Unique effect of coordination of an alkene moiety in products on Ruthenium-catalyzed chemoselective C-H alkenylation

Organic Letters

Volumn 11, Issue 4, 2009, Pages 855-858

  Ueno, Satoshi ^a   Kochi, Takuya ^b   Chatani, Naoto ^a   Kakiuchi, Fumitoshi ^b  

^a KEIO UNIVERSITY   (Japan)

^b OSAKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 64349107670     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol802819b     Document Type: Article

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43. A reaction of 2 with trimethylvinylsilane affords dehydrogenated ruthenium complex, which shows high activity for C-H bond cleavage. See, also ref 7b.
44. In the absence of pinacolone, acetophenone (8) not only functions as a substrate, but as a hydride acceptor. See ref 5b for further information.
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