Desulfurization of vacuum gasoil by MCM-41 supported molybdenum-nickel catalysts

Industrial and Engineering Chemistry Research

Volumn 48, Issue 4, 2009, Pages 1797-1803

  Ling, Tzong Rong ^a   Wan, Ben Zu ^b   Lin, Hong Ping ^b   Mou, Chung Yuan ^c  

^a I SHOU UNIVERSITY   (Taiwan)

^b NATIONAL TAIWAN UNIVERSITY   (Taiwan)

^c NATIONAL CHENG KUNG UNIVERSITY   (Taiwan)

Author keywords

[No Author keywords available]

Indexed keywords

ATMOSPHERIC TEMPERATURE; CATALYSIS; CATALYST ACTIVITY; CHEMICAL REACTORS; COMPUTER PROGRAMMING; DESORPTION; DYES; FLUID CATALYTIC CRACKING; GAS ADSORPTION; GAS OILS; HYDRODESULFURIZATION; MERCURY (METAL); MESOPOROUS MATERIALS; MOLECULAR SIEVES; MOLYBDENUM; NICKEL ALLOYS; SCANNING ELECTRON MICROSCOPY; SIEVES; SILICA; VACUUM;

ELECTRONIC MICROSCOPIES; HDS ACTIVITIES; HYDRO DESULFURIZATIONS; NICKEL CATALYSTS; NITROGEN ADSORPTION DESORPTIONS; SEM; SI/AL RATIOS; SUPPORTED CATALYSTS; TEM; TEMPERATURE-PROGRAMMING; TRICKLE-BED REACTORS; VACUUM GAS OIL; WEIGHT HOURLY SPACE VELOCITIES; X-RAY DIFFRACTIONS;

CATALYST SUPPORTS;

EID: 61649106014     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie8014389     Document Type: Article

References (42)

