Improved normal-phase high-performance liquid chromatography procedure for the determination of carotenoids in cereals

Journal of Agricultural and Food Chemistry

Volumn 52, Issue 21, 2004, Pages 6373-6377

  Panfili, Gianfranco ^a   Fratianni, Alessandra ^a   Irano, Mario ^a  

^a UNIVERSITY OF MOLISE   (Italy)

Author keywords

Carotenoids; Cereals; Food; HPLC; Lutein; Pigments

Indexed keywords

ALPHA CAROTENE; BETA CAROTENE; CAROTENOID; CRYPTOXANTHIN; XANTHOPHYLL; ZEAXANTHIN;

ANALYTIC METHOD; ARTICLE; CEREAL; CHEMICAL COMPOSITION; DRY WEIGHT; EXTRACTION; FOOD ANALYSIS; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; MAIZE; OAT; SAPONIFICATION; SEED KERNEL; WHEAT;

CAROTENOIDS; CEREALS; CHROMATOGRAPHY, HIGH PRESSURE LIQUID; TRITICUM; ZEA MAYS;

TRITICUM AESTIVUM; TRITICUM TURGIDUM SUBSP. DURUM; ZEA MAYS;

EID: 6344282919     PISSN: 00218561     EISSN: None     Source Type: Journal    
DOI: 10.1021/jf0402025     Document Type: Article

References (26)

1. Palozza, P.; Krinsky, N. I. Antioxidant effects of carotenoids in vivo and in vitro: an overview. Methods Enzymol. 1992, 213, 403-420.
2. Basu, H. N.; Del Vecchio, A.; Flider, F.; Orthoefer, F. T. Nutritional and potential disease prevention properties of carotenoids. J. Am. Oil Chem. Soc. 2001, 78, 665-675.
3. Humphries, J. M.; Khachik, F. Distribution of lutein, zeaxanthin, and related geometrical isomers in fruits, vegetables, wheat and pasta products. J. Agric. Food Chem. 2003, 57, 1322-1327.
4. Approved Methods of the American Association of Cereal Chemists; AACC: Minneapolis, MN, 1994; AACC method 14-50 1961 (revised).
5. Oliver, J.; Palou, A. Chromatographic determination of carotenoids in foods. J. Chromatogr. A 2000, 881, 543-555.
6. Barua, A. B. Improved normal-phase and reversed-phase gradient high-performance liquid chromatography procedures for the analysis of retinoids and carotenoids in human serum, plant and animal tissues. J. Chromatogr. A 2001, 936, 71-82.
7. 30 stationary phases for the analysis of food by liquid chromatography. J. Chromatogr. A 2000, 880, 189-202.
8. Manzi, P.; Panfili, G.; Pizzoferrato, L. Normal and reversed-phase HPLC for more complete evaluation of tocopherols, retinols, carotenes and sterols in dairy products. Chromatographia 1996, 43, 89-93.
9. Lessin, W. J.; Catigani, G. L.; Schwartz, S. J. Quantification of cis-trans isomers of provitamin A carotenoids in fresh and processed fruits and vegetables. J. Agric. Food Chem. 1997, 45, 3728-3732.
10. Breithaupt, D.; Bamedi, A. Carotenoid esters in vegetables and fruits: a screening with emphasis on β cryptoxanthin esters. J. Agric. Food Chem. 2001, 49, 2064-2070.
11. Olmedilla, B. G. F.; Blanco, I.; Gil Martinez, E. Carotenoids content in fruit and vegetables and its relevance to human health: some of the factors involved. Recent Res. Dev. Agric. Food Chem. 1998, 2, 57-70.
12. Barnes, P. J. Non-saponifiable lipids in cereals. In Lipids in Cereal Technology; Barnes, P. J., Ed.; Academic Press: London, U.K., 1983; p 33.
13. Lepage, M.; Sims, R. P. A. Carotenoids of wheat flour: their identification and composition. Cereal Chem. 1968, 45, 600-604.
14. Taungbodhitham, A. K.; Jones, G. P.; Wahlqvist, M. L.; Briggs, D. R. Evaluation of extraction method for the analysis of carotenoids in fruits and vegetables. Food Chem. 1998, 4, 577-584.
15. Aebischer, C.-P.; Schierle, J.; Schüep, W. Simultaneous determination of retinol, tocopherols, carotene, lycopene, and xanthophylls in plasma by means of reversed-phase high-performance liquid chromatography. Methods Enzymol. 1998, 299, 348-362.
16. Panfili, G.; Fratianni, A.; Irano, M. Normal-phase high performance liquid chromatography method for tocopherols and tocotrienols determination in cereal foods. J. Agric. Food Chem. 2003, 51, 3940-3944.
17. AOAC. Official Methods of Analysis, 13th ed.; Association of Official Analytical Chemists: Arlington, VA, 1980; method 14.088-14.089.
18. Folch, J.; Lees, M.; Sloane Stanley, G. H. A simple method for the isolation and purification of total lipids from animal tissues. J. Biol. Chem. 1957, 226, 497-509.
19. Kaiser, H. Quantitation in elemental analysis. Anal. Chem. 1970, 4, 24A-59A.
20. Oliver, J.; Palou, A.; Pons, A. Semi-quantification of carotenoids by high-performance liquid chromatography: saponification-induced losses in fatty foods. J. Chromatogr. A 1998, 829, 393-399.
21. Panfili, G.; Manzi, P.; Pizzoferrato, L. High performance liquid chromatographic method for the simultaneous determination of tocopherols, carotenes, and retinol and its geometric isomers in Italian cheeses. Analyst 1994, 119, 1161-1165.
22. 2: oil and defatted cake characterization. J. Am. Oil Chem. Soc. 2003, 80, 157-161.
23. Hentschel, V.; Kranl, K.; Hollmann, J.; Lindhauer, M. G.; Böhm, V.; Bitsch, R. Spectrophotometric determination of yellow pigment content and evaluation of carotenoids by high-performance liquid chromatography in durum wheat grain. J. Agric. Food Chem. 2002, 50, 6663-6668.
24. Chung, O. K. Cereal lipids. In Handbook of Cereal Science and Technology; Lorenz, K. J., Kulp, K., Eds.; Dekker: New York, 1993; p 497.
25. Abdel-Aal, E.-S. M.; Young, J. C.; Wood, P. J.; Rabalski, I.; Hucl, P.; Falk, D.; Frégeau-Reid, J. Einkorn: a potential candidate for developing high lutein wheat. Cereal Chem. 2002, 79, 455-457.
26. Kurilich, A. C.; Juvik, J. A. Quantification of carotenoid and tocopherol antioxidants in Zea mays. J. Agric. Food Chem. 1999, 47, 1948-1955.