REE and HFS element behaviour in the alteration facies of the Erenler Daǧi{dotless} Volcanics (Konya, Turkey) and kaolinite occurrence

Journal of Geochemical Exploration

Volumn 101, Issue 2, 2009, Pages 185-208

  Karakaya, Necati ^a  

^a Selçuk Üniveristesi Müh Mim Fak Jeoloji Müh Bölümü   (Turkey)

Author keywords

HFSE; Hydrothermal alteration; Kaolinite; Konya; REE; Turkey

Indexed keywords

HFSE; HYDROTHERMAL ALTERATION; KONYA; REE; TURKEY;

CALCIUM; EUROPIUM; GEOCHEMISTRY; HAFNIUM; KAOLINITE; NIOBIUM; ROCKS; SILICA; SILICATE MINERALS; SULFATE MINERALS; TRACE ELEMENTS; VOLCANOES; ZIRCONIUM;

VOLCANIC ROCKS;

CALC ALKALINE ROCK; CHEMICAL COMPOSITION; HYDROTHERMAL ALTERATION; IGNEOUS GEOCHEMISTRY; KAOLINITE; MIOCENE; PLIOCENE; RARE EARTH ELEMENT; TREND ANALYSIS; VOLCANIC ROCK;

EURASIA; KONYA [TURKEY]; TURKEY;

EID: 63549084942     PISSN: 03756742     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.gexplo.2008.07.001     Document Type: Article

References (46)