1. Sherwood, D. E., Jr. Dai, P.S. E. US patent 5,928,499, 1999.
2. Reddy, K. M.; Wei, B. L.; Song, C. S. Mesoporous Molecular-Sieve MCM-41 Supported Co-Mo Catalyst for Hydrodesulfurization of Petroleum Resids. Catal. Today. 1998, 43, 261-272.
3. Carrado, K. A.; Marshall, C. L.; Brenner, J. R.; Song, K. Materials Derived from Synthetic Organo-Clay Complexes as Novel Hydrodesulfurization Catalyst Supports. Microporous Mesoporous Mater. 1998, 20, 17-26.
4. Rhee, Y. W.; Guin, J. A.; Curtis, C. W. Effects of Pore Structure on Initial Catalystic Activity for Residuum Desulfurization and Coal Liquefaction. Energy Fuels. 1989, 3, 391-397.
5. Li, C.; Chen, Y. W.; Yang, S. J.; Wu, J. C. Hydrodesulfurization Reactions of Atmospheric Gas Oil over CoMo/Alumina-Aluminum Borate Catalysts. Ind. Eng. Chem. Res. 1993, 32, 1573-1578.
6. Aubert, C.; Durand, R.; Geneste, P.; Moreau, C. Hydroprocessing of Dibenzothiophene, Phenothiazine, Phenoxathiin, Thianthrene, and Thioxanthene on a Sulfided. J. Catal. 1986, 97, 169-176.
7. Chen, Y. W.; Tsai, M. C. Hydrodesulfurization of Atomospheric Gas Oil Over NiMo/Alminum Borate Catalysts in a Trickle Bed Reactor. Ind. Eng. Chem. Res. 1997, 36, 2521-2525.
8. Chen, Y. W.; Hsu, W. C. Hydrodemetalation of Residue oil over CoMo/Alumina-Aluminum Phosphate Catalysts in a Trickle Bed Reactor. Ind. Eng. Chem. Res. 1997, 36, 2526-2532.
9. Duan, A.; Wan, G.; Zhao, Z.; Xu, C.; Zheng, Y.; Zhang, Y.; Dou, T.; Bao, X.; Chung, K. Characterization and activity of Mo supported catalysts for diesel deep hydrodesulphurization. Catal Today 2007, 119, 13-18.
10. Tsai, M. C.; Chen, Y. W. Restritive Diffusion under Hydrotreating Reactions of Heavy Residue Oils in a Trickle Bed Reactor. Ind. Eng. Chem. Res. 1993, 32, 1603-1609.
11. Breysse, M.; Afanasiev, P.; Geantet, C.; Vrinat, M. Overview of support effects in hydrotreating catalysts. Catal. Today 2003, 86, 5-16.
12. Turagal, U. T.; Song, C. S. MCM-41-supported Co-Mo catalysts for deep hydrodesulfurization of light cycle oil. Catal. Today 2003, 86, 129-140.
13. Li, X.; Wang, A.; Wang, Y.; Chen, Y.; Liu, Y.; Hu, Y. Hydrodesulfurization of dibenzothiophene over Ni-Mo Sulfides supported by protonexchanged siliceous MCM-41. Catal. Lett. 2002, 84 (1-2), 107-113.
14. Ternan, M.; Rahimi, P. M.; Clugston, D. M.; Dettman, H. M. The +525° Residue Before and After Hydrocracking with Bimodal Catalysts of Varying Macropore. Energy Fuels 1994, 8, 518-530.
15. Wang, W. P.; Guin, J. A. A Comparison of Unimodel and Bimodal Catalyst Deactivation Behavior in a Model Compound System with Rapid Coke Deposition. Fuel Process. Technol. 1991, 28, 149-166.
16. Tsai, M. C.; Chen, Y. W. Restritive Diffusion under Hydrotreating Reactions of Heavy Residue Oils in a Trickle Bed Reactor. Ind. Eng. Chem. Res. 1993, 32, 1603-1609.
17. Marafi, M.; Stanislaus, A. Effect of Initial Coking on Hydrotreating Catalyst Functionalities and Properties. Appl. Catal. A, Gen. 1997, 159 (1-2), 259-267.
18. Kresge, C. T.; Leonowicz, M. E.; Roth, W. J.; Vartuli, J. C.; Beck, J. S. Ordered Mesoporous Molecular-Sieves Synthesized by a Liquid-Crystal Template Mechanism. Nature 1992, 359, 710-712.
19. Sayari, A.; Kruk, M.; Jaroniec, M.; Moudrakovski, I. L. New Approaches to Pore-Size Engineering of Mesoporous Silicates. Adv. Mater. 1998, 10, 1376-1382.
20. Sayari, A. Catalysis by Crystalline Mesoporous Molecular-Sieves. Chem. Mater. 1996, 8, 1840-1852.
21. Corma, A.; Martinez, A.; Martinez-Soria, V.; Monton, J. B. Hydrocracking of Vacuum Gasoil on the Novel Mesoporous MCM-41 Aluminosilicate Catalyst. J. Catal. 1995, 153, 25-31.
