Polymerization of acrylamide initiated with Ce(IV)- and KMnO4-mercaptosuccinic acid redox systems in acid-aqueous medium

Express Polymer Letters

Volumn 1, Issue 3, 2007, Pages 132-141

  Ozeroglu C ^a   Sezgin, S ^a  

^a ISTANBUL UNIVERSITY   (Turkey)

Author keywords

Acrylamide; Cerium(IV) sulfate; Mercaptosuccinic acid; Molecular engineering; Polymer synthesis; Redox polymerization

Indexed keywords

EID: 63049122596     PISSN: 1788618X     EISSN: None     Source Type: Journal    
DOI: 10.3144/expresspolymlett.2007.22     Document Type: Article

References (36)

1. Launer H. F., Yost D. M.: The kinetics of the reaction between potassium permanganate and oxalic acid. Journal of the American Chemical Society, 56, 2571-2577 (1934).
2. Misra G. S., Bajpai U. D. N.: Redox polymerization. Progress in Polymer Science, 8, 61-131 (1982).
3. Narita H., Maghida S.: The polymerization of acrylamide initiated with ceric ion. Die Angewandte Makromolekulare Chemie, 97, 209-215 (1966).
4. Pramanik D., Chaterjee A. K.: Mechanistic studies on ceric-thiourea-initiated polymerization in acid aqueous media from end group analysis. Journal of Polymer Science Part A-Polymer Chemistry, 18, 311-319 (1980).
5. Özeroglu C., Yalçinyuva T.: Oxidative polymerization of methyl methacrylate in acid-aqueous medium. Polymer-plastics Technology and Engineering, 43, 731-743 (2004).
6. Biçak N., Özeroglu C.: Low temperature initiation by methylene bis(diethyl malonate)-Ce(IV) redox system in organic solvents. European Polymer Journal, 37, 2393-2395 (2001).
7. Sui K. Y., Gu L. X.: Preparation and characterization of amplihilic block copolymer of polyacrylonitrileblock-poly(ethylene oxide). Journal of Applied Polymer Science, 89, 1753-1759 (2003).
8. Saraç A. S., Özkara. Ş., Ustamehmetoglu B., Sezer E.: Controlled electroinduced polymerization of methyl meyhacrylate in the presence of catalytic amount of Ce(IV). Journal of Macromolecular Science Part A: Pure and Applied Chemistry, 40, 193-207 (2003).
9. Ananthanarayanan V. S., Santappa M.: Kinetics of vinyl polymerization initiated by ceric ion in aqueous solution. Journal of Applied Polymer Science, 9, 2437-2447 (1965).
10. Mino G., Kaizerman S., Rasmussen E.: The polymerization of acrylamide initiated by ceric nitrate-3-chloro-1-propanol redox system. Journal of Polymer Science, 38, 393-401 (1959).
11. Subramaniun S. V., Santappa M.: Vinyl polymerization initiated by ceric ion-reducing agent system in sulfuric acid media. Journal of Polymer Science Part A-Polymer Chemistry, 6, 493-504 (1968).
12. Palit S. R., Konar R. S.: Permanganate-oxalic acid as a initiator of acrylonitrile polymerization in aqueous media: (III) Kinetics and degree of polymerization. Journal of Polymer Science Part A-Polymer Chemistry, 2, 1731-1748 (1964).
13. 4 as an initiator in aquelus media: (II) The kinetics and degree of polymerization. Journal of Polymer Science, 58, 85-102 (1962).
14. Misra G. S., Narain H.: Aqueous polymerization of acrylic acid initiated by potassium permanganateoxalic acid redox system. Die Makromoleculare Chemie, 113, 85-94 (1968).
15. Hussain M. M., Gupta A.: Effect of some additions on the aqueous polymerization of acrylamide initiated by permanganate-oxalic acid redox system. Die Makromoleculare Chemie, 178, 29-36 (1977).
16. Akar A., Öz N.: Low molecular weight poly(acrylic acid) with nitrilo di(methylenephosponic acid) chain ends for scale inhibition. Die Angewandte Makromolekulare Chemie, 273, 12-14 (1999).
17. Saraç A. S., Erbil C., Soydan A. B.: Polymerization of acrylamide initiated with electrogenerated cerium(IV) in the presence of EDTA. Journal of Applied Polymer Science, 44, 877-881 (1992).
18. Erbil C., Cin C., Soydan A. B., Saraç A. S.: Polyaminocarboxylic acids-Ce(IV) redox systems as an initiator in acrylamide polymerization. Journal of Applied Polymer Science, 47, 1643-1648 (1993).
