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2O: (a) Kurtz, D. M., Jr Dalton Trans. 2007, 41154121.
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Based on sequence analyses, certain NOR families in fact appear to be heme-copper enzymes. Personal communication, R. B. Gennis, U. Illinois
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Based on sequence analyses, certain NOR families in fact appear to be heme-copper enzymes. Personal communication, R. B. Gennis, U. Illinois.
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Kadish, K. M, Smith, K. M, Guilard, R, Eds, Academic Press: New York
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69649105845
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See Supporting Information
-
See Supporting Information.
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-
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26
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69649089702
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The dinitrosyl complex 2 is inherently interesting and will be the subject of separate future reports.
-
The dinitrosyl complex 2 is inherently interesting and will be the subject of separate future reports.
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27
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84869709666
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ESI-MS analysis of the reaction mixture gives only the well-known structurally characterized μ-oxo complex, 6LFe III-O-CuII, 4, m/z, 1173, matching a spectrum calculated for the structure which includes the distinctive pattern due to the 63,65Cu isotopes, In fact, solutions of 3 are cleanly converted to 4 with addition of Et3N/H 2O as indicated by the change to the known UV-vis spectrum with red-shifted Soret band, λmax, 440, 557 nm
-
max ) 440, 557 nm.
-
-
-
-
28
-
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84869730059
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+ is exposed to excess ̇NO(g), unpublished observations.
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+ is exposed to excess ̇NO(g), unpublished observations.
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29
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69649084013
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To date, a heme dinitrosyl species such as 2 has not been observed as an intermediate in the enzyme reaction.
-
To date, a heme dinitrosyl species such as 2 has not been observed as an intermediate in the enzyme reaction.
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30
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57349161940
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2O, see: Arikawa, Y.; Asayama, T.; Moriguchi, Y.; Agari, S.; Onishi, M. J. Am. Chem. Soc. 2007, 129, 14160-14161.
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2O, see: Arikawa, Y.; Asayama, T.; Moriguchi, Y.; Agari, S.; Onishi, M. J. Am. Chem. Soc. 2007, 129, 14160-14161.
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34
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