An EPR study of the V(IV) species formed upon activation of a vanadyl phenoxyimine polymerization catalyst with AlR3 and AlR2Cl (R = Me, Et)

Macromolecular Chemistry and Physics

Volumn 210, Issue 7, 2009, Pages 542-548

  Soshnikov, Igor E ^a,b   Semikolenova, Nina V ^a   Bryliakov, Konstantin P ^a,b   Shubin, Alexander A ^a,b   Zakharov, Vladimir A ^a   Redshaw, Carl ^c   Talsi, Evgenii P ^a,b  

^a BORESKOV INSTITUTE OF CATALYSIS   (Russian Federation)

^b NOVOSIBIRSK STATE UNIVERSITY   (Russian Federation)

^c UNIVERSITY OF EAST ANGLIA   (United Kingdom)

Author keywords

Active species; EPR; Olefin polymerization; Vanadium catalysts

Indexed keywords

ACTIVE SPECIES; CONCENTRATION OF; EPR; EPR STUDIES; OLEFIN POLYMERIZATION; PHENOXY IMINES; POLYMERIZATION ACTIVITIES; POLYMERIZATION CATALYSTS; REACTION SOLUTIONS; VANADIUM CATALYSTS; VANADYL;

CATALYSIS; CATALYSTS; ELECTRON RESONANCE; ELECTRON SPIN RESONANCE SPECTROSCOPY; ETHYLENE; LIGANDS; MONOMERS; PARAMAGNETIC RESONANCE; POLYMERIZATION; POLYMERS; QUANTUM THEORY; TRANSITION METALS; VANADIUM ALLOYS;

VANADIUM COMPOUNDS;

EID: 63849122504     PISSN: 10221352     EISSN: 15213935     Source Type: Journal    
DOI: 10.1002/macp.200800556     Document Type: Article

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