Multinuclear NMR study of the structure and micro-dynamics of counterions and water molecules within clay colloids

Current Opinion in Colloid and Interface Science

Volumn 14, Issue 3, 2009, Pages 216-222

  Porion, Patrice ^a   Delville, Alfred ^a  

^a UNIVERSITÉ D'ORLÉANS   (France)

Author keywords

Clay; Colloids; Diffusion; NMR; Quadrupolar nuclei; Relaxometry

Indexed keywords

ANISOTROPIC CLAYS; BASAL SURFACES; CLAY COLLOIDS; CLAY PARTICLES; COLLOIDAL DISPERSIONS; COUNTER-IONS; DIFFUSION MEASUREMENTS; IONIC MOBILITIES; MICRO-DYNAMICS; MULTI-NUCLEAR NMR; MULTI-SCALE; MULTINUCLEAR NMR SPECTROSCOPIES; NMR; NMR RELAXATIONS; NUMERICAL MODELING; QUADRUPOLAR NUCLEI; RELAXOMETRY; WATER MOLECULES;

COLLOID CHEMISTRY; DIFFUSION; IONIZATION OF LIQUIDS; MOLECULES; NUCLEAR MAGNETIC RESONANCE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SURFACE DIFFUSION; SURFACE RELAXATION;

CLAY MINERALS;

COUNTERION; WATER;

CHEMICAL STRUCTURE; COLLOID; DIFFUSION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; REVIEW;

EID: 63749114833     PISSN: 13590294     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cocis.2008.08.002     Document Type: Review

References (43)

