DC and AC voltammetry of a free-base porphyrin adsorbed onto basal-plane graphite under acidic conditions: An example of a close to ideal reversible two-electron surface-confined redox process at sub-monolayer coverages

Electrochimica Acta

Volumn 54, Issue 10, 2009, Pages 2713-2719

  Fleming, Barry D ^a   Bond, Alan M ^a  

^a MONASH UNIVERSITY   (Australia)

Author keywords

AC voltammetry; Diffusionless; Large amplitude; Porphyrin; Sine wave

Indexed keywords

ELECTRON TRANSITIONS; GRAPHITE; GRAPHITE ELECTRODES; PORPHYRINS; RATE CONSTANTS; SODIUM CHLORIDE;

AC VOLTAMMETRY; ACIDIC CONDITIONS; ADSORBED LAYERS; AG/AGCL; DICATION; DIFFUSIONLESS; ELECTRON SURFACES; ELECTRON TRANSFER PROCESS; ELECTRON-TRANSFER KINETICS; EXPERIMENTAL DATUM; FAST ELECTRON TRANSFERS; FOURIER; HIGHER HARMONICS; LARGE-AMPLITUDE; MONOLAYER SURFACES; NON IDEALITIES; OXIDATION AND REDUCTIONS; PORPHINE; PROTONATED; PYRIDYL; REACTION MECHANISMS; REDOX PROCESS; REVERSIBLE POTENTIALS; SCAN RATES; SINE-WAVE; SUB-MONOLAYER COVERAGES; SUPPORTING ELECTROLYTES; TETRAKIS; TWO-ELECTRON PROCESS; TWO-ELECTRON REDUCTIONS; VOLTAMMETRIC;

CYCLIC VOLTAMMETRY;

EID: 61449252912     PISSN: 00134686     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.electacta.2008.11.042     Document Type: Article

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