Synthesis and Coordination Properties of Trifluoromethyl Decorated Derivatives of 2,6-Bis[(diphenylphosphinoyl)methyl]pyridine N-Oxide Ligands with Lanthanide Ions

Inorganic Chemistry

Volumn 48, Issue 7, 2009, Pages 3104-3113

  Pailloux, Sylvie ^a,b,c   Shirima, Cornel Edicome ^a,b,c   Ray, Alisha D ^a,b,c   Duesler, Eileen N ^a,b,c   Paine, Robert T ^a,b,c   Klaehn, John R ^a,b,c   McIlwain, Michael E ^a,b,c   Hay, Benjamin P ^a,b,c  

^a UNIVERSITY OF NEW MEXICO   (United States)

^b IDAHO NATIONAL LABORATORY   (United States)

^c OAK RIDGE NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

2,6 BIS((DIPHENYLPHOSPHINOYL)METHYL)PYRIDINE N OXIDE; 2,6-BIS((DIPHENYLPHOSPHINOYL)METHYL)PYRIDINE N-OXIDE; AMINE OXIDE; ION; LANTHANIDE; LIGAND; ORGANOMETALLIC COMPOUND; PYRIDINE DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

CRYSTALLOGRAPHY, X-RAY; CYCLIC N-OXIDES; IONS; LANTHANOID SERIES ELEMENTS; LIGANDS; MODELS, MOLECULAR; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; PYRIDINES;

EID: 64349090837     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic802390c     Document Type: Article

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44. For example F(l)/C(7)-P(l)-C(14), 112.65(6)°; F(4)/0(1)-P(l)-C(14). 111.82(6)°; F(7)/C(22)-P(2)-C(29), 113.61(7)°, F(10)/O(2)-P(2)-C(21), 111.83(7)°.
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46. PO. Pi-electron shifts also certainly contribute in these molecules and further study will be required to provide a more detailed picture of the impacts of CF3 substituents on the bonding and spectra for these and related compounds.