Persistent phosphinyl radicals featuring a bulky amino substituent and the 2,6-bis(trifluoromethyl)phenyl group

Inorganic Chemistry

Volumn 43, Issue 21, 2004, Pages 6546-6548

  Dumitrescu, Anca ^a   Rudzevich, Valentyn L ^a,b   Romanenko, Vadim D ^a,b   Mari, Alain ^c   Schoeller, Wolfgang W ^d   Bourissou, Didier ^a   Bertrand, Guy ^a,b  

^a UNIVERSITÉ PAUL SABATIER   (France)

^b UNIVERSITY OF CALIFORNIA   (United States)

^c LCC LABORATOIRE DE CHIMIE DE COORDINATION   (France)

^d BIELEFELD UNIVERSITY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

2,6 BIS(TRIFLUOROMETHYL)PHENYL DERIVATIVE; DIPHOSPHINE; PHOSPHINE DERIVATIVE; PHOSPHINYL RADICAL; RADICAL; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL STRUCTURE; DIMERIZATION; ELECTRON SPIN RESONANCE; ENTHALPY; HYDROGEN BOND; LOW TEMPERATURE; STEREOCHEMISTRY; STRUCTURE ANALYSIS;

EID: 6344235202     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic049152b     Document Type: Article

References (26)

1. (a) Grützmacher, H.; Breher, F. Angew. Chem., Int. Ed. 2002, 41, 4006.
2. (b) Power, P. P. Chem. Rev. 2003, 103, 789.
3. (a) Canac, Y.; Bourissou, D.; Baceiredo, A.; Gornitzka, H.; Schoeller, W. W.; Bertrand, G. Science 1998, 279, 2080.
4. (b) Scheschkewitz, D.; Amii, H.; Gornitzka, H.; Schoeller, W. W.; Bourissou, D.; Bertrand, G. Science 2002, 295, 1880.
5. Tordo, P. In The Chemistry of Organophosphorus Compounds; Pataï, S., Hartley, F. R. Eds.; Wiley: New York, 1990; Vol. 1, p 137.
6. (a) Gynane, M. J. S.; Hudson, A.; Lappert, M. F.; Power, P. P. J. Chem. Soc., Chem. Commun. 1976, 623.
7. (b) Gynane, M. J. S.; Hudson, A.; Lappert, M. F.; Power, P. P. J. Chem. Soc., Dalton Trans. 1980, 2428.
8. Cetinkaya, B.; Hudson, A.; Lappert, M. F.; Goldwhite, H. J. Chem. Soc., Chem. Commun. 1982, 609.
9. (a) Cattani-Lorente, M.; Geoffroy, M. J. Chem. Phys. 1989, 91, 1498.
10. (b) Loss, S.; Magistrato, A.; Cataldo, L.; Hoffmann, S.; Geoffroy, M.; Röthlisberger, U.; Grützmacher H. Angew. Chem., Int. Ed. 2001, 40, 723.
11. Sasaki, S.; Murakami, F.; Yoshifuji, M. Angew. Chem., Int. Ed. 1999, 38, 340.
12. Wienk, M. M.; Janssen, R. A. J. Chem. Commun. 1996, 1919.
13. Edelmann, F. T. Comments Inorg. Chem. 1992, 12, 259.
14. (a) Hirai, K.; Tomioka, H. J. Am. Chem. Soc. 1999, 121, 10213.
15. (b) Woodcock, H. L.; Moran, D.; Schleyer, P. v. R.; Schaefer, H. F., III. J. Am. Chem. Soc. 2001, 123, 4331.
16. (a) Buron, C.; Gornitzka, H.; Romanenko, V.; Bertrand, G. Science 2000, 288, 834.
17. (b) Despagnet-Ayoub, E.; Solé, S.; Gornitzka, H.; Rozhenko, A. B.; Schoeller, W. W.; Bourissou, D.; Bertrand, G. J. Am. Chem. Soc. 2003, 125, 124.
18. Solé, S.; Gornitzka, H.; Schoeller, W. W.; Bourissou, D.; Bertrand, G. Science 2001, 292, 1901.
19. (a) Burford, N.; Macdonald, C. L. B.; LeBlanc, D. J.; Cameron, T. S. Organometallics 2000, 19, 152.
20. (b) Dumitrescu, A.; Gornitzka, H.; Schoeller, W. W.; Bourissou, D.; Bertrand, G. Eur. J. Inorg. Chem. 2002, 1953.
21. Since phosphinyl radicals 2 are only generated in modest yields by photolysis, no attempts were made to isolate the corresponding diphosphines.
22. (a) Hinchley, S. L.; Morrison, C. A.; Rankin, D. W. H.; Macdonald, C. L. B.; Wiacek, R. J.; Cowley, A. H.; Lappert, M. F.; Gundersen, G.; Clyburne, J. A. C.; Power, P. P. Chem. Commun. 2000, 2045.
23. (b) Hinchley, S. L.; Morrison, C. A.; Rankin, D. W. H.; Macdonald, C. L. B.; Wiacek, R. J.; Voigt, A.; Cowley, A. H.; Lappert, M. F.; Gundersen, G.; Clyburne, J. A. C.; Power, P. P. J. Am. Chem. Soc. 2001, 123, 9045.
24. Borisenko, K. B.; Rankin, D. W. H. Inorg. Chem. 2003, 42, 7129.
25. (a) Bezombes, J. P.; Hitchcock, P. B.; Lappert, M. F.; Nycz, J. E. Dalton Trans. 2004, 499.
26. (b) Bezombes, J. P.; Borisenko, K. B.; Hitchcock, P. B.; Lappert, M. F.; Nycz, J. E.; Rankin, D. W. H.; Robertson, H. E. Dalton Trans. 2004, 1980.