Determination of kinetic and diffusional parameters for sodium borohydride oxidation on gold electrodes

Journal of the Electrochemical Society

Volumn 156, Issue 5, 2009, Pages

  Santos, D M F ^a   Sequeira, C A C ^a  

^a INSTITUTO SUPERIOR TÉCNICO   (Portugal)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ANALYSIS; ARRHENIUS PLOTS; CHARGE TRANSFER; DIFFUSION; ELECTROCHEMICAL OXIDATION; ELECTROCHEMISTRY; FUEL CELLS; ION EXCHANGE; RATE CONSTANTS; SODIUM;

BOROHYDRIDE; CELL TYPES; CHRONOCOULOMETRIC MEASUREMENTS; CURRENT RESPONSE; CURRENT TRANSIENTS; DIFFUSION ACTIVATION ENERGIES; DIFFUSION COEFFICIENTS; DIFFUSIONAL PARAMETERS; DISK ELECTRODES; ELECTRON TRANSFERS; EXCHANGE CURRENT DENSITIES; GOLD ELECTRODES; INFINITE MASS; KINETIC RATE CONSTANTS; MIXED CONTROLS; POTENTIAL STEP EXPERIMENTS; RESEARCH AND DEVELOPMENT; SODIUM BOROHYDRIDE; STANDARD RATE CONSTANTS; TAFEL PLOTS; TIME-SCALE; TRANSFER COEFFICIENTS;

ACTIVATION ENERGY;

EID: 63649102245     PISSN: 00134651     EISSN: None     Source Type: Journal    
DOI: 10.1149/1.3082371     Document Type: Article

References (30)

1. C. Kim, K. J. Kim, and M. Y. Ha, J. Power Sources, 180, 154 (2008).
2. B. H. Liu, Z. P. Li, and S. Suda, Electrochim. Acta, 49, 3097 (2004).
3. L. Wang, C. Ma, and X. Mao, J. Alloys Compd., 397, 313 (2005).
4. S. C. Amendola, P. Onnerud, M. T. Kelly, P. J. Petillo, S. L. Sharp-Goldman, and M. Binder, J. Power Sources, 84, 130 (1999).
5. H. Cheng and K. Scott, Electrochim. Acta, 51, 3429 (2006).
6. R. K. Raman and A. K. Shukla, Fuel Cells, 7, 225 (2007).
7. B. H. Liu, Z. P. Li, and S. Suda, J. Power Sources, 185, 1257 (2008).
8. N. Luo, G. H. Miley, K. J. Kim, R. Burton, and X. Huang, J. Power Sources, 185, 685 (2008).
9. A. J. Bard and L. R. Faulkner, Electrochemical Methods, Fundamentals and Applications, 2nd ed., John Wiley & Sons, Inc., Hoboken, NJ (2001).
10. C. G. Zoski, Editor, Handbook of Electrochemistry, Elsevier, Amsterdam (2007).
11. P. A. Christensen and A. Hamnett, Techniques and Mechanisms in Electrochemistry, Blackie, Edinburgh (1995).
12. M. H. Atwan, C. L. B. Macdonald, D. O. Northwood, and E. L. Gyenge, J. Power Sources, 158, 36 (2006).
13. G. Denuault, M. V. Mirkin, and A. J. Bard, J. Electroanal. Chem. Interfacial Electrochem., 308, 27 (1991).
14. P. Krishnan, T. H. Yang, S. G. Advani, and A. K. Prasad, J. Power Sources, 182, 106 (2008).
15. R. Jamard, A. Latour, J. Salomon, P. Capron, and A. Martinent-Beaumont, J. Power Sources, 176, 287 (2008).
16. E. Gyenge, Electrochim. Acta, 49, 965 (2004).
17. K. Wang, J. Lu, and L. Zhuang, J. Electroanal. Chem., 585, 191 (2005).
18. M. Chatenet, F. Micoud, I. Roche, and E. Chainet, Electrochim. Acta, 51, 5459 (2006).
19. M. H. Atwan, D. O. Northwood, and E. L. Gyenge, Int. J. Hydrogen Energy, 32, 3116 (2007).
20. H. Dong, R. Feng, X. Ai, Y. Cao, H. Yang, and C. Cha, J. Phys. Chem. B, 109, 10896 (2005).
21. E. Gyenge, M. Atwan, and D. Northwood, J. Electrochem. Soc., 153, A150 (2006).
22. C. Ponce de Leon, F. C. Walsh, D. Pletcher, D. J. Browning, and J. B. Lakeman, J. Power Sources, 155, 172 (2006).
23. B. M. Concha, M. Chatenet, C. Coutanceau, and F. Hahn, Electrochem. Commun., 11, 223 (2009).
24. G. Rostamikia and M. J. Janik, J. Electrochem. Soc., 156, B86 (2008).
25. F. A. Coowar, G. Vitins, G. O. Mepsted, S. C. Waring, and J. A. Horsfall, J. Power Sources, 175, 317 (2008).
26. B. H. Liu, Z. P. Li, and S. Suda, J. Electrochem. Soc., 150, A398 (2003).
27. F. G. Cottrell, Z. Phys. Chem., Stoechiom. Verwandtschaftsl., 42, 385 (1902).
28. K. Wang, K. Jiang, J. Lu, L. Zhuang, C. Cha, X. Hu, and G. Z. Chen, J. Power Sources, 185, 892 (2008).
29. M. V. Mirkin, H. Yang, and A. J. Bard, J. Electrochem. Soc., 139, 2212 (1992).
30. J. A. Gardiner and J. W. Collat, Inorg. Chem., 4, 1208 (1965).