1. Arribas Jr. A., Cunningham C.G., Rytuba J.J., Rye R.O., Kelly W.C., Podwisocki M.H., McKee E.H., and Tosdal R.M. Geology, geochronology, fluid inclusions, and isotope geochemistry of the Rodalquilar gold alunite deposit. Spain. Econ. Geol. 90 (1995) 795-822
2. Bau M. Rare-earth element mobility during hydrothermal and metamorphic fluid-rock interaction and the significance of the oxidation state of europium. Chem. Geol. 93 (1991) 219-230
3. Boynton W.V. Geochemistry of rare earth elements: meteorite studies. In: Henderson P. (Ed). Rare Earth Element Geochemistry (1984), Elsevier 63-114
4. Braun J.-J., Pagel M., Muller J.-P., Bilong P., Michard A., and Guillet B. Cerium anomalies in lateritic profiles. Geochemica et Cosmochemica Acta 54/3 (1990) 781-795
5. Çelik M. Minamiite and alunite occurrences formed from volcanic emanations, west-southwest of Konya. Türkiye Jeoloji Mühendisleri Dergisi 42/2 (1999) 89-99
6. Çelik M., Temel A., Orhan O., and Tunoǧlu C. Economic importance of clay and aluminum sulphate occurrences in west-southwest of Konya, Turkey. Turk. J. Eart. Sci. 6/2 (1997) 85-94
7. Class C., and la Roex A.P. Ce anomalies in Gough Island lavas-trace element characteristics of a recycled sediment component. Earth Planet. Sci. Lett. 265 (2008) 475-486
8. Ece Ö.I., and Nakagawa Z. Alteration of volcanic rocks and genesis of kaolin deposits in Şile Region, Northern Istanbul, Turkey. II: differential mobility of elements. Clay Miner. 38 (2003) 529-550
9. Fulignati P., Gioncada A., and Sbrana A. Rare-element (REE) behaviour in the alteration facies of the active magmatic-hydrothermal system of Vulcano (Aeolian Islands, Italy). J. Volcanol. Geotherm. Res. 88 (1999) 325-342
10. Hayashi T., Tanimizu M., and Tanaka T. Origin of negative Ce anomalies in Barberton sedimentary rocks, deduced from La-Ce and Sm-Nd isotope systematics. Precambrian Res. 135 (2004) 345-357
11. Hedenquist J.W. The ascent of magmatic fluid: discharge versus mineralization. In: Thompson J.F.H. (Ed). Magmas, Fluids and Ore Deposits. Mineralogical Association of Canada, Short Course vol. 23 (1995) 263-289
12. Hopf S. Behaviour of rare earth elements in geothermal systems of New Zealand. J. Geochem. Explor. 47 (1993) 333-357
13. Hynes A. Carbonatization and mobility of Ti, Y and Zr in Ascot Formation metabasalts, SE Quebec. Contrib. Mineral. Petrol. 75 (1980) 79-87
14. Jenner G.A. Trace element geochemistry of igneous rocks: geochemical nomenclature and analytical geochemistry. In: Wyman D.A. (Ed). Trace element geochemistry of volcanic rocks: Applications for massive sulfide exploration. Geological Association of Canada Short Course Notes vol. 12 (1996) 51-77
15. Jiang S.-Y. Controls on the mobility of high field strength elements (HFSE), U, and Th in an ancient submarine hydrothermal system of the Proterozoic Sullivan Pb-Zn-Ag deposit, British Columbia, Canada. Geochem. J. 34 (2000) 341-348
16. Jiang N., Sun S., Chu X., Mizuta T., and Ishiyama D. Mobilization and enrichment of high-field strength elements during late- and post-magmatic processes in the Shuiquangou syenitic complex, Northern China. Chem. Geol. 200 (2003) 117-128
17. Jiang S.Y., Wang R.C., Xu X.S., and Zhao K.D. Mobility of high field strength elements (HFSE) in magmatic-, metamorphic-, and submarine-hydrothermal systems. Phys. Chem. Earth 30 (2005) 1020-1029
18. Kamineni D.C. Distribution of uranium, thorium and rare earth elements in the Eye-Dashwa Lakes pluton - a study of some analogue elements. Chem. Geol. 55 (1986) 61-373
19. Karakaya M.Ç., Karakaya N., and Temel A. Kaolin occurrences in Erenler Daǧi{dotless} volcanics, southwest Konya Province, Turkey. Int. Geol. Rev. 43/8 (2001) 711-722
20. Keller J., Jung D., Burgath K., and Wolf F. Geologie und petrologie des Neogenen kalkalkali-vulkanismus von Konya (Erenler Daǧ-Alaca Daǧ-Massiv Zentral-Anatolian). Geo. Jb. B 25 (1977) 37-117
21. Klinkhammer G.P., Elderfield H., Edmond J.M., and Mitra A. Geochemical implications of rare earth element patterns in hydrothermal fluids from mid-ocean ridges. Geochem. Cosmochem. Acta 58 (1994) 5105-5113
22. Knight J.E. A thermochemical study of alunite, enargite, luzonite and tennantite deposits. Econ. Geol. 72 (1977) 1321-1336
23. MacLean W.H. Rare earth element mobility at constant inter-REE ratios in the alteration zone at the Phelps Dodge massive sulphide deposit, Matagami, Quebec. Miner. Depos. 23 (1988) 231-238
24. MacLean W.H. Mass change calculations in altered rock series. Miner. Depos. (1990) 44-49