19. Saraç A. S., Başak A. H., Soydan A. B., Akar A.: Polymerization of acrylamide by electrolytically generated Ce(IV)-organic acid redox system. Die Angewandte Makromolekulare Chemie, 198, 191-198 (1992).
20. 4 redox systems in the presence of glycine. Journal of Applied Polymer Science, 60, 759-765 (1996).
21. Özeroglu C., Güney O., Mustafaev M. I.: Oxidative polymerization of acrylamide in the presence of Lthreonine. Die Angewandte Makromolekulare Chemie, 249, 1-9 (1997).
22. Özeroglu C., Kurtoglu A. E.: The synthesis and characterization of acrylamide polymer containing R-(+)-cystein end groups. European Polymer Journal, 37, 1053-1059 (2001).
23. Ustamehmetoglu B., Diler Z. I., Saraç A. S.: Chemical polymerization of acrylamide initiated with Ce(IV)-dicarboxylic acid redox system: effect of chain length between the carboxyl groups. International Journal of Polymer Analysis and Characterization, 7, 263-272 (2002).
24. Saraç A. S., Özeroglu C., Mustafaev M. I.: The ternary complexes of bovine serum albumin and polyacrylamide derivatives in the presence of copper ions in neutral water. Journal of Bioactive and Compatible Polymers, 10, 121-134 (1995).
25. Özeroglu C., Namazova N., Mustafaev M. I., Saraç A. S.: The complex formation between polyacrylamide containing glycine end groups and bovine serum albumin in the presence of copper(II) in neutral aqueous water. Colloid and Polymer Science, 274, 418-427 (1996).
26. Petrov R. V., Mustafaev M. I., Norimov A. Sh.: Physicochemical criteria for the constraction of artificial immunomodulators and immunogens on the basis of polyelectrolyte complexes. Sov. Med. Rev. D. Immunol., pp. 1-13. Harwood Academic Publisher GmbH. London UK (1992).
27. Özcan M., Akman S., Özeroglu C.: The use of water soluble polymers for the preconcentration and separation of copper, lead and chromium prior to their determination by graphite furnace atomic absorption spectrometry. Analytical Letters, 35, 1075-1083 (2002).
28. Özcan M., Akman S., Erbil C., Saraç A. S.: Determination of copper, chromium, manganese and zinc by graphite furnace atomic absorption spectrometry after separation on polyacrylamide modified with nitriloacetic acid. Fresenius' Journal of Analytical Chemistry, 355, 665-666 (1996).
29. Chuah H. H., Lin-Vien D., Soni U.: Poly(trimethylene terephthalate) molecular weight and Mark-Houwink equation. Polymer, 42, 7137-7139 (2001).
30. Özeroglu C., Erdogan S.: Oxidative polymerization of acrylamide in the presence of thioglycolic acid. Central European Journal of Chemistry, 3, 705-720 (2005).
31. Tsubokawa N., Maruyama K., Sone Y., Shimomura M.: Graft polymerization of acrylamide from ultra silica particles by use of a redox system consisting of ceric ion and reducing groups on the surface. Polymer Journal, 21, 475-481 (1989).
32. Lozinsky V. I., Ivanov R. V., Kalinina E. V., Timofeeva G. I., Khoklov A. R.: Redox-initiated polymerization of acrylamide in moderately frozen water solutions. Macromolecular Rapid Communications, 22, 1441-1446 (2001).
33. Saraç A. S.: Redox polymerization. Progress in Polymer Science, 24, 1149-1204 (1999).
34. 4 redox system for polymerization of acrylamide monomer. Polymer-plastics Technology and Engineering, 45, 549-554 (2006).
35. Saha S. K., Chaudhuri A. K.: Effect of amines on ceric ion-initiated polymerization of vinyl monomers. II. Polymerization of acrylonitrile by ceric ion in the presence of various substituted amines. Journal of Polymer Science Part A-Polymer Chemistry, 10, 797-808 (1972).
36. Patra M., Sinha B. K.: Acrylamide polymerization initiated with the redox system Ce(IV)-cyclohexanone in miceller phase: A kinetic study. Macromolecular Chemistry and Physics, 199, 311-317 (1998).