Synthesis of zeolite β from kaolin and its catalytic performance for FCC naphtha aromatization

Energy and Fuels

Volumn 23, Issue 1, 2009, Pages 60-64

  Baojian, Shen ^a   Ping, Wang ^a   Zhou, Yi ^a   Wei, Zhang ^a   Xuefang, Tong ^a   Yuan, Liu ^a   Qiaoxia, Guo ^a   Jinsen, Gao ^a   Chunming, Xu ^a  

^a CHINA UNIVERSITY OF PETROLEUM   (China)

Author keywords

[No Author keywords available]

Indexed keywords

ACID SITES; BET SURFACE AREA MEASUREMENTS; CATALYTIC EVALUATIONS; CATALYTIC PERFORMANCE; CRYSTALLINITY; LOW COSTS; MACRO POROSITIES; PRODUCT DISTRIBUTIONS; SEM; SYNTHESIS CONDITIONS; THERMAL STABILITIES; XRD;

AROMATIC HYDROCARBONS; AROMATIZATION; CATALYSIS; CATALYSTS; KAOLIN; NAPHTHAS; ZEOLITES; ZINC;

HYDROTHERMAL SYNTHESIS;

EID: 64249136640     PISSN: 08870624     EISSN: None     Source Type: Journal    
DOI: 10.1021/ef800681e     Document Type: Article

References (28)

