Conformational analysis of bis(L-N,N-dimethylvalinato)copper(II) and bis(L-N,N-dimethylleucinato)copper(II) in different solvents by EPR spectroscopy and a molecular mechanics study

European Journal of Inorganic Chemistry

Volumn , Issue 19, 2004, Pages 3930-3937

  Mirosavljević, Krunoslav ^a   Sabolović, Jasmina ^b   Noethig Laslo, Vesna ^a  

^a RUDER BO KOVI INSTITUTE   (Croatia)

^b INSTITUTE FOR MEDICAL RESEARCH AND OCCUPATIONAL HEALTH   (Croatia)

Author keywords

Amino acids; Complexes; EPR spectroscopy; Force field; N,O ligands

Indexed keywords

BROWNIAN MOVEMENT; CONFORMATIONS; COPPER COMPOUNDS; ELECTRON SPIN RESONANCE SPECTROSCOPY; HYDROGEN BONDS; MOLECULAR MECHANICS; MOLECULES; SOLVENTS;

AMINO-ACIDS; COMPLEX; CONFORMATIONAL ANALYSIS; DIFFERENT SOLVENTS; EPR SPECTROSCOPY; EPR SPECTRUM; EPR STUDIES; FORCEFIELDS; N,O LIGAND; O LIGANDS;

AMINO ACIDS;

AMINO ACID DERIVATIVE; BIS(N,N DIMETHYLLEUCINATO)COPPER; BIS(N,N DIMETHYLVALINATO)COPPER; CHLOROFORM; COPPER COMPLEX; DEUTERIUM; LEUCINE; LIGAND; METHANOL; NITROGEN DERIVATIVE; OXYGEN; SOLVENT; UNCLASSIFIED DRUG; VALINE; WATER;

ARTICLE; BROWNIAN MOTION; CONFORMATION; ELECTRON SPIN RESONANCE; FORCE; FORCE FIELD; HYDROGEN BOND; MOLECULAR MECHANICS; MOTION; STRUCTURE ANALYSIS; TEMPERATURE;

EID: 6344231932     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejic.200300781     Document Type: Article

References (47)

1. B. Bóka, A. Myani, I. Sóvágó, N. Hadjiliadis, J. Inorg. Biochem. 2004, 98, 113-122.
2. Z. Arkosi, T. Szabó-Plánka, A. Rockenbauer, N. V. Nagy, L. Lázár, F. Fülöp, Inorg. Chem. 2003, 16, 4842-4848.
3. M. D. Apostolova, P. R. Bontchev, B. B. Ivanova, W. R. Russell, D. R. Mehandjiev, J. H. Beattie, C. K. Nachev, J. Inorg. Biochem. 2003, 95, 321-333.
4. G. Facchin, M. H. Torre, E. Kremer, O. E. Piro, E. E. Castellano, E. J. Baran, J. Inorg. Biochem. 2002, 89, 174-180.
5. T. Szabó-Plánka, N. Nagy, A. Rockenbauer, L. Korecz, Polyhedron 2000, 19, 2049-2057.
6. R. Pogni, M. C. Baratto, E. Busi, R. Basosi, J. Inorg. Biochem. 1999, 73, 153-165.
7. G. Branica, N. Paulić, B. Grgas, D. Omanović, Chem. Spec. Bioavail. 1999, 11, 125-134.
8. D. R. Brown, V. Guantieri, G. Grasso, G. Impellizzeri, G. Pappalardo, E. Rizzarelli, J. Inorg. Biochem. 2004, 98, 133-143.
9. M. J. Pushie, A. Rauk, J Biol. Inorg. Chem. 2003, 8, 53-65.
10. M. Orfei, M. C. Alcaro, G. Marcon, M. Chelli, M. Ginanneschi, H. Kozlowski, J. Brasun, L. Messori, J. Inorg. Biochem. 2003, 97, 299-307.
11. P. Comba, Coord. Chem. Rev. 2000, 200-202, 217-245.
12. G. Liang, R. Tribolet, H. Sigel, Inorg. Chem. Acta 1989, 27, 273-280.
13. H. Sigel, Pure Appl. Chem. 1989, 61, 923-932.
14. V. Noethig-Laslo, N. Paulić, J. Chem. Soc., Dalton Trans. 1992, 2045-2047.
15. V. Noethig-Laslo, N. Paulić, Z. Anorg. Allg. Chem. 1995, 62, 84-88.
16. B. Kaitner, N. Paulić, N. Raos, V. Simeon, J. Coord. Chem. 1987, 15, 373-381.
17. B. Kaitner, N. Paulić, N. Raos, J. Coord. Chem. 1991, 22, 269-279.
18. B. Kaitner, G. Pavlović, N. Paulić, N. Raos, J. Coord. Chem. 1995, 36, 327-338.
19. B. Kamenar, M. Penavić, A. Škorić, N. Paulić, N. Raos, V. Simeon, J. Coord. Chem. 1988, 17, 85-94.
20. C. S. Tautermann, J. Sabolović, A. F. Voegele, K. R. Liedl, J. Phys. Chem. B 2004, 198, 2098-2102.
21. V. Noethig-Laslo, N. Paulić, Polyhedron 1999, 18, 1609-1614.
22. V. Noethig-Laslo, N. Paulić, R. Pogni, R. Bassosi, Polyhedron 2002, 27, 1643-1649.
23. J. Sabolović, V. Noethig-Laslo, Cellul. Mol. Biol. Lett. 2002, 7, 151-153.
24. R. Basosi, W. A. Antholine, J. S. Hyde, Biological Magn. Res. 1993, 13, 103-150.
25. R. Pogni, G. della Lunga, R. Basosi, J. Am. Chem. Soc. 1993, 115, 1546-1550.
26. J. Sabolović, C. S. Tautermann, T. Loerting, K. R. Liedl, Inorg. Chem. 2003, 42, 2268-2279.
27. C. Conato, A. Contino, G. Maccaone, A. Magri, M. Remelli, G. Tabbi, Thermochim. Acta 2000, 362, 13-23.
28. B. A. Goodman, C. G. Palivan, H. Palivan, S. Tomas, Appl. Magn. Reson. 2003, 25, 13-28.
29. B. Kaitner, N. Paulić, G. Pavlović, J. Sabolović, Polyhedron 1999, 18, 2301-2311.
30. B. A. Goodman, D. B. McPhail, H. K. J. Powell, J. Chem. Soc., Dalton Trans. 1981, 822-827.
31. B. A. Goodman, D. B. McPhail, J. Chem. Soc., Dalton Trans. 1985, 1717-1719.
32. M. Pasenkiewicz-Gierula, W. Froncisz, R. Basosi, W. E. Antholine, J. S. Hyde, Inorg. Chem. 1987, 26, 801-805.
33. A. Rockenbauer, J. Magn. Res. 1979, 35, 429-438.
34. T. Szabo-Planka, A. Rockenbauer, L. Korecz, D. Nagy, Polyhedron 2000, 19, 1123-1131.
35. D. B. McPhail, B. A. Goodman, J. Chem. Soc., Faraday Trans. 1987, 3683-3692.
36. J. Peisach, W. E. Blumberg, Arch. Biochem. Biophys. 1974, 165, 691-708.
37. P. Comba, P. Jursic, Y. D. Lampeka, A. Peters, A. I. Prikhod'ko, H. Pritzkow, Inorg. Chim. Acta 2001, 324, 99-107.
38. J. Sabolović, K. R. Liedl, Inorg. Chem. 1999, 38, 2764-2774.
39. H. M. McConnell, J. Chem. Phys. 1956, 25, 709-711.
40. F. G. Hering, J. M. Park, J. Magn. Res. 1979, 36, 311-323.
41. CRC Handbook of Chemistry and Physics, 58th edition, CRC PRESS, 1977-1978.
42. S. R. Niketić, K. Rasmussen, The Consistent Force Field: A Documentation; Lectures Notes in Chemistry, Springer-Verlag: Berlin Heidelberg New York, 1977, vol. 3.
43. K. Rasmussen, Potential Energy Functions in Conformational Analysis; Lectures Notes in Chemistry, Springer-Verlag: Berlin, Heidelberg, New York, 1985, Vol. 37.
44. K. Rasmussen, S. B. Engelsen, J. Fabricius, B. Rasmussen in the Recent Experimental and Computational Advances in Molecular Spectroscopy (Ed.: R. Fausto), NATO ASI Series C: Mathematical and Physical Sciences; Kluwer Academic Publishers: Dordrecht, The Netherlands, 1993, vol. 406, pp. 381-419.
45. T. J. M. de Bruin, T. M. Marcelis, H. Zuilhof, E. J. R. Sudhölter, Phys. Chem. Chem. Phys. 1999, 1, 4157-4163.
46. R. E. Bowman, H. H. Stroud, J. Chem. Soc. 1950, 1342-1349.
47. C. P. Nash, W. P. Schaefer, J. Am. Chem. Soc. 1969, 91, 1319-1324.