Studies on the molecular flexibility of novel dendronized carboxymethyl cellulose derivatives

European Polymer Journal

Volumn 45, Issue 4, 2009, Pages 1098-1110

  Pohl, Matthias ^a,b   Morris, Gordon A ^c   Harding, Steve E ^c   Heinze, Thomas ^a,b  

^a Thuringian Institute for Textile and Plastics Research   (Germany)

^b FRIEDRICH SCHILLER UNIVERSITY JENA   (Germany)

^c UNIVERSITY OF NOTTINGHAM   (United Kingdom)

Author keywords

Cellulose; Conformation analysis; Dendronization; Dendronized cellulose; Polysaccharides; Ultracentrifugation

Indexed keywords

BIOPOLYMERS; CELLULOSE DERIVATIVES; CENTRIFUGATION; DENDRIMERS; DIELECTRIC RELAXATION; LAND USE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLYMERS; POLYSACCHARIDES; SYNTHESIS (CHEMICAL); ZONING;

CARBOXY METHYL CELLULOSE; CARBOXYMETHYL; CARBOXYMETHYLATION; CONFORMATION ANALYSIS; DEGREE OF SUBSTITUTIONS; DENDRONIZATION; DENDRONIZED CELLULOSE; FLEXIBLE COILS; GLOBAL METHODS; INTRINSIC VISCOSITIES; IR AND NMR SPECTROSCOPIES; MOLECULAR FLEXIBILITIES; PERSISTENCE LENGTHS; POLYAMIDOAMINE; SEDIMENTATION COEFFICIENTS; SOLUTION CONFORMATIONS; STARTING MATERIALS; THIRD GENERATIONS; ULTRACENTRIFUGATION;

CELLULOSE;

CARBOXYMETHYL CELLULOSE; CARBOXYMETHYLATION; CELLULOSE DERIVATIVES; CENTRIFUGATION; FLEXIBILITY; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE; POLYSACCHARIDES; RELAXATION; SEDIMENTATION;

EID: 61349158011     PISSN: 00143057     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.eurpolymj.2009.01.009     Document Type: Article

References (45)