25. MacLean W.H., and Kranidiotis P. Immobile elements as monitors of mass transfer in hydrothermal alteration. Phelps Dodge massive sulphide deposits, Matagami, Quebec. Econ. Geol. 82 (1987) 951-962
26. Murphy J.B., and Hynes A. Contrasting secondary mobility of Ti, P, Zr, Nb and Y in two metabasaltic suites in the Appalachians. Can. J. Earth Sci. 23 (1986) 1138-1144
27. Nesbitt H.W., and Markovics G. Weathering of granidioritic crust, long-term storage of elements in weathering profiles, and petrogenesis of siliciclastic sediments. Geochim. Cosmochim. Acta 61 (1997) 1653-1670
28. Nesbitt H.W., and Young G.M. Early Paleozoic climates and plate motions inferred from major element chemistry of lutites. Nature 229 (1982) 715-717
29. Nesbitt H.W., and Young G.M. Prediction of some weathering trends of plutonic and volcanic rocks based on thermodynamic and kinetic considerations. Geochim. Cosmochim. Acta 48 (1984) 1523-1534
30. Palacios C.M., Hein U.F., and Dulski P. Behaviour of rare earth elements during hydrothermal alteration at the Buena Esperanza copper-silver deposit, northern Chile. Earth Planet. Sci. Lett. 80 (1986) 208-216
31. Parr J.M. Rare-earth element distribution in exhalites associated with Broken Hills-type mineralization at the Pinnacles deposit, New South Wales, Australia. Chem. Geol. 100 (1992) 73-91
32. Patino L.C., Velbel M.A., Price J.R., and Wade J.A. Trace element mobility during spheroidal weathering of basalts and andesites in Hawaii and Guatemala. Chem. Geol. 202 (2003) 343-364
33. Rollinson H. Using geochemical data; evaluation, presentation, interpretation (1993), Longman Scientific and Technical, Harlow UK 352 pp.
34. Salvi S., and Williams-Jones A.E. The role of hydrothermal processes in concentrating high-field strength elements in the Strange Lake peralkaline complex, north-eastern Canada. Geochim. Cosmochim. Acta 60 (1996) 1917-1932
35. Salvi S., Fontan F., Monchoux P., Williams-Jones A., and Eand Moine B. Hydrothermal mobilization of high field strength elements in alkaline igneous systems: evidence from the Tamazeght Complex (Morocco). Econ. Geol. 95 (2000) 559-576
36. Saunders A.D., Tarney J., Marsh N.G., and Wood D.A. Ophiolites as ocean crust: a geochemical approach. In: Panayiotou A. (Ed). Ophiolites: Proceedings of the International Ophiolite Symposium, Cyprus 1979, Ministry of Agriculture and Natural Resources (1980), Geological Survey Department, Cyprus 193-204
37. Sun S.S., and McDonough W.F. Chemical and isotopic systematics of oceanic basalts: implications for mantle composition processes. In: Saunders A.D., and Norry M.J. (Eds). Magmatism in the Ocean Basins 42 (1989), Geological Society Special Publication 313-345
38. Schilling J.G. Iceland Mantle Plume: geochemical study of Reykjanes ridge. Nature 242 (1973) 565-571
39. Sverjensky D.A. Europium redox equilibrium in aqueous solution. Earth Planet. Sci. Lett. 67 (1984) 70-78
40. Temel A., Çelik M., and Tunoǧlu C. Konya bati{dotless}-güneybati{dotless}si{dotless}nda yer alan Neojen yaşli{dotless} volkanosedimanter basenindeki kil oluşumlari{dotless}. In: Şener M., Öner F., and ve Koşun E. (Eds). VII. Ulusal Kil Sempozyumu, Kil'95, Ankara, Bildiriler Kitabi{dotless} (1995) 32-45 (Turkish with English abstract)
41. Temel A., Gündoǧdu M.N., and Gourgaud A. Petrological and geochemical characteristics of Cenozoic high-K calc-alkaline volcanism in Konya, Central Anatolia, Turkey. J. Volcanol. Geotherm. Res. 85 (1998) 327-354
42. Torres-Alvarado I.S. Mineral chemistry of hydrothermal silicates in Los Azufres geothermal field, Mexico. World Geothermal Congress, Kyushu-Tohoku, Japan, Proceedings of the International Geothermal Association (2000) 1861-1866
43. Torres-Alvarado I.S. Chemical equilibrium in hydrothermal systems; the case of Los Azures geothermal field, Mexico. Int. Geol. Rev. 44 (2002) 639-652
44. Torres-Alvarado I.S., Pandarinath K., Verma S.P., and Dulski P. Mineralogical and geochemical effects due to hydrothermal alteration in the Los Azures geothermal field, Mexico. Rev. Mex. Cienc. Geol. 24/1 (2007) 15-24
45. Winchester J.A., and Floyd P.A. Geochemical discrimination of different magma series and their differentiation products using immobile elements. Chem. Geol. 20 (1977) 245-252
46. Wood S.A. The aqueous geochemistry of the rare earth elements and yttrium: 2. Theoretical prediction of speciation in hydrothermal solutions to 350 °C at saturation water vapour pressure. Chem. Geol. 88 (1990) 99-125