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6244275072
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note
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2, where μ is the transition dipole moment and E is the electric field of the radiation). Although these numerical results of the orientation angle are not strictly precise due to the experimental errors, they do provide information of orientation of two different types of carbonyl groups.
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25
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6244281668
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note
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The in-phase and out-of-phase of the carbonyl and hydroxyl groups in the hydrogen-bonded chain may also result in the doublet feature. However, for the C=O groups orientating in the same direction, their dipoles reinforce if they vibrate in-phase, and therefore bring about an increase in intensity and a decrease in frequency. And the out-of-phase vibration case will result in a decrease in intensity and an increase in frequency. The spectroscopic data in this study lie in contradiction to this prediction and therefore exclude the factor group splitting mechanism.
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