Synthesis and physico-chemical studies on 18-membered octaazamacrocyclic complexes of Mn(II), Co(II), Ni(II), Cu(II), and Zn(II) ions

Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry

Volumn 34, Issue 8, 2004, Pages 1305-1318

  Khan, Tahir Ali ^a   Tabassum, Shabana ^a   Azim, Yasser ^a   Shakir, Mohammad ^a  

^a ALIGARH MUSLIM UNIVERSITY   (India)

Author keywords

Octaazamacrocyclic complexes; Octahedral geometry; Spectroscopic studies; Template synthesis

Indexed keywords

ACETALDEHYDE; COBALT; COPPER; FORMALDEHYDE; HYDRAZINE; MACROCYCLIC COMPOUND; MANGANESE; NICKEL; PHTHALALDEHYDE; ZINC;

ARTICLE; CHEMICAL MODIFICATION; CONDUCTANCE; ELECTRON SPIN RESONANCE; GEOMETRY; INFRARED SPECTROSCOPY; MAGNETISM; MEASUREMENT; PHYSICAL CHEMISTRY; POLYMERIZATION; PROTON NUCLEAR MAGNETIC RESONANCE; STEREOCHEMISTRY; ULTRAVIOLET SPECTROSCOPY;

EID: 6344294936     PISSN: 00945714     EISSN: None     Source Type: Journal    
DOI: 10.1081/SIM-200026200     Document Type: Article

References (25)

