Steroid isotopic standards for gas chromatography-combustion isotope ratio mass spectrometry (GCC-IRMS)

Steroids

Volumn 74, Issue 3, 2009, Pages 369-378

  Zhang, Ying ^a   Tobias, Herbert J ^a   Brenna, J Thomas ^a  

^a Department of Obstetrics Gynecology   (United States)

Author keywords

Anti doping test; Isotope ratio mass spectrometry (IRMS); Steroid isotopic standards

Indexed keywords

5 ALPHA ANDROSTAN 3BETA OL ACETATE; 5 ALPHA CHOLESTANE; 5ALPHA ANDROSTAN 3ALPHA OL 17 ONE ACETATE; 5BETA ANDROSTAN 3ALPHA OL 11, 17 DIONE ACETATE; 5BETA PREGNANE 3ALPHA,20 ALPHA DIOL; ACETIC ACID DERIVATIVE; ANDROSTERONE; ETIOCHOLANOLONE; PREGNANE DERIVATIVE; STEROID; UNCLASSIFIED DRUG;

AMPOULE; ARTICLE; CALIBRATION; CLINICAL PROTOCOL; CONTAMINATION; DOPING; DRUG ISOLATION; DRUG MIXTURE; FRACTIONATION; GAS CHROMATOGRAPHY; GAS CHROMATOGRAPHY COMBUSTION ISOTOPE RATIO MASS SPECTROMETRY; GENETIC CODE; INTERNATIONAL STANDARD UNIT; ISOTOPE ANALYSIS; LABORATORY TEST; MASS SPECTROMETRY; NORMAL VALUE; REPRODUCIBILITY; STANDARD; STEROID ANALYSIS; STEROID EXCRETION; STEROID URINE LEVEL;

CARBON ISOTOPES; GAS CHROMATOGRAPHY-MASS SPECTROMETRY; HUMANS; MODELS, THEORETICAL; REFERENCE STANDARDS; STEROIDS;

BELEMNOIDEA;

EID: 61349184438     PISSN: 0039128X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.steroids.2008.10.001     Document Type: Article

References (19)

1. Bowers L.D. Analytical advances in detection of performance enhancing compounds. Clin Chem 43 (1997) 1299-1304
2. Aguilera R., Chapman T.E., and Catlin D.H. A rapid screening assay for measuring urinary androsterone and etiocholanolone delta(13)C (per thousand) values by gas chromatography/combustion/isotope ratio mass spectrometry. Rapid Comm Mass Spectrom 14 (2000) 2294-2299
3. Donike M., Barwald K.R., Klostermann K., Schanzer W., and Zimmermann J. The detection of exogenous testosterone. Int J Sports Med 4 (1983) 68
4. Cawley A.T., Kazlauskas R., and Trout G.J. Catching the cheats: advances in the detection of endogenous steroid abuse in sport. Chem in Australia 73 (2006) 3-7
5. Shackleton C.H., Phillips A., Chang T., and Li Y. Confirming testosterone administration by isotope ratio mass spectrometric analysis of urinary androstanediols. Steroids 62 (1997) 379-387
6. Murphey B.F. The temperature variation of the thermal diffusion factors for binary mixtures of hydrogen, deuterium, and Helium. Phys Rev 72 (1947) 834-837
7. McKinney C.R., McCrea J.M., Epstein S., Allen H.A., and Urey H.C. Improvements in mass spectrometers for the measurement of small differences in isotope abundance ratios. Rev Sci Instrum 21 (1950) 724-730
8. Matthews D.E., and Hayes J.M. Isotope-ratio-monitoring gas chromatography-mass spectrometry. Anal Chem 50 (1978) 1465-1473
9. Sano M., Yotsui Y., Abe H., and Sasaki S. New technique for detection of metabolites labeled by isotope C-13 using mass fragmentography. Biomed Mass Spectrom 3 (1976) 1-3
10. Becchi M., Aguilera R., Farizon Y., Flament M.M., Casabianca H., and James P. Gas chromatography/combustion/isotope-ratio mass spectrometry analysis of urinary steroids to detect misuse of testosterone in sport. Rapid Commun Mass Spectrom 8 (1994) 304-308
11. Kleemann A., and Roth H.J. Arzneistoffgewinnung: Natrustoffe und Derivate (1983), Thieme, Stuttgart
12. Vogel J.C. Fractionation of the carbon isotopes during photosynthesis (1980), Springer-Verlag, Berlin, Heidelberg, New York
13. Farquhar G.D. On the nature of carbon isotope discrimination in species. Australian J Plant Physiol 10 (1983) 205-226
14. WADA Laboratory Committee. Reporting and Evaluation Guidance for Testosterone, Epitestosterone, T/E Ratio and Other Endogenous Steroids. World Anti-doping Agency, Montreal. WADA Document TD2004EAAS. 2004; http://www.wada-ama.org/rtecontent/document/criteria_1_2.pdf.
15. Anonymous. Harmonization of Inter-laboratory Results. Second Annual USADA Symposium on Anti-Doping Science: Application of Gas Chromatography-Combustion-Isotope Ratio Mass Spectrometry to Doping Control. Los Angeles, Ca, 2003:103-4.
16. Caimi R.J., Houghton L.A., and Brenna J.T. Condensed-phase carbon isotopic standards for compound-specific isotope analysis. Anal Chem 66 (1994) 2989-2991
17. Brenna J.T., Corso T.N., Tobias H.J., and Caimi R.J. High-precision continuous-flow isotope ratio mass spectrometry. Mass Spectrom Rev 16 (1997) 227-258
18. Meier-Augenstein W. A reference gas inlet module for internal isotopic calibration in high preision gas chromatography/combustion-isotope ratio mass spectrometry. Rap Comm Mass Spectrom 11 (1997) 1775-1780
19. Anonymous. National Institute of Standards & Technology, Gaithersburg, MD 20899. 2004; http://www.cstl.nist.gov/div837/837.01/outputs/standards/NGS.pdf (access date 06.10.2008).