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2OH, with possible unknown intermediate formation. In eq 8, the competition with reaction 3 could be better appreciated if the O-bound complex would be the reactant. However, the N-bound complex was considered a more realistic approach to diazene formation, given that the competition with reaction 3 is still established through reactions 2a and b.
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6344234037
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2-,3- couple should be of ca. 0.5 V.13
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89
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6344264073
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note
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Ongoing experiments aim to better explore the transition region through a broader variation of pH's and concentrations of hydroxylamine. These results will be reported in due course.
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