Differential reactivity of aromatic diamines during polyimide formation in water

European Polymer Journal

Volumn 45, Issue 5, 2009, Pages 1607-1616

  Dao, Buu ^a   Groth, Andrew M ^a   Hodgkin, Jonathan ^a  

^a CSIRO   (Australia)

Author keywords

Diamine reactivity; Model compounds; Polyimide synthesis; Water solubility

Indexed keywords

AMINO GROUPS; AQUEOUS SOLUTIONS; AROMATIC DIAMINES; DIAMINE REACTIVITY; FTIR; MASS SPECTROSCOPIES; MODEL COMPOUNDS; REACTIVITY CHANGES; WATER SOLUBILITY;

AMINATION; AMINES; AROMATIC COMPOUNDS; CHEMICAL REACTIVITY; COMPLEXATION; FOURIER TRANSFORM INFRARED SPECTROSCOPY; MASS SPECTROMETRY; MECHANICAL PROPERTIES; POLYIMIDES; POLYMERS; SOLUBILITY; TERNARY SYSTEMS;

SYNTHESIS (CHEMICAL);

EID: 64349111507     PISSN: 00143057     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.eurpolymj.2008.12.012     Document Type: Article

References (15)

1. Wilson D., Stenzenberger H.D., and Hergenrother P.M. Polyimides (1990), Blackie & Son Ltd., London p. 297
2. Hedrick J.L., Charlier Y., DiPietro R., Jayaraman S., and McGrath J. High Tg polyimide nanofoams derived from pyromellitic dianhydride and 1,1-bis(4-aminophenyl)-1-phenyl-2,2,2-trifluoroethane. J Polym Sc. A: Polym Chem 34 14 (1996) 2867
3. Mittal KL, editor. Polyimides: synthesis, characterization, and applications, vol. 2. In: Proceedings of the first technical conference on polyimides, held under the auspices of the mid-hudson section of the society of plastics engineers, November 10-12, 1982, Ellenville, NY; 1984. p. 565.
4. Mittal KL, editor. Polyimides: synthesis, characterization, and applications, vol. 1. In: Proceedings of the first technical conference on polyimides, held under the auspices of mid-hudson section of the society of plastics engineers, November 10-12, 1982, Ellenville, NY; 1984. p. 614.
5. Ohya H, Kudryavtsev VV, Semenova SI. Polyimide membranes: applications, fabrications, and properties; 1996. p. 324.
6. Kim Y.J., Glass T.E., Lyle G.D., and McGrath J.E. Kinetic and mechanistic investigations of the formation of polyimides under homogeneous conditions. Macromolecules 26 6 (1993) 1344-1358
7. Hodgkin J.H. Reactivity changes during polyimide formation. J Polym Sci: Polym Chem Ed 14 2 (1976) 409-431
8. Hawthorne D.G., and Hodgkin J.H. Amine reactivity changes in imide formation from heterocyclic bases. High Perform Polym 11 3 (1999) 315-329
9. Chiefari J., Dao B.N., Groth A.M., and Hodgkin J.H. Water as solvent in polyimide synthesis: thermoset and thermoplastic examples. High Perform Polym 15 3 (2003) 269-279
10. Chiefari J., Dao B.N., Groth A.M., and Hodgkin J.H. Water as solvent in polyimide synthesis. II: Processable aromatic polyimides. High Perform Polym 18 1 (2006) 31-44
11. Chiefari J., Dao B.N., Groth A.M., and Hodgkin J.H. Water as solvent in polyimide synthesis. III: Towards the synthesis of polyamideimides. High Perform Polym 18 4 (2006) 437-451
12. Dao B.N., Groth A.M., and Hodgkin J.H. Microwave-assisted aqueous polyimidization using high-throughput techniques. Macromol Rapid Commun 28 5 (2007) 604-607
13. Hodgkin JH, Laycock BG, Morton TC, Hawthorn DG. US Patent Specification 6,333,391, Aqueous Polyimide Process; 2001.
14. Dao B., Hodgkin J.H., and Morton T.C. Important factors controlling synthesis of imides in water. High Perform Polym 11 2 (1999) 205-218
15. Andres Ordax F.J., and Merino de la Fuente J.M. Potentiometric study of formation equilibriums of bivalent cation-diamine complexes. I: Protonation equilibriums of some phenylenediamines. Bull Soc Chim Fr 9-10 Pt. 1 (1979) 430-433