1. Woessner D.E., and Snowden B.S. NMR doublet splitting in aqueous Montmorillonite gels. J Chem Phys 50 (1969) 1516-1523
2. Woessner D.E., Snowden B.S., and Meyer G.H. A tetrahedral model for pulsed Nuclear Magnetic Resonance transverse relaxation: application to the clay-water system. J Colloid Interface Sci 34 (1970) 43-52
3. 2+ exchanged Montmorillonite. J Chem Soc Faraday Trans I 80 (1984) 309-324
4. Delville A., Grandjean J., and Laszlo P. Order acquisition by clay platelets in a magnetic field. NMR study of the structure and microdynamics of the adsorbed water layer. J Phys Chem 95 (1991) 1383-1392
5. Delville A., and Letellier M. Structure and dynamics of simple liquids in heterogeneous condition - an NMR study of the clay water interface. Langmuir 11 (1995) 1361-1367
6. Levitz P. Random flights in confining interfacial systems. J Phys Condens Matter 17 (2005) S4059-S4074
7. Skipper N.T., Williams G.D., de Siqueira A.V.C., Lobban C., and Soper A. Time-of-flight neutron diffraction studies of clay-fluid interactions under basin conditions. Clay Miner 35 (2000) 283-290
8. Swenson J., Bergman R., and Howells W.S. Quasielastic neutron scattering of two-dimensional water in a vermiculite clay. J Chem Phys 113 (2000) 2873-2879
9. Swenson J., Bergman R., and Longeville S. A neutron spin-echo study of confined water. J Chem Phys 115 (2001) 11299-11305
10. Porion P., Rodts S., Al-Mukhtar M., Faugère A.M., and Delville A. Anisotropy of the solvent self-diffusion tensor as a probe of nematic ordering within dispersion of nano-composite. Phys Rev Lett 87 (2001) 208302
11. 1H pulsed gradient spin-echo NMR measurements. J Phys Chem B 107 (2003) 4012-4023
12. Malikova N., Cadène A., Marry V., Dubois E., and Turq P. Diffusion of water in clays on the microscopic scale: modeling and experiment. J Phys Chem B 110 (2006) 3206-3214
13. Takahashi T., Ohkubo T., and Ikeda Y. Montmorillonite alignment induced by magnetic field: evidence based on the diffusion anisotropy of water molecules. J Colloid Interface Sci 299 (2006) 198-203
14. 1H NMR spectroscopy. J Phys Chem B 110 (2006) 7813-7819
15. de Azevedo E.N., Engelsberg M., Fossum J.O., and de Souza R.E. Anisotropic water diffusion in nematic self-assemblies of clay nanoplatelets suspended in water. Langmuir 23 (2007) 5100-5105
16. Michot L.J., Delville A., Humbert B., Plazanet M., and Levitz P. Diffusion of water in a synthetic clay with tetrahedral charges by combined neutron time-of-flight measurements and molecular dynamics simulations. J Phys Chem C 111 (2007) 9818-9831
17. Sur S.K., Heinsbergen J.F., and Bryant R.G. Nuclear magnetic relaxation dispersion studies on bentonite clay suspensions. J Magn Reson A 103 (1993) 8-12
18. 23Na Nuclear quadripolar relaxation as a probe of the microstructure and dynamics of aqueous clay dispersions: an application to Laponite gels. J Phys Chem B 102 (1998) 3477-3485
19. 1H Pulsed Gradient Spin-Echo detection of the critical concentration corresponding to the isotrope/nematic transition within aqueous dispersions of charged anisotropic nanoparticles. J Phys Chem B 108 (2004) 10825-10831
20. 23Na Nuclear Magnetic Resonance spectroscopy. J Phys Chem B 109 (2005) 20145-20154
21. Delville A., Porion P., and Faugère A.M. Ion diffusion within charged porous network as probed by nuclear quadrupolar relaxation. J Phys Chem B 104 (2000) 1546-1551
22. 23Na Nuclear Quadrupolar Spectroscopy. J Phys Chem B 105 (2001) 10505-10514
23. Nakashima Y. Nuclear magnetic resonance properties of water-rich gels of Kunigel-V1 bentonite. J Nucl Sci Technol 41 (2004) 981-992
24. 2O layers: PGSE NMR study of water-rich saponite gels. Appl Clay Sci 28 (2005) 209-221
25. 2O self-diffusion coefficient of water-rich MX-80 bentonite gels. Clay Miner 41 (2006) 659-668
26. Mourchid A., Delville A., Lambard J., Lécolier E., and Levitz P. Phase diagram of colloidal dispersions of anisotropic charged particles: equilibrium properties, structure, and rheology of Laponite suspensions. Langmuir 11 (1995) 1942-1950
27. Michot L.J., Bihannic I., Maddi S., Funari S.S., Baravian C., Levitz P., et al. Liquid-crystalline aqueous clay suspensions. Proc Natl Acad Sci USA 103 (2006) 16101-16104
28. Onsager L. The effects of shape on the interaction of colloidal particles. Ann N Y Acad Sci 51 (1949) 627-659
29. Forsyth P.A., Marcelja S., Mitchell D.J., and Ninham B.W. Ordering in colloidal systems. Adv Colloid Interface Sci 9 (1978) 37-60
30. Eppenga R., and Frenkel D. Monte-Carlo study of the isotropic and nematic phases of infinitely thin hard platelets. Mol Phys 52 (1984) 1303-1334
31. Meyer S., Levitz P., and Delville A. Influence of the relative orientation of two charged anisotropic colloidal particles on their electrostatic coupling: a (N,V,T) Monte Carlo study. J Phys Chem B 105 (2001) 10684-10690
32. Petit D., Korb J.P., Delville A., Grandjean J., and Laszlo P. Theory of nuclear spin relaxation in heterogeneous media and application to the cross correlation between quadrupolar and dipolar fluctuations of deuterons in clay gels. J Magn Reson 96 (1992) 252-279
33. Balnois E., Durand-Vidal S., and Levitz P. Probing the morphology of Laponite clay colloids by atomic force microscopy. Langmuir 19 (2003) 6633-6637
34. Kimmich R. NMR: tomography, diffusometry, relaxometry (1997), Springer-Verlag, Berlin
35. Abragam A. The principles of nuclear magnetism (1961), Clarendon Press, Oxford
36. 23Na NMR investigation. Biophys Chemist 24 (1986) 121-133
37. 133Cs spin relaxation in macroscopically oriented Li-DNA and Cs-DNA fibers. J Magn Reson 93 (1991) 34-46
38. van der Maarel J.R.C. Thermal relaxation and coherence dynamics of spin 3/2. I. Static and fluctuating quadrupolar interactions in the multipole basis. Concepts Magn Reson Part A 19A (2003) 97-116
39. Barbara T.M., Vold R.R., and Vold R.L. A determination of individual spectral densities in a smectic liquid-crystal from angle dependent nuclear spin relaxation measurements. J Chem Phys 79 (1983) 6338-6340
40. + cations: an application to dense clay sediments. J Phys Chem C 112 (2008) 9808-9821
41. Harris R.K., and Mann B.E. NMR and the periodic table (1978), Academic Press, London
42. 2H NMR spectroscopy and multiscale numerical modeling. J Phys Chem C 111 (2007) 5441-5453
43. 2H NMR analysis using spin-locking relaxation rates. J Phys Chem C 111 (2007) 13117-13128