Thermal behavior of J-aggregates in a langmuir-blodgett film of pure merocyanine dye investigated by UV-visible and IR absorption spectroscopy

Journal of Physical Chemistry B

Volumn 113, Issue 9, 2009, Pages 2764-2772

  Hirano, Yoshiaki ^a   Tateno, Shinsuke ^a   Maio, Ari ^a   Ozaki, Yukihiro ^a  

^a KWANSEI GAKUIN UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION; AGGREGATES; CADMIUM; CADMIUM COMPOUNDS; CHARGE TRANSFER; CHROMOPHORES; DISSOCIATION; DYES; HYDROCARBONS; INFRARED ABSORPTION; ION EXCHANGE; LANGMUIR BLODGETT FILMS; MELTING; MELTING POINT; SULFUR COMPOUNDS; SYSTEMS (METALLURGICAL);

AGGREGATION STATE; AQUEOUS SUBPHASE; ARACHIDIC ACIDS; BINARY SYSTEMS; BLUE-SHIFTED BANDS; DISSOCIATION TEMPERATURES; DRIVING FORCES; HYDROCARBON CHAINS; INTRA-MOLECULAR CHARGE TRANSFERS; IR ABSORPTION SPECTROSCOPIES; IR ABSORPTION SPECTRUM; J AGGREGATES; MEROCYANINE DYES; PARTIAL-MELTING; STRUCTURAL DISORDERS; TEMPERATURE DEPENDENTS; TEMPERATURE-DEPENDENT CHANGES; THERMAL BEHAVIORS; THERMAL MOBILITIES; THERMALLY INDUCED; UV-VISIBLE; UV-VISIBLE SPECTRUM;

ABSORPTION SPECTROSCOPY;

EID: 63049139757     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp808220w     Document Type: Article

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59. In Figures 3B and 6, peak at 1468 cm-1 at 25 ?C is assigned to the coupling mode of CH2 in-plane bending mode of the octadecyl group substituted to MS18, and the acetic acid in MS18 chromophore.16 In addition, the shoulder near 1460 cm-1 at the same temperature is identified as the CH2 in-plane bending mode of the acetic acid in MS18 chromophore.16 Therefore, their two peaks, which can be well recognized from 120 up to 230 ?C in Figure 6, suggest no orthorhombic nature between the MS18 octadecyl groups.