A simplified three-way catalyst model for transient hot-mode driving cycles

Industrial and Engineering Chemistry Research

Volumn 48, Issue 4, 2009, Pages 1772-1785

  Tsinoglou, Dimitrios N ^a   Weilenmann, Martin ^a  

^a SWISS FEDERAL LABORATORIES FOR MATERIALS SCIENCE AND TECHNOLOGY   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

AUTOMOBILES; CATALYSIS; CONVERSION EFFICIENCY; EXPOSURE CONTROLS; LEAKAGE (FLUID); OXYGEN; POLLUTION; SOLID SOLUTIONS; SURFACE REACTIONS;

CATALYTIC REACTIONS; CHEMICAL PHENOMENON; COMPLEX CHEMICAL PHENOMENON; COMPUTATIONAL LOADS; DEGREE OF CORRELATIONS; DRIVING CYCLES; EMPIRICAL CORRELATIONS; GAS CONDITIONS; LARGE DATABASE; NUMEROUS MODELS; ONE-DIMENSIONAL SIMULATIONS; OXYGEN STORAGES; PARAMETRIZATION; POLLUTANT EMISSIONS; REAL-WORLD; RELEASE DYNAMICS; SIMPLIFIED MATHEMATICAL MODELS; THREE-WAY CATALYSTS; THREE-WAY CATALYTIC CONVERTERS; TRANSFER PHENOMENON;

CATALYTIC CONVERTERS;

EID: 61649087193     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie8010325     Document Type: Article

References (26)

1. 3 three-way catalyst. Appl. Catal. B: Environ. 1998, 19, 245-259.
2. Chatterjee, D.; Deutschmann, O.; Warnatz, J. Detailed surface reaction mechanism in a three-way catalyst. Faraday Discuss. 2001, 119, 371-384.
3. Yamauchi, T. Numerical Simulation for Designing Next Generation TWC System with Detailed Chemistry Numerical Simulation for Designing Next Generation TWC System with Detailed Chemistry; SAE Paper 2008-01-1540; SÁE International: Warrendale, PA, 2008.
4. Oh, S.; Cavendish, J. Transients of Monolithic Catalytic Converters: Response to Step Changes in Feedstream Temperature as Related to Controlling Automobile Emissions. Ind. Eng. Chem. Prod. Res. Dev. 1982, 21, 29-37.
5. Voltz, S. E.; Morgan, C. R.; Liederman, D.; Jacob, S. M. Kinetic study of carbon monoxide and propylene oxidation on platinum catalysis. Ind. Eng. Chem. Prod. Res. Dev. 1973, 12, 294-301.
6. Herz, R. K.; Klela, J. B.; Sell, J. A. Dynamic Behavior of Automotive Catalysts. 2. Carbon Monoxide Conversion under Transient Air/Fuel Ratio Conditions. Ind. Eng. Chem. Prod. Res. Dev. 1983, 22, 387-396.
7. Taylor, K. C.; Sinkevitch, R. M. Behavior of Automobile Exhaust Catalysts with Cycled Feedstreams. Ind. Eng. Chem. Prod. Res. Dev. 1983, 22, 45-51.
8. Silveston, P. L. Automotive exhaust catalysis: Is periodic operation beneficial? Chem. Eng. Sci. 1996, 51, 10, 2419-2426.
9. Jackson, R. A.; Peyton Jones, J. C.; Pan, J.; Roberts, J. B.; Childs, P. R. N. Chemical Aspects of the Dynamic Performance of a Three-Way Catalyst; SAE Paper 1999-01-312; SAE International: Warrendale, PA, 1999.
10. Fisher, G. B.; Theis, J. R.; Casarella, M. V.; Mahan, S. T. The Role of Ceria in Automotive Exhaust Catalysis and OBD-II Catalyst Monitoring; SAE Paper 931034; SAE International: Warrendale, PA, 1993.
11. Koltsakis, G. C.; Konstantinidis, P. A.; Stamatelos, A. M. Development and Application Range of Mathematical Models for 3-Way Catalytic Converters. Appl Catal. B: Environ. 1997, 12, 161-191.
12. Tsinoglou, D. N.; Koltsakis, G. C.; Peyton Jones, J. C. Oxygen Storage Modeling in Three-Way Catalytic Converters. Ind. Eng. Chem. Res. 2002, 41, 1152-1165.
13. Pontikakis, G. N.; Konstantas, G. S.; Stamatelos, A. M. Three-way catalytic converter modeling as a modern engineering design tool. J. Eng. Gas Turbines Power 2004, 126, 4, 906-923.
14. Holder, R.; Bollig, M.; Anderson, D.; Hochmuth, J. Chem. Eng. Sci. 2006, 61, 8010-8027.
15. Wanker, R.; Wurzenberger, J.; Schuemie, H. Three-Way Catalyst Light-off during the NEDC Test Cycle: Fully Coupled 0D/1D Simulation of Gasoline Combustion, Pollutant Formation and Aftertreatment Systems; SAE Paper 2008-01-1755; SAE International: Warrendale, PA, 2008.
16. Muske, K. R.; Peyton Jones, J. C. Multi-objective model-based control for an automotive catalyst. J. Process Control 2006, 16, 27-35.
17. Soumelidis, M.; Stobart, R.; Jackson, R. Proc. Inst. Mech. Eng. D: J. Automob. Eng. 2007, 221, 1169-1182.
18. André, M. The ARTEMIS European driving cycles for measuring car pollutant emissions. Sci. Total Environ. 2004, 334-335, 73-84.
19. De Haan, P.; Keller, M. Real-world driving cycles for emission measurements: ARTEMIS and Swiss cycles; FOEN Report SRU No. 255; Swiss Federal Office for the Environment (FOEN): Bern, Switzerland, 2001. Available online at http://www.bafu.admin.ch/luft/00596/00597/00604/ (accessed Oct 2008).
20. Ajtay, D.; Weilenmann, M. Compensation of the Exhaust Gas Transport Dynamics for Accurate Instantaneous Emission Measurements. Environ. Sci. Technol. 2004, 38, 5141-5148.
21. Brettschneider, J. Berechnung des Luftverhältnisses λ von Luft-Kraftstoff-Gemischen und des Einflusses von Messfehlern auf λ. Bosch Technol. Ber. 1979, 6, 177-186.
22. Heywood, J. B. Internal Combustion Engine Fundamentals; McGraw-Hill: New York, 1988; pp 152-153.
23. Incropera, F.; DeWitt, D. Introduction to Heat Transfer, 4th ed.; Wiley: New York, 2002.
24. Dubien, C.; Schweich, D.; Mabilon, G.; Martin, B.; Prigent, M. Three-way catalytic converter modelling: Fast- and slow-oxidizing hydrocarbons, inhibiting species, and steam-reforming reaction. Chem. Eng. Sci. 1997, 53 (3), 471-483.
25. Ajtay, D.; Weilenmann, M; Soltic, P. Towards accurate instantaneous emission models. Atmos. Environ. 2005, 39, 2443-2449.
26. Hausberger, S.; Rodler, J.; Sturm, P.; Rexeis, M. Emission factors for heavy-duty vehicles and validation by tunnel measurements. Atmos. Environ. 2003, 37, 5237-5245.