High-pressure thermolysis of sulfate turpentine

Journal of Supercritical Fluids

Volumn 48, Issue 2, 2009, Pages 139-145

  Yermakova, A ^a   Chibiryaev, A M ^b,c   Kozhevnikov, I V ^a   Anikeev, V I ^a  

^a BORESKOV INSTITUTE OF CATALYSIS   (Russian Federation)

^b N N VOROZHTSOV NOVOSIBIRSK INSTITUTE OF ORGANIC CHEMISTRY   (Russian Federation)

^c NOVOSIBIRSK STATE UNIVERSITY   (Russian Federation)

Author keywords

High pressure; Isomerization; Kinetics; Sulfate turpentine; Supercritical solvent; Thermodynamic; Thermolysis; Transition state theory

Indexed keywords

ELECTRON TRANSITIONS; ETHANOL; ISOMERIZATION; ISOMERS; THERMODYNAMICS; THERMOLYSIS;

DILUTED SOLUTIONS; HIGH-PRESSURE; PRESSURE RANGES; REVERSIBLE REACTIONS; SULFATE TURPENTINE; SUPER-CRITICAL; SUPERCRITICAL ETHANOLS; SUPERCRITICAL SOLVENT; THERMODYNAMIC PARAMETERS; TRANSITION STATE THEORY; WORKING MEDIUMS;

TURPENTINE;

EID: 63749131467     PISSN: 08968446     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.supflu.2008.10.013     Document Type: Article

References (26)

1. Dorsky J. The chemistry of synthetic raw materials production. In: Müller P.M., and Lamparsky D. (Eds). Perfumes: Art, Science, Technology (1991), Elsevier Applied Science, London, New York 399-420
2. Brylyakov Yu.E., Gorlovskii S.I., and Shadrin A.B. Dispersing action of flotation agents at the gas-liquid interface. Kompleksn. Ispol'z. Miner. Syr'ya 2 (1988) 21-24 (Chem. Abstr., 1988, 109, 25653)
3. Sun J.-H., and Zeng T. Study on one-step preparation of frother for mineral flotation from crude sulfate turpentine. Linchan Huaxue Yu Gongye (Chem. Ind. Forest Products) 25 Suppl. (2005) 43-46
4. Summers H.B., Hedrick G.W., Magne F.C., and Mayne R.Y. PVC plasticizers from turpentine. Ind. Eng. Chem. 51 (1959) 549-550
5. Johansson A. By-product recovery and valorization in the kraft industry: a review of current trends in the recovery and use of turpentine and tall oil derivatives. Biomass 2 (1982) 103-113
6. Yumrutaşa R., Alma M.H., Özcan H., and Kaşka O. Investigation of purified sulfate turpentine on engine performance and exhaust emission. Fuel 87 (2008) 252-259
7. Afre R.A., Soga T., Jimbo T., Kumar M., Ando Y., Sharon M., Somani P.R., and Umeno M. Carbon nanotubes by spray pyrolysis of turpentine oil at different temperatures and their studies. Micropor. Mesopor. Mater. 96 (2006) 184-190
8. Radbil A.B. The lines of qualified use of turpentine. Chem. Vegetable Feedstock 1 (2005) 5-11
9. Chibiryaev A.M., Anikeev V.I., Yermakova A., Mikenin P.E., Kozhevnikov I.V., and Salnikova O.I. Thermolysis of α-pinene in supercritical lower alcohols. Russ. Chem. Bull. Int. Ed. 55 (2006) 987-992
10. Anikeev V.I., Yermakova A., Chibiryaev A.M., Kozhevnikov I.V., and Mikenin P.E. The thermal isomerization of terpene compounds in supercritical alcohols. Russ. J. Phys. Chem. 81 (2007) 711-716
11. Yermakova A., Chibiryaev A.M., Kozhevnikov I.V., Mikenin P.E., and Anikeev V.I. Thermal isomerization of α-pinene in supercritical ethanol. Chem. Eng. Sci. 62 (2007) 2414-2421
12. Chibiryaev A.M., Yermakova A., Kozhevnikov I.V., Salnikova O.I., and Anikeev V.I. Comparative thermolysis of β-and α-pinenes in supercritical ethanol: the reaction characterization and enantiomeric ratios of products. Russ. Chem. Bull. Int. Ed. 56 (2007) 1234-1238
13. Yermakova A., Chibiryaev A.M., Mikenin P.E., Sal'nikova O.I., and Anikeev V.I. The influence of water on the isomerization of α-pinene in a supercritical aqueous-alcoholic solvent. Russ. J. Phys. Chem. 82 (2008) 62-67
14. Anikeev V.I., Yermakova A., and Goto M. Decomposition and oxidation of aliphatic nitrocompounds in supercritical water. Indus. Eng. Chem. Res. 43 (2004) 8141-8147
15. Joback K.G., and Reid R.C. Estimation of pure-component properties from group-contributions. Chem. Eng. Commun. 57 (1987) 233-243
16. Pines H., and Ryer J. Studies in the terpene series, XXIII. Pyrolysis of d-limonene and of related hydrocarbons. Mechanism of pyrolysis. J. Am. Chem. Soc. 77 (1955) 4370-4375
17. Cocker W., Hanna D.P., and Shannon P.V.R. The chemistry of terpenes, VI. Pyrolysis and acid-catalyzed rearrangements of (+)-car-3-ene and some derivatives. J. Chem. Soc. (C) 5 (1968) 489-495
18. Shimazu K., Hattori H., and Tanabe K. Isomerization of 3-carene over MgO and CaO. J. Catal. 48 (1977) 302-311
19. Lesage P., Candy J.-P., Hirigoyen C., Humblot F., Leconte M., and Basset J.-M. An example of the valorization of terpenes: the selective isomerization of 3-carene to 2-carene in the presence of silica supported nickel catalysts modified by tetrabutyl tin. J. Mol. Catal. A: Chem. 112 (1996) 303-309
20. Meyer U., and Hoelderich W.F. Application of basic zeolites in the decomposition reaction of 2-methyl-3-butyn-2-ol and the isomerization of 3-carene. J. Mol. Catal. A: Chem. 142 (1999) 213-222
21. Carey F., and Sundberg R. Advanced Organic Chemistry. Part A. Structure and Mechanisms. 4th ed. (2000), Kluwer Academic/Plenum Publishers, New York-Boston-Dordrecht-London-Moscow 836 pp
22. Anikeev V.I., and Yermakova A. Density effect of supercritical water on the rate constant of isopropyl alcohol dehydration. J. Phys. Chem. 77 2 (2003) 265-268
23. Baliga B.T., and Whalley E. Effect of pressure and temperature on the rate the acid-catalyzed hydration of ethylene. Can. J. Chem. 9 (1965) 2453-2456
24. Narayan R., and Antal M.J. Influence of pressure on the acid-catalyzed rate constant for 1-propanol dehydration in supercritical water. J. Am. Chem. Soc. 112 (1990) 1927-1931
25. Akiya N., and Savage P.E. Effect of water density on hydrogen peroxide dissociation in supercritical water. 2. Reaction kinetics. J. Phys. Chem. A 104 (2000) 4441-4448
26. Sandler S.I. Chemical, Biochemical and Engineering Thermodynamics. 4th ed. (2006), John Willey & Sons, Inc., New York 960 p