1. Alexander, V. Design and synthesis of macrocyclic ligands and their complexes of lanthanides and actinides. Chem. Rev. 1995, 95 (2), 273-342.
2. Menon, S.C.; Panda, A.; Singh, H.B.; Butcher, R.J. Synthesis and single crystal x-ray structure of the first cationic Pd(II) complex of a tellurium containing polyaazamacrocycle contrasting reactions of Pd(II) and Pt(II) with 22-membered macrocyclic Schiff base. J. Chem. Soc. Chem., Commun. 2000 (2), 143-144.
3. Clifford, T.; Danby, A.M.; Lightfoot, P.; Richens, D.T.; Hay, R.W. Preparation of the copper (II) complex of the binucleating hexaazamacrocycle 2,5,8,17,20,23-hexaaza[9.9]paracyclophane and its solution chemistry, hydrolytic activity and acid dissociation kinetics. J. Chem. Soc., Dalton Trans. 2001, 240-246.
4. Howlander, M.B.H.; Islam, M.S.; Karim, M.R. Synthesis of some 16-membered macrocyclic complexes of chromium(III), manganese(II), iron(III), cobalt(II), nickel(II) and copper(II) containing a tetraoxooctaaza cyclohexadecane ligand. Indian. J. Chem. 2000, 39 (A), 407-409.
5. McKenzic, C.J.; Robson, R. High turnover catalysis at bimetallic sites of the hydration of nitriles to carboxamides co-catalysed by acid highly specific hydration of acrylanitrile to acrylamide. J. Chem. Soc., Chem. Commun. 1988, 112-114.
6. Fransto da Silva, J.J.R.; Williams, R.J.P. The Biological Chemistry of the Elements; Clarendon Press: Oxford, 1991.
7. Adam, K.R.; Antotovich, M.; Baldwin, D.S.; Duckworth, P.A.; Leong, A.J.; Lindoy, L.F.; McParlin, M.; Tasker, P.A. Ligand design and metal-ion recognition. The interaction of copper(II) with a range of 16- to 19-membered macrocycles incorporating oxygen, nitrogen and sulfur donor atoms. J. Chem. Soc., Dalton Trans. 1993, 1013-1017.
8. Sibert, J.W.; Cory, A.H.; Cory, J.G. Lipophilic derivatives of cyclam as new inhibitors of tumor cell growth. J. Chem. Soc., Chem. Commun. 2002, 154-155.
9. Brucher, E.; Sherry, A.D. The Chemistry of Contrast Agents in Medical Magnetic Resonance Imaging; Merbach, A.E., Toth, E., Eds.; Wiley J.: New York, 2001; Chapter 6 (and references therein).
10. Suh, M.P.; Kang, S.G. Synthesis and properties of nickel(II) and copper(II) complexes of 14-membered hexaazamacrocycles: 1,8-dimethyl and 1,8-diethyl-1,3,6,8,10,13-hexaazacyclotetradecane. Inorg. Chem. 1988, 27, 2544-2546.
11. Khan, T.A.; Hasan, S.S.; Jahan, N.; Mohamed, A.K.; Islam, K.S. Synthesis and characterization of highly conjugated 22-membered octaazamacrocycles and their manganese(II), copper(II), cobalt(II), and zinc(II) complexes. Indian J. Chem. 2000, 39 (A), 1090-1092.
12. Reilley, C.N.; Schmid, R.W.; Sadak, F.S. Chelon approach to analysis (II). Illustrative experiments. J. Chem. Edn. 1959, 36, 619-626.
13. Vogel, A.L. A Text Book of Quantitative Inorganic Analysis, 3rd Ed.; Longmans: London, 1961; 433-434.
14. Geary, W.J. Use of conductivity measurements in organic solvents for the characterization of coordination compounds. Coord. Chem. Rev. 1971, 7 (1), 81-122.
15. Shakir, M.; Varkey, S.P. Synthesis and spectral studies of binuclear transition metal complexes of diamidediimine hexaazamacrocycles. Polyhedron 1994, 13 (5), 791-797.
16. Shakir, M.; Varkey, S.P.; Hameed, P.S. Synthesis and spectral studies of binuclear transition metal complexes of diamidediimihexaazamacrocycles. Polyhedron 1994, 13 (9), 1355-1361.
17. Nakamoto, K. Infrared Spectra of Inorganic and Coordination Compounds; Wiley Interscience: New York, 1970.
18. Rana, V.B.; Singh, P.; Singh, D.P.; Teotia, M.P. Divalent nickel, cobalt and copper complexes of tetradentate macrocycle, dibenzo[F,n]-2, 4,10,12-tetramethyl-1,5,9,13-tetracyclohexadeca-[16]-1,3,9,11-tetraene. Polyhedron 1982, 1, 377-381.
19. 5), as uninegative bidentate bridging ligands. Synthesis and characterization of dimeric complexes with cobalt, copper and silver. Polyhedron 1992, 11 (22), 2831-2836.
20. Procter, I.M.; Hathaway, B.J.; Nicholls, P. The electronic properties and stereochemistry of the copper(II) ion. Part I. bis(Ethylenediamine) copper(II) complexes. J. Chem. Soc. (A) 1968, 1678-1684.
21. Ray, R.K.; Kauffman, G.B. An EPR study of some copper(II) coordination compounds of substituted biguanides. Part IV. Inorg. Chim. Acta 1990, 174 (2), 62-257.
22. Hay, R.W.; Ali, M.A.; Jeragh, B. The preparation of 5,7,7,12,14- pentamethyl-1,4,8,11-tetra-azacyclotetradeca-4,11-diene and its complexes with copper(II), nickel(II), zinc(II) and cobalt(II). J. Chem. Soc., Dalton Trans. 1988, 2763-2767.
23. Burgess, K.; Lim, D.; Kwok, K.H.; Chun, Y.K. Asymmetric synthesis of protected derivatives of carnosadine and its stereoisomers as conformationally constrained surrogates for arginine. J. Org. Chem. 1994, 59, 2179-2185.
24. Shakir, M.; Mohammed, A.K.; Varkey, S.P.; Nasman, O.S.M. Synthesis and structural studies of bis(macrocyclic) dimetal(II) complexes based on 14-18-membered pentaaza unit. Indian J. Chem. 1996, 35 (A), 935-939.
25. Lever, A.B.P. Crystal field spectra. In Inorganic Electronic Spectroscopy, 2nd Ed.; Elsevier: Amsterdam, 1984; Chap 9, 318-357.