22. Carrado, K. A.; Marshall, C. L.; Brenner, J. R.; Song, K. Materials derived from synthetic organo-clay complexes as novel hydrodesulfurization catalyst supports. Microporous Mesoporous Mater. 1998, 20, 17-26.
23. Schacht, P.; Noreña-Franco, L.; Ancheyta, J.; Ramírez, S.; Hernández-Pérez, I.; Garcí, L. A. Characterization of hydrothermally treated MCM-41 and Ti-MCM-41 molecular sieves. Catal. Today 2004, 98, 115-121.
24. Wang, A.; Ruan, L.; Teng, Y.; Li, X.; Lu, M.; Rena, J.; Wang, Y.; Hu, Y. Hydrodesulfurization of dibenzothiophene over siliceous MCM-41-supported nickel phosphide catalysts. J. Catal. 2005, 229, 314-321.
25. Sorensen, A. C.; Fuller, B. L.; Eklund, A. G.; Landry, C. C. MoDoped Mesoporous Silica for Thiophene Hydrodesulfurization: Comparison of Materials and Methods. Chem. Mater. 2004, 16, 2157-2164.
26. 2 catalysts for HDS reactions. Catal. Lett. 2003, 85, 147-151.
27. Cedeño, L.; Hernandez, D.; Klimova, T.; Ramirez, J. Synthesis of Nb-containing mesoporous silica molecular sieves Analysis of its potential use in HDS catalysts. Appl. Catal. A, Gen. 2003, 241, 39-50.
28. 3 Catalysts Prepared by Impregnation and Coprecipitation Methods for Hydrodesulfurization of Dibenzothiophene. J. Phys. Chem. C. 2007, 111, 7396-7402.
29. Yuan, Z. Y.; Su, B. L. Insights into hierarchically mesomacroporous structured materials. J. Mater. Chem. 2006, 16, 663-677.
30. Lin, H. P.; Mou, C. Y. Tubules-within-A-Tubule Hierarchical Order of Mesoporous Molecular-Sieves in MCM-41. Science 1996, 273, 765-768.
31. Lin, H. P.; Cheng, S. F.; Mou, C. Y. Mesoporous Molecular-Sieves MCM-41 with a Hollow Tubular Morphology. Chem. Mater. 1998, 10, 581-589.
32. Ling, T. R.; Wan, B. Z.; Lin, H. P.; Mou, C. Y. Optimum Synthesis Conditions for Tubular Shape MCM-41. The Proceedings of the 12th International Zeolite Conference, 1998, Materials Research Society, 1999; pp 931-938.
33. Lin, H. P.; Cheng, S. F.; Mou, C. Y. Effect of Delayed Neutralization on the Synthesis of Mesoporous MCM-41 Molecular-Sieves. Microporous Mater. 1997, 10, 111-121.
34. Lin, H. P.; Wong, S. T.; Liu, S. B.; Mou, C. Y.; Tang, C. Y. The Synthesis and Characterization of Mesoporous Molecular Sieves MCM-41 with Interconnected Channels. Stud. Surf. Sci. Catal. 2000, 129, 15.
35. Lin, H. P.; Wong, S. T.; Mou, C. Y.; Tang, C. Y. Extensive Void Defects in Mesoporous Aluminosilicate MCM-41. J. Phys. Chem. B. 2000, 104, 8967.
36. Chen, W. H.; Zhao, Q.; Lin, H. P.; Yang, Y. S.; Mou, C. Y.; Liu, S. B. Hydrocracking in Al-MCM-41: diffusion effect. Microporous Mesoporous Mater. 2003, 66, 209-218.
37. Wong, S. T.; Lin, H. P.; Mou, C. Y. Tubular MCM-41 supported Transitional metal oxide Catalytst for Ethylbenzene Dehydrogenation Reaction. Appl. Catal. A, Gen. 2000, 198, 103-114.
38. Lin, H. P.; Mou, C. Y. Structural and Morphological Control of Cationic Surfactant Templated Mesoporous Silica. Acc. Chem. Res. 2002, 35, 927-935.
39. Ren, J.; Wang, A. J.; Li, X.; Chen, Y. Y.; Liu, H.; Hu, Y. K. Hydrodesulfurization of dibenzothiophene catalyzed by Ni-Mo sulfides supported on a mixture of MCM-41 and HY zeolites. Appl. Catal. A, Gen. 2000, 344, 175-182.
40. Tan, Q. F.; Fan, Y.; Liu, H. Y.; Song, T. C.; Shi, G.; Shen, B. J.; Bao, X. J. Bimodal micro-mesoporous aluminosilicates for heavy oil cracking: Porosity tuning and catalytic propertie. AIChE J. 2008,54, 1850-1859.
41. Zheng, J. L.; Zhai, S. R.; Zhang, Y.; Wu, D.; Sun, Y. H.; Yang, Y. X.; Chen, L.; Deng, F. Hydrothermally stable MCM-41 analogue with extensive embedded voids. Catal. Today 2004, 93-95, 529-534.
42. Hsu, Y. C.; Hsu, Y. T.; Hsu, H. Y.; Yang, C. M. Facile synthesis of mesoporous silica SBA-15 with additional intraparticle porosities. Chem. Mater. 2007, 19, 1120-1126.