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Pearson, J. M.; Haynes, A.; Morris, G. E.; Sunley, G. J.; Maitlis, P. M. J. Chem. Soc., Chem. Commun. 1995, 1045.
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Ghaffar, T.; Adams, H.; Maitlis, P. M.; Sunley, G. J.; Baker, M. J.; Haynes, A. Chem. Commun. 1998, 1023.
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5
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Haynes, A.; Maitlis, P. M.; Morris, G. E.; Sunley, G. J.; Adams, H.; Badger, P. W.; Bowers, C. M.; Cook, D. B.; Elliott, P. I. P.; Ghaffar, T.; Green, H.; Griffin, T. R.; Payne, M.; Pearson, J. M.; Taylor, M. J.; Vickers, P. W.; Watt, R. J. J. Am. Chem. Soc. 2004, 126, 2847.
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Bowers, C.M.7
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Green, H.11
Griffin, T.R.12
Payne, M.13
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Taylor, M.J.15
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6
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33644602641
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Volpe, M.; Wu, G.; Iretskii, A.; Ford, P. C. Inorg. Chem. 2006, 45, 1861.
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Volpe, M.1
Wu, G.2
Iretskii, A.3
Ford, P.C.4
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8
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8344272747
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Vickers, P. W.; Pearson, J. M.; Ghaffar, T.; Adams, H.; Haynes, A. J. Phys. Org. Chem. 2004, 17, 1007.
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Vickers, P.W.1
Pearson, J.M.2
Ghaffar, T.3
Adams, H.4
Haynes, A.5
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9
-
-
61849096920
-
-
This v(CO) band is close to a transient IR absorption at 2032 cm -1 observed after the flash photolysis of la by Volpe et al, ref 6
-
-1 observed after the flash photolysis of la by Volpe et al. (ref 6).
-
-
-
-
10
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0042877162
-
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Gautron, S.; Giordano, R.; Le Berre, C.; Jaud, J.; Daran, J.-C.; Serp, P.; Kalck, P. Inorg. Chem. 2003, 42, 5523.
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Gautron, S.1
Giordano, R.2
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Jaud, J.4
Daran, J.-C.5
Serp, P.6
Kalck, P.7
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11
-
-
33845891646
-
-
Gautron, S.; Lassauque, N.; Le Berre, C.; Azam, L.; Giordano, R.; Serp, P.; Laurenczy, G.; Daran, J.-C.; Duhayon, C.; Thiébaut, D.; Kalck, P. Organometallics 2006, 25, 5894.
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Gautron, S.1
Lassauque, N.2
Le Berre, C.3
Azam, L.4
Giordano, R.5
Serp, P.6
Laurenczy, G.7
Daran, J.-C.8
Duhayon, C.9
Thiébaut, D.10
Kalck, P.11
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12
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61849104279
-
-
In the structure obtained in this study, 3b]AsPh4 crystallizes in a different spacej;roup (P21/c) than that in the structure reported by Volpe et al, P1, ref 6
-
1/c) than that in the structure reported by Volpe et al. (P1, ref 6).
-
-
-
-
13
-
-
61849086460
-
-
The observed v(CO) frequencies for isotopomers of 1b were modeled by a CO factored force field (based on the analysis by Braterman in Metal Carbonyl Spectra; Academic Press: London, 1975) to give the following C-O stretching (k) and interaction (i) force constants for 1b: kc, 1707.1 N m-1 (CO cis to Me, kt, 1746.7 N m-1 (CO trans to Me, and i, 38.6 N m-1 (see the Supporting Information for calculated v(CO) frequencies, A similar analysis for the cis,fac isomer 1a gives values of kc, 1734 N m-1 and i, 43.2 N m-1. The shift to low frequency of the v(CO) bands of 1b relative to 1a is therefore due to a lower average value of k for the inequivalent CO ligands in 1b despite the higher value of kt
-
t).
-
-
-
-
14
-
-
61849095847
-
-
CH 5.2 Hz, strong doublet with intervening weak singlet.
-
CH 5.2 Hz, strong doublet with intervening weak singlet.
-
-
-
-
15
-
-
61849176709
-
-
2-. This would result from the reaction of 2d with 1 equiv of CO before complete cleavage of the dimer to give 1b.
-
2-. This would result from the reaction of 2d with 1 equiv of CO before complete cleavage of the dimer to give 1b.
-
-
-
-
16
-
-
61849125516
-
-
-1):
-
-1):
-
-
-
-
17
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0001023599
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(a) Haynes, A.; Mann, B. E.; Morris, G. E.; Maitlis, P. M. J. Am. Chem. Soc. 1993, 115, 4093.
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J. Am. Chem. Soc
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Haynes, A.1
Mann, B.E.2
Morris, G.E.3
Maitlis, P.M.4
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19
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0001739136
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Kubota, M.; McClesky, T. M.; Hayashi, R. K.; Webb, C. G. J. Am. Chem. Soc. 1987, 109, 7569.
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Kubota, M.1
McClesky, T.M.2
Hayashi, R.K.3
Webb, C.G.4
-
20
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-
0001005995
-
-
Haynes, A.; Pearson, J. M.; Vickers, P. W.; Charmant, J. P. H.; Maitlis, P. M. Inorg. Chim. Acta 1998, 270, 382.
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(1998)
Inorg. Chim. Acta
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Haynes, A.1
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Vickers, P.W.3
Charmant, J.P.H.4
Maitlis, P.M.5
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21
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33751386219
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Bellachioma, G.; Cardaci, G.; Jablonski, C.; Macchioni, A.; Reichen-bach, G. Inorg. Chem. 1993, 32, 2404.
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Inorg. Chem
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Bellachioma, G.1
Cardaci, G.2
Jablonski, C.3
Macchioni, A.4
Reichen-bach, G.5
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22
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0031206480
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Bellachioma, G.; Cardaci, G.; Macchioni, A.; Reichenbach, G. J. Organomet. Chem. 1997, 540, 7.
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Bellachioma, G.1
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-
23
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0001763627
-
-
Cheong, M.; Schmid, R.; Ziegler, T. Organometallics 2000, 19, 1973.
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(2000)
Organometallics
, vol.19
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-
-
Cheong, M.1
Schmid, R.2
Ziegler, T.3
-
24
-
-
61849130842
-
-
-1 (CCSD(T)).
-
-1 (CCSD(T)).
-
-
-
-
25
-
-
61849182216
-
-
We note that Ziegler and co-workers calculated that the activation barrier for methyl migration in [Ir(CO)3I2Me] is lower for isomers that have CO trans to methyl ref 22
-
2Me] is lower for isomers that have CO trans to methyl (ref 22).
-
-
-
-
26
-
-
61849123095
-
-
-1 w.r.t. 4) in which the acetyl ligand displays an agostic C-H-Ir interaction with the vacant cis coordination site.
-
-1 w.r.t. 4) in which the acetyl ligand displays an agostic C-H-Ir interaction with the vacant cis coordination site.
-
-
-
-
27
-
-
61849123881
-
-
- selectively.
-
- selectively.
-
-
-
-
28
-
-
61849158974
-
-
-1, suggesting that CO loss might be competitive with methyl migration in 1a. These values do not include entropic effects, which are likely significant for a dissociative process.
-
-1, suggesting that CO loss might be competitive with methyl migration in 1a. These values do not include entropic effects, which are likely significant for a dissociative process.
-
-
-
-
29
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5244370033
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Pangborn, A. B.; Giardello, M. A.; Grubbs, R. H.; Rosen, R. K.; Timmers, F. J. Organometallics 1996, 15, 1518.
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(1996)
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Pangborn, A.B.1
Giardello, M.A.2
Grubbs, R.H.3
Rosen, R.K.4
Timmers, F.J.5
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31
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0004150157
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SHELXTL
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Sheldrick, G.M.1
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61849166899
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Frisch, M. J, Trucks, G. W, Schlegel, H. B, Scuseria, G. E, Robb, M. A, Cheeseman, J. R, Montgomery, J. A, Jr, Vreven, T, Kudin, K. N, Burant, J. C, Millam, J. M, Iyengar, S. S, Tomasi, J, Barone, V, Mennucci, B, Cossi, M, Scalmani, G, Rega, N, Petersson, G. A, Nakatsuji, H, Hada, M, Ehara, M, Toyota, K, Fukuda, R, Hasegawa, J, Ishida, M, Nakajima, T, Honda, Y, Kitao, O, Nakai, H, Klene, M, Li, X, Knox, J. E, Hratchian, H. P, Cross, J. B, Bakken, V, Adamo, C; Jaramillo, J, Gomperts, R, Stratmann, R. E, Yazyev, O, Austin, A. J, Cammi, R, Pomelli, C, Ochterski, J. W, Ayala, P. Y, Morokuma, K, Voth, G. A, Salvador, P, Dannenberg, J. J, Zakrzewski, V. G, Dapprich, S, Daniels, A. D, Strain, M. C, Farkas, O, Malick, D. K, Rabuck, A. D, Raghavachari, K, Foresman, J. B, Ortiz, J. V, Cui, Q, Baboul, A. G, Clifford, S, Cioslowski, J, Stefanov, B. B, Liu, G, Liashenko, A, Piskorz, P, Komaromi, I, Martin, R. L, Fox, D. J, Keith
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Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Montgomery, J. A., Jr.; Vreven, T.; Kudin, K. N.; Burant, J. C.; Millam, J. M.; Iyengar, S. S.; Tomasi, J.; Barone, V.; Mennucci, B.; Cossi, M.; Scalmani, G.; Rega, N.; Petersson, G. A.; Nakatsuji, H.; Hada, M.; Ehara, M.; Toyota, K.; Fukuda, R.; Hasegawa, J.; Ishida, M.; Nakajima, T.; Honda, Y.; Kitao, O.; Nakai, H.; Klene, M.; Li, X.; Knox, J. E.; Hratchian, H. P.; Cross, J. B.; Bakken, V.; Adamo, C; Jaramillo, J.; Gomperts, R.; Stratmann, R. E.; Yazyev, O.; Austin, A. J.; Cammi, R.; Pomelli, C.; Ochterski, J. W.; Ayala, P. Y.; Morokuma, K.; Voth, G. A.; Salvador, P.; Dannenberg, J. J.; Zakrzewski, V. G.; Dapprich, S.; Daniels, A. D.; Strain, M. C.; Farkas, O.; Malick, D. K.; Rabuck, A. D.; Raghavachari, K.; Foresman, J. B.; Ortiz, J. V.; Cui, Q.; Baboul, A. G.; Clifford, S.; Cioslowski, J.; Stefanov, B. B.; Liu, G.; Liashenko, A.; Piskorz, P.; Komaromi, I.; Martin, R. L.; Fox, D. J.; Keith, T.; Al-Laham, M. A.; Peng, C. Y.; Nanayakkara, A.; Challacombe, M.; Gill, P. M. W.; Johnson, B.; Chen, W.; Wong, M. W.; Gonzalez, C.; Pople, J. A. Gaussian 03, revision B.05; Gaussian, Inc.: Wallingford, CT, 2004.
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