DSC measurements and modelling of the kinetics of methane hydrate formation in water-in-oil emulsion

Chemical Engineering Science

Volumn 64, Issue 9, 2009, Pages 2020-2026

  Dalmazzone, Didier ^a   Hamed, Néjib ^a   Dalmazzone, Christine ^b  

^a ENSTA PARISTECH   (France)

^b IFP ENERGIES NOUVELLES   (France)

Author keywords

Crystallization; Differential calorimetry; Emulsion; Gas hydrates; Kinetics; Mathematical modelling

Indexed keywords

CLATHRATE HYDRATES; DIFFERENTIAL CALORIMETRY; DRIVING FORCES; DSC MEASUREMENTS; EQUILIBRIUM CONDITIONS; EXPERIMENTAL CONDITIONS; GAS PRESSURES; GROWTH RATE CONSTANTS; HEAT PEAKS; HYDRATE FORMATIONS; INDUCTION TIME; MATHEMATICAL MODELLING; METHANE HYDRATES; MODEL-BASED; PRESSURE DIFFERENTIAL SCANNING CALORIMETRIES; STANDARD DEVIATIONS; SUB-COOLING; WATER PHASE; WATER-IN-OIL EMULSIONS;

CALORIMETERS; COMPUTER SIMULATION; CRYSTALLIZATION KINETICS; DIFFERENTIAL SCANNING CALORIMETRY; EMULSIFICATION; EMULSIONS; GASES; GRAIN BOUNDARIES; HYDRATION; MATHEMATICAL MODELS; METALLIC GLASS; METHANE; NORMAL DISTRIBUTION; RATE CONSTANTS;

GAS HYDRATES;

EID: 63249096505     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ces.2009.01.028     Document Type: Article

References (19)

1. Barker J.W., and Gomez R.K. Formation of hydrates during deepwater drilling operations. Journal of Petroleum Technology 41 (1989) 297
2. Clausse D. Thermal behavior of emulsions studied by differential scanning calorimetry. Journal of Dispersion Science and Technology 20 (1999) 315
3. Clausse D., Babin L., Broto F., Aguerd M., and Clausse M. Kinetics of ice nucleation in aqueous emulsion. Journal of Physical Chemistry 87 21 (1983) 4030-4034
4. Dalmazzone, C., Herzhaft, B., Dalmazzone, D., 2002a. Characterization of hydrate formation in drilling muds using differential scanning calorimetry (DSC). in: Proceedings of Fourth International Conference on Gas Hydrates, Yokohama, Japan, May 19-23.
5. Dalmazzone, D., Kharrat, M., Lachet, V., Fouconnier, B., Clausse, D., 2002b. DSC and PVT measurements of methane and trichlorofluoromethane hydrate dissociation equilibria in highly concentrated calcium chloride solutions and water-in-oil emulsions. Journal of Thermal Analysis and Calorimetry 70, 493-505.
6. Dalmazzone D., Clausse D., Dalmazzone C., and Herzhaft B. The stability of methane hydrates in highly concentrated electrolyte solutions by differential scanning calorimetry and theoretical computation. American Mineralogist 89 (2004) 1183-1191
7. Dalmazzone, D., Dalmazzone, C., Hamed, N., Herzhaft, B., Rousseau, L., 2005. HP DSC investigations of the kinetics of gas hydrate formation: application to drilling fluids. In: Proceedings of 5th International Conference on Gas Hydrates, Trondheim, Norway, June 13-16.
8. Dalmazzone D., Hamed N., Dalmazzone C., and Rousseau L. Application of high pressure DSC to the kinetics of formation of methane hydrate in water-in-oil emulsion. Journal of Thermal Analysis and Calorimetry 85 (2006) 361-368
9. Dalmazzone, D., Hamed, N., Clausse, D., Pezron, I., Luong, A.-T., Dalmazzone, C., 2008. Study of the kinetics of formation of trichlorofluoromethane hydrates and methane hydrates in water-in-oil emulsion by microcalorimetry. In: Proceedings of Sixth International Conference on Gas Hydrates, Vancouver, Canada, July 6-10.
10. Ebeltoft, H., Yousif, M., Soergaard, E., 1997. Hydrate control during deep water drilling: overview and new drilling fluids. in: Proceedings of the SPE Annual Technical Conference and Exhibition, SPE 38567, San Antonio, Texas, October 5-8.
11. Fouconnier, B., 2002. Calorimetry study of trichloro-fluoromethane hydrate formation in emulsion: a model system for the study of gas hydrates. Ph.D. Thesis, Université de Technologie de Compiègne, France, July 18.
12. Fu, B., Neff, S., Mathur, A., Bakeev, K., 2001. Novel low dosage hydrate inhibitors for deepwater operations. In: Proceedings of the SPE Annual Technical Conference and Exhibition, SPE 71472, New Orleans, Louisiana, September 30-October 3.
13. Hamed, N., 2006. Study of the kinetics of formation of methane hydrates in offshore drilling fluids by high-pressure calorimetric analysis. Ph.D. Thesis, Ecole des Mines de Paris, France, November 10.
14. Jakobsen T., Sjöblom J., and Ruoff P. Kinetics of gas hydrate formation in w/o emulsion. The model system trichlorofluoromethane/water/non-ionic surfactant studied by dielectric spectroscopy. Colloids and Surfaces A: Physicochemical and Engineering Aspects 112 (1996) 73-84
15. Kharrat M., and Dalmazzone D. Experimental determination of stability conditions of methane hydrate in aqueous calcium chloride solutions using high pressure differential scanning calorimetry. Journal of Chemical Thermodynamics 35 (2003) 1489-1505
16. Koh C.A., Westacott R.E., Zang W., Hirachand K., Creek J.L., and Soper A.K. Mechanisms of gas hydrate formation and inhibition. Fluid Phase Equilibria 194-197 (2002) 143-151
17. Le Parlouër P., Dalmazzone C., Herzhaft B., Rousseau L., and Mathonat C. Characterisation of gas hydrate formation using a new high-pressure micro-DSC. Journal of Thermal Analysis and Calorimetry 78 (2004) 165-172
18. Nguyen, J.-P., 1996. Drilling fluids. In: Drilling, Technip Editions, Paris (Chapter 5).
19. Power, D., Slater, K., Aldea, C., Lattanzi, S., 2003. Gas hydrate inhibited water-based muds for ultra-deepwater drilling. in: Practical Solutions for Drilling Challenges, Proceedings of AADE National Technology Conference, Houston, Texas, April 1-3.