1. Heinze Th. Chemical Functionalization of Cellulose. In: Dumitriu S. (editor). Polysaccharides: Structural Diversity and Functional Versatility, 2nd ed. New York, Basel, Hong Kong: Marcel Dekker, Inc.; 2004. p. 551-590 and references cited therein.
2. Klemm D., Heublein B., Fink H.-P., and Bohn A. Cellulose: faszinierendes Biopolymer und nachhaltiger Rohstoff. Angew Chem 117 (2005) 3422-3458
3. Liebert T., and Heinze T. Tailored Cellulose Esters: Synthesis and Structure Determination. Biomacromolecules 6 (2005) 333-340
4. Pohl M, Schaller J, Meister F, Heinze Th. Novel Bulky Esters of Biopolymers: Dendritic Cellulose. Macromol Symp 2008;262:119-128 and references cited therein.
5. Zhang C., Price L.M., and Daly W.H. Synthesis and Characterization of a Comp Copolymer with a Cellulose Backbone and with Hydrophilic Brushes on Amphiphilic Teeth. Polym Prepr 45 (2004) 421-422
6. Zhang C., and Daly W.H. Synthesis and Characterization of a Trifunctional Aminoamide Cellulose Derivative. Polym Prepr 46 (2005) 707
7. Zhang C., Daly W.H., and Price L.M. Synthesis and Characterization of a Trifunctional Aminoamide Cellulose Derivative. Biomacromolecules 7 (2006) 139-145
8. Hassan M.L., Moorefield C.N., and Newkome G.R. Regioselective Dendritic Functionalization of Cellulose. Macromol Rapid Commun 25 (2004) 1999-2002
9. Hassan M.L., Moorefield C.N., Kotta K.K., and Newkome G.R. Regioselective combinatorial-type synthesis, characterization, and physical properties of dendronized cellulose. Polymer 46 (2005) 8947-8955
10. Pohl M., Schaller J., Meister F., and Heinze T. Selectively Dendronized Cellulose: Synthesis and Characterization. Macromol Rapid Commun 29 (2008) 142-148
11. Heinze T., Schöbitz M., Pohl M., and Meister F. Interactions of Ionic Liquids with Polysaccharides. IV. Dendronization of 6-Azido-6-Deoxy Cellulose. J Polym Sci Part A: Polym Chem 46 (2008) 3853-3859
12. Pohl M., and Heinze T. Novel biopolymer structures synthesized by dendronization of 6-deoxy-6-amino-propargyl cellulose. Macromol Rapid Commun 29 (2008) 1739-1745
13. Östmark E., Lindqvist J., Nyström D., and Malmström E. Dendronized Hydroxypropyl Cellulose: Synthesis and Characterization of Biobased Nanoobjects. Biomacromolecules 8 (2007) 3815-3822
14. Klemm D, Philipp B, Heinze Th, Heinze U, Wagenknecht W. Comprehensive cellulose chemistry. Vol 2: Functionalization of cellulose. Chichester: Wiley; 1998. p. 221.
15. Schlüter AD, Rabe JP. Dendronisierte Polymere: Synthese, Charakterisierung, Grenzflächenverhalten und Manipulation. Angew Chem 2000;112:860-880. and references cited therein.
16. Heinze T., Koschella A., Brackhagen M., Engelhardt J., and Nachtkamp K. Studies on Non-natural Deoxyammonium Cellulose. Macromol Symp 244 (2006) 74-82
17. Liebert T., Hänsch C., and Heinze T. Click Chemistry with Polysaccharides. Macromol Rapid Commun 27 (2006) 208-213
18. Harding SE. Analysis of polysaccharides size, shape and interactions. In: Scott DJ, Harding SE, Rowe AJ. (editors) Analytical ultracentrifugation techniques and methods. Cambridge: Royal Society of Chemistry; 2005. p. 231-252.
19. Schuck P. Sedimentation analysis of noninteracting and self-associating solutes using numerical solutions to the Lamm equation. Biophys J 75 (1998) 1503-1512
20. Ralston G. Introduction to analytical ultracentrifugation. Palo Alto: Beckman Instruments, Inc.; 1993. p. 27.
21. Pavlov G.M., Michaeilova N., Tarabukina E., and Korneeva E. Velocity sedimentation of water-soluble methyl cellulose. Prog Colloid Polym Sci 99 (1995) 109-113
22. Gralén N. Sedimentation and diffusion measurements on cellulose and cellulose derivatives, Ph.D. Dissertation. Sweden: University of Uppsala; 1944.
23. Rowe A.J. The concentration dependence of transport processes: a general description applicable to the sedimentation, translational diffusion and viscosity coefficients of macromolecular solutes. Biopolymers 16 (1977) 2595-2611
24. Rahn K., Diamantoglou M., Klemm D., Berghmans H., and Heinze T. Homogeneous synthesis of cellulose p-toluenesulfonates in N,N-dimethylacetamide/LiCl solvent system. Angew Makromol Chem 238 (1996) 143-163
25. Lee J.W., Kim J.H., and Kim B.K. Synthesis of azide-functionalized PAMAM dendrons at the focal point and their application for synthesis of PAMAM-like dendrimers. Tetrahedron Lett 47 (2006) 2683-2686
26. Lee J.W., Kim J.H., Han S.C., Kim W.R., Kim B.K., Kim J.H., Huh D.S., Shin W.S., and Jin S.-H. Synthesis of Diblock Codendrimers by Fusion of the Fréchet-Type and the PAMAM Dendrons. Macromol Symp 249-250 (2007) 357-364
27. Lee J.W., Kim B.K., Kim H.J., Han S.C., Shin W.S., and Jin S.-H. Convergent Synthesis of Symmetrical and Unsymmetrical PAMAM Dendrimers. Macