Cobalt bis(dicarbollide) ions functionalized by CMPO-like groups attached to boron by short bonds; efficient extraction agents for separation of trivalent f-block elements from highly acidic nuclear waste

Journal of Organometallic Chemistry

Volumn 694, Issue 11, 2009, Pages 1678-1689

  Grüner, Bohumír ^a   Kvíčalová, Magdaléna ^a   Plešek, Jaromír ^a   Šícha, Václav ^a   Císařová, Ivana ^b   Lučaníková, Mária ^c   Selucký, Pavel ^c  

^a INSTITUTE OF INORGANIC CHEMISTRY   (Czech Republic)

^b CHARLES UNIVERSITY   (Czech Republic)

^c NUCLEAR RESEARCH INSTITUTE   (Czech Republic)

Author keywords

Carboranes; Lanthanide actinide pertitioning; Liquid liquid extraction; Metallacarbaboranes

Indexed keywords

ACETONE; ACTINIDES; AMMONIUM COMPOUNDS; BORON; BORON COMPOUNDS; CALCIUM; CHELATION; COBALT; IONIZATION OF LIQUIDS; LIGANDS; LIQUIDS; METAL RECOVERY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OXYGEN; RADIOACTIVE WASTES; RARE EARTH ELEMENTS; STRUCTURAL METALS; X RAY DIFFRACTION ANALYSIS;

ANIONIC LIGANDS; CARBORANES; COBALT BIS(DICARBOLLIDE); CRYSTALLOGRAPHIC STUDIES; DICARBOLLIDE; DODECANE; EXTRACTION EFFICIENCIES; FUNCTIONALIZED; IONIC LIGANDS; LANTHANIDE-ACTINIDE PERTITIONING; LANTHANIDES; LINEAR CHAINS; LIQUID-LIQUID EXTRACTION; METAL CATIONS; METAL TO LIGAND RATIOS; METALLACARBABORANES; METHYL KETONES; MULTINUCLEAR NMR SPECTROSCOPIES; NEW CLASS; NUCLEAR WASTES; OXYGEN ATOMS; POLAR SOLVENTS; TECHNOLOGICAL APPLICATIONS; TERMINAL GROUPS; X-RAY STRUCTURES;

SOLVENT EXTRACTION;

EID: 63249132856     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2008.11.056     Document Type: Article

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