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1
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0036625218
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For reviews on Cp-ligated half-sandwich rare-earth-metal complexes, see: (a) Arndt, S.; Okuda, J. Chem. Rev. 2002, 102, 1953. (b) Hou, Z.; Luo, Y.; Li, X. J. Organomet. Chem. 2006, 691, 3114. (c) Okuda, J. Dalton Trans. 2003, 2367.
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For reviews on Cp-ligated half-sandwich rare-earth-metal complexes, see: (a) Arndt, S.; Okuda, J. Chem. Rev. 2002, 102, 1953. (b) Hou, Z.; Luo, Y.; Li, X. J. Organomet. Chem. 2006, 691, 3114. (c) Okuda, J. Dalton Trans. 2003, 2367.
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Edelmann, F. T.; Freckmann, D. M. M; Schumann, H. Chem. Rev. 2002, 102, 1851.
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Edelmann, F.T.1
Freckmann, D.M.M.2
Schumann, H.3
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Liu, S.-Y.; Lo, M. M. C; Fu, G. C. Angew. Chem., Int. Ed. 2002, 41, 174.
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Liu, S.-Y.1
Lo, M.M.C.2
Fu, G.C.3
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7
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61849152271
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There are a few scattered examples of Ab-ligated half-sandwich late-transition-metal non-alkylated complexes (e.g. Cr/Co/Rh); see: (a) Schmid, G. In Comprehensive Heterocyclic Chemistry 11; Shinkai, I., Ed.; Elsevier: Oxford, U.K., 1996; Chapter 3.17. (b) Schmid, G.; Schütz, M. Organometallics 1992, 11, 1789. (c) Liu, S.-Y.; Hills, I. D.; Fu, G. C. Organometallics 2002, 21, 4323.
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There are a few scattered examples of Ab-ligated half-sandwich late-transition-metal non-alkylated complexes (e.g. Cr/Co/Rh); see: (a) Schmid, G. In Comprehensive Heterocyclic Chemistry 11; Shinkai, I., Ed.; Elsevier: Oxford, U.K., 1996; Chapter 3.17. (b) Schmid, G.; Schütz, M. Organometallics 1992, 11, 1789. (c) Liu, S.-Y.; Hills, I. D.; Fu, G. C. Organometallics 2002, 21, 4323.
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8
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61849097081
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Half-sandwich rare-earth-metal dialkyl complexes bearing pyrollyl and phospholyl ligands were reported recently. See: (a) Nishiura, M; Mashiko, T.; Hou, Z. Chem. Commun. 2008, 2019. (b) Jaroschik, F.; Shima, T.; Li, X.; Mori, K.; Ricard, L.; Le Goff, X.-F.; Nief, F.; Hou, Z. Organometallics 2007, 26, 5654. (c) Roux, E. L.; Nief, F.; Jaroschik, F.; Törnroos, K. W.; Anwander, R. Dalton Trans. 2007, 4866.
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Half-sandwich rare-earth-metal dialkyl complexes bearing pyrollyl and phospholyl ligands were reported recently. See: (a) Nishiura, M; Mashiko, T.; Hou, Z. Chem. Commun. 2008, 2019. (b) Jaroschik, F.; Shima, T.; Li, X.; Mori, K.; Ricard, L.; Le Goff, X.-F.; Nief, F.; Hou, Z. Organometallics 2007, 26, 5654. (c) Roux, E. L.; Nief, F.; Jaroschik, F.; Törnroos, K. W.; Anwander, R. Dalton Trans. 2007, 4866.
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Evans, W. J.; Brady, J. C; Ziller, J. W. J. Am. Chem. Soc. 2001, 123, 7711. (b) Hultzsch, K. C; Spaniol, T. P.; Okuda, J. Angew. Chem., Int. Ed. 1999, 38, 227. (c) Cameron, T. M.; Gordon, J. C; Scott, B. L. Organometallics 2004, 23, 2995. (d) Cui, D. ML; N¡shiura, M; Hou, Z. M. Macromolecules 2005, 38, 4089.
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(a) Evans, W. J.; Brady, J. C; Ziller, J. W. J. Am. Chem. Soc. 2001, 123, 7711. (b) Hultzsch, K. C; Spaniol, T. P.; Okuda, J. Angew. Chem., Int. Ed. 1999, 38, 227. (c) Cameron, T. M.; Gordon, J. C; Scott, B. L. Organometallics 2004, 23, 2995. (d) Cui, D. ML; N¡shiura, M; Hou, Z. M. Macromolecules 2005, 38, 4089.
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(a) Elvidge, B. R.; Arndt, S.; Zeimentz, P. M.; Spaniol, T. P.; Okuda, J. Inorg. Chem. 2005, 44, 6777.
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Inorg. Chem
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Elvidge, B.R.1
Arndt, S.2
Zeimentz, P.M.3
Spaniol, T.P.4
Okuda, J.5
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47949125269
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Fang, X.; Deng, Y.; Xie, Q.; Moingeon, F. Organometallics 2008, 27, 2892.
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Organometallics
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Fang, X.1
Deng, Y.2
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Moingeon, F.4
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2 dianionic species; see: Bazan, G. C; Schaefer, W. P.; Bercaw, J. E. Organometallics 1993, 12, 2126.
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2 dianionic species; see: Bazan, G. C; Schaefer, W. P.; Bercaw, J. E. Organometallics 1993, 12, 2126.
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14
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Li, X.; Baldamus, J.; Hou, Z. Angew. Chem., Int. Ed. 2005, 44, 962.
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Li, X.1
Baldamus, J.2
Hou, Z.3
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61849164394
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Lange's Handbook of Chemistry, 13th ed.; Dean, J. A., Ed.; McGraw-Hill: New York, 1985.
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Lange's Handbook of Chemistry, 13th ed.; Dean, J. A., Ed.; McGraw-Hill: New York, 1985.
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16
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61849144764
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2 hybridized and the exocyclic B-N bond lengths are in an appropriate range for a moiety with substantial double-bond character (unpublished work).
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2 hybridized and the exocyclic B-N bond lengths are in an appropriate range for a moiety with substantial double-bond character (unpublished work).
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(a) Luo, Y.; Baldamus, J.; Hou, Z. J. Am. Chem. Soc. 2004, 126, 13910.
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(b) Zhang, H.; Luo, Y.; Hou, Z. Macromolecules 2008, 41, 1064.
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Zhang, H.1
Luo, Y.2
Hou, Z.3
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21
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61849183461
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In the absence of AliBu3, 7/[Ph3C, B(C6F5)4] alone showed much lower activity and gave a bimodal polymer under the same conditions, which was in contrast with case for the Cp-ligated analogues
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4] alone showed much lower activity and gave a bimodal polymer under the same conditions, which was in contrast with case for the Cp-ligated analogues.
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23
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61849101691
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SAINT, Version 6.02; Bruker AXS, Inc, Madison, WI, 1999
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SAINT+, Version 6.02; Bruker AXS, Inc., Madison, WI, 1999.
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Sheldrick, G. M. SADABS; Bruker AXS, Inc., Madison, WI, 1998.
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Sheldrick, G. M. SADABS; Bruker AXS, Inc., Madison, WI, 1998.
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61849102756
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Sheldrick, G. M. SHELXTL, Version 5.1; Bruker AXS, Inc, Madison, WI, 1998
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Sheldrick, G. M. SHELXTL, Version 5.1; Bruker AXS, Inc., Madison, WI, 1998.
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