1. Treacy, M. M. J.; Newsam, J. M. Two new three-dimensional twelvering zeolite frameworks of which zeolite beta is a disordered intergrowth. Nature 1988, 332, 249-251.
2. Higgins, J. B.; LaPierre, R. B.; Schlenker, J. L.; Rohrman, A. C.; Wood, J. D.; Kerr, G. T.; Rohrbaugh, W. J. The framework topology of zeolite beta. Zeolites 1988, 8 (5), 446-452.
3. Camblor, M. A.; Corma, A.; Martinez, A.; Perez-Pariente, J. Synthesis of a titaniumsilicoaluminate isomorphous to zeolite beta and its application as a catalyst for the selective oxidation of large organic molecules. J. Chem. Soc. Chem. Commun. 1992, 589-590.
4. Murrell, L. L.; Overbeek, R. A.; Method for making molecular sieves and novel molecular sieves compositions. US Patent 6004527, 1999.
5. Takewaki, T.; Hwang, S. H.; Yamashita, H.; Davis, M. E. Synthesis of *BEA-type molecular sieves using mesoporous materials as reagents. Microporous Mesoporous Mater. 1999, 32 (3), 265-278.
6. Boretto, L.; Camblor, M. A.; Corma, A.; Perez-Pariente, J. Optimization of zeolite-β in cracking catalysts influence of crystallite size. Appl. Catal., A 199282, (1), 37-50.
7. Kiricsi, I.; Flego, C.; Pazzuconi, G.; Parker, W. O.; Millini, R.; Perego, C.; Bellussi, G. Progress toward understanding zeolite acidity: An IR and 27Al NMR spectroscopic study. J. Phys. Chem. 1994, 98, 4627-4634.
8. Taylor, R. J.; Petty, R. H. Selective hydroisomerization of long chain normal paraffins. Appl. Catal., A 1994, 119 (1), 121-138.
9. Corma, A.; Martinez, A.; Arroyo, P. A.; Monteiro, J. L. F.; Sousa-Aguiar, E. F. Isobutane/2-butene alkylation on zeolite beta: Influence of post-synthesis treatments. Appl. Catal., A 1996, 142 (1), 139-150.
10. Hari, Prasad; Rao, H. P. R.; Ueyama, K.; Matsukata, M. Crystallization of high silica BEA by dry gel conversion. Appl. Catal., A 1998, 166 (1), 97-103.
11. Xia, Q. H.; Chen, X.; Tatsum, T. Epoxidation of cyclic alkenes with hydrogen peroxide and tert-butyl hydroperoxide on Na-containing Tiβ zeolites. J. Mol. Catal. A: General 2001, 176 (1-2), 179-193.
12. Derouane, E. G.; Hutchings, G. J.; Mbafor, W. F.; Roberts, S. M. Titanium-substituted zeolite beta: An efficient catalyst in the oxy-fictionalisation of cyclic alkenes using hydrogen peroxide in organic solvents. New J. Chem. 1998, 22 (8), 797-799.
13. Wadlinger, R. L.; Kerr, G. T.; Rosinski, E. J. Catalytic composition of a crystalline zeolite. US patent 3308069, 1967.
14. Caullet, P.; Hazm, J.; Guth, J. L.; Joly, J. F.; Lynch, J.; Raatz, F. Synthesis of zeolite Beta from nonalkaline fluoride aqueous aluminosilicate gels. Zeolites 1992, 12 (3), 240-250.
15. Camblor, M. A.; Corma, A.; Valencia, S. Synthesis in fluoride media and characterisation of aluminosilicate zeolite beta. J. Mater. Chem. 1998, 8, 2137-2145.
16. Prasad Rao, P. R. H.; Leon y Leon, C. A.; Ueyama, K.; Matsukata, M. Synthesis of BEA by dry gel conversion and its characterization. Microporous Mesoporous Mater. 1998, 21 (4-6), 305-313.
17. Liu, Y.; Pinnavaia, T. J. Assembly of hydrothermally stable aluminosilicate foams and large-pore hexagonal mesostructures from zeolite seeds under strongly acidic conditions. Chem. Mater. (Commun.) 2002, 14 (1), 3-5.
18. Groen, J. C.; Abello, S.; Villaescusa, L. A.; Pérez- Ramírez, J. Mesoporous beta zeolite obtained by desilication. Microporous Mesoporous Mater. 2008, 114, 93-102.
19. Aguado, J.; Serrano, D. P.; Rodríguez, J. M. Zeolite Beta with hierarchical porosity prepared from organofunctionalized seeds. Microporous Mesoporous Mater. 2008, 115, 504-513.
20. Chandrasekhar, S.; Raghavan, P.; Sebastian, G.; Damodaran, A. D. Brightness improvement studies on "kaolin based" zeolite 4A. Appl. Clay Sci. 199712, (3), 221-231.
21. Akolekar, D.; Chaffee, A.; Howe, R. F. The transformation of kaolin to low-silica X zeolite. Zeolites 1997, 19 (5-6), 359-365.
22. Peng, W.; Shen, B.; Shen, D.; Peng, T.; Gao, J. Synthesis of ZSM-5 zeolite from expanded perlite/kaolin and its catalytic performance for FCC naphtha aromatization. Catal. Commun. 2007, 8 (10), 1452-1456.
23. Liu, H.; Zhao, H.; Gao, X.; Ma, J. A novel FCC catalyst synthesized via in situ overgrowth of NaY zeolite on kaolin microspheres for maximizing propylene yield. Catal. Today 2007, 125 (3-4), 163-168.
24. You, H.; Xu, C.; Gao, J.; Liu, Z.; Yan, P. Nine lumped kinetic models of FCC gasoline under the aromatization reaction conditions. Catal. Commun. 2006, 7 (8), 554-558.
25. Osako, K.; Nakashiro, K.; Ono, Y. The role of zinc cations in the conversion of isobutane into aromatic over mechanical mixtures of ZnO and H-ZSM-5. Bull. Chem. Soc. Jpn. 1993, 66, 755-759.
26. Nash, R. J.; Dry, M. E.; O'Connor, C. T. Aromatization of 1-hexane and 1-octene by Gallium/H-ZSM-5 catalysts. Appl. Catal., A 1996, 134 (2), 285-297.
27. Xu, R.; Pang, W.; Yu, J.; Huo, Q.; Chen, J. Chemistry-Zeolites and Porous Materials; China Sciences Press: Beijing, 2004, pp 73-75.
28. 3 supported Pt for reforming reactions. J. Catal. 1993, 140 (2), 526-542.