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Volumn 42, Issue 3, 2009, Pages 612-619

Anionic ring-opening polymerization of hexafluoropropylene oxide using alkali metal fluorides as catalysts: A mechanistic study

Author keywords

[No Author keywords available]

Indexed keywords

ANIONIC POLYMERIZATION; BENZENE; CATALYST ACTIVITY; CESIUM; CHEMICAL REACTIONS; CHROMATOGRAPHIC ANALYSIS; DYNAMIC POSITIONING; ESTERS; FLUORINE COMPOUNDS; FREE RADICAL POLYMERIZATION; GAS CHROMATOGRAPHY; LIGHT METALS; MOLAR MASS; MONOMERS; PERCOLATION (SOLID STATE); POLYMERS; POTASSIUM; SODIUM;

EID: 61849137307     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma8012338     Document Type: Article
Times cited : (40)

References (35)
  • 4
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    • Scheirs, J, Ed, Wiley: New York, Chapter 24, pp
    • Scheirs, J. In Scheirs, J., Ed.; Modern Fluoropolymers; Wiley: New York, 1997; Chapter 24, pp 446-452.
    • (1997) Modern Fluoropolymers , pp. 446-452
    • Scheirs, J.1
  • 20
    • 61849132269 scopus 로고    scopus 로고
    • Hintzer, K.; Moore, G.; Zipples, T.; Kaspar, H. (3M) WO patent 2007/140112.
    • Hintzer, K.; Moore, G.; Zipples, T.; Kaspar, H. (3M) WO patent 2007/140112.
  • 21
    • 61849171187 scopus 로고    scopus 로고
    • Meyer, M, Hoechst Aktiengesellschaft US Patent 5,208,373
    • Meyer, M. (Hoechst Aktiengesellschaft) US Patent 5,208,373.
  • 22
    • 61849134900 scopus 로고    scopus 로고
    • Koike, N, Matsuda, T, Sato, S, Shin-Etsu Chemical Co, Ltd, US Patent 6,034,207
    • Koike, N.; Matsuda, T.; Sato, S. (Shin-Etsu Chemical Co., Ltd.) US Patent 6,034,207.
  • 26
    • 61849162814 scopus 로고    scopus 로고
    • ns, was seen to evaporate under our work-up procedure, i.e., using rotary evaporator and conditions reported in the Experimental Part (10-20 mmHg/40-50 °C for 5-10 min).
    • ns, was seen to evaporate under our work-up procedure, i.e., using rotary evaporator and conditions reported in the Experimental Part (10-20 mmHg/40-50 °C for 5-10 min).
  • 30
    • 61849131172 scopus 로고    scopus 로고
    • Reaction of acyl fluoride with traces of water may explain the second population of small bumps observed in GC chromatograms (see for instance Figure 1b, These were either eliminated through several washes with water, according to the surfactant behavior or fatty perfluorinated acids ref 15 of this work, prior to analysis or in too low contents to be quantified by 1H NMR
    • 1H NMR.
  • 35
    • 0003495893 scopus 로고    scopus 로고
    • 4th ed, John Wiley & Sons: Hoboken, NJ
    • Odian, G. Principles of Polymerization, 4th ed.; John Wiley & Sons: Hoboken, NJ, 2004; p 384.
    • (2004) Principles of Polymerization , pp. 384
    • Odian, G.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.