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Volumn 126, Issue 41, 2004, Pages 13432-13442

Metal-catalyzed anaerobic disproportionation of hydroxylamine. Role of diazene and nitroxyl intermediates in the formation of N2, N 2O, NO+, and NH3

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; CATALYST ACTIVITY; COORDINATION REACTIONS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OXIDATION; PH EFFECTS; REDUCTION; ULTRAVIOLET SPECTROSCOPY;

EID: 6344227963     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja046724i     Document Type: Article
Times cited : (48)

References (89)
  • 3
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    • Schlegel, H. G., Bowien, B., Eds.; Science Tech Publishers
    • Hooper, A. B. In Autotrophic Bacteria; Schlegel, H. G., Bowien, B., Eds.; Science Tech Publishers: 1989.
    • (1989) Autotrophic Bacteria
    • Hooper, A.B.1
  • 40
    • 0001878433 scopus 로고
    • Grasshoftt, K., Ed.; Verlag Chemie: New York
    • Koroleff, F. In Methods of Seawater Analysis; Grasshoftt, K., Ed.; Verlag Chemie: New York, 1976; pp 126-133.
    • (1976) Methods of Seawater Analysis , pp. 126-133
    • Koroleff, F.1
  • 55
    • 6344265971 scopus 로고    scopus 로고
    • note
    • 0 ca. 5-6.
  • 57
    • 0030797969 scopus 로고    scopus 로고
    • (b) ibid. 1997, 119, 8869-8878.
    • (1997) J. Am. Chem. Soc. , vol.119 , pp. 8869-8878
  • 59
    • 33746551405 scopus 로고
    • Mason, J. Chem. Rev. 1981, 81, 205-227.
    • (1981) Chem. Rev. , vol.81 , pp. 205-227
    • Mason, J.1
  • 70
    • 0003712587 scopus 로고    scopus 로고
    • The Royal Society of Chemistry: U.K.
    • -1, respectively. The chain propagation and its precursor, reaction 3, reveal a close analogy between hydroxylamine and hydrogen peroxide chemistry (Fenton-type), with Fe(II) species leading to free radicals (cf. Jones, C. W. Applications of Hydrogen Peroxide and Derivatives; The Royal Society of Chemistry: U.K., 1999; p 44).
    • (1999) Applications of Hydrogen Peroxide and Derivatives , pp. 44
    • Jones, C.W.1
  • 79
    • 6344270485 scopus 로고    scopus 로고
    • note
    • 2OH, with possible unknown intermediate formation. In eq 8, the competition with reaction 3 could be better appreciated if the O-bound complex would be the reactant. However, the N-bound complex was considered a more realistic approach to diazene formation, given that the competition with reaction 3 is still established through reactions 2a and b.
  • 84
    • 6344234037 scopus 로고    scopus 로고
    • note
    • 2-,3- couple should be of ca. 0.5 V.13
  • 89
    • 6344264073 scopus 로고    scopus 로고
    • note
    • Ongoing experiments aim to better explore the transition region through a broader variation of pH's and concentrations of hydroxylamine. These results will be reported in due course.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.