493-496.
15. Obata, K.; Kira, M. Macromolecules 1998, 31, 4666-4668.
16. Nakanishi, K.; Berova, N. Circular Dichroism: Principles and Applications; Wiley-VCH: New York, 1994; Chapter 19.
17. Calculations were performed using CS Chem3D Pro v. 5.0 with standard bond lengths.
18. Nakashima, H. Ph.D. Thesis, Waseda University, Tokyo, 2002, Chapter 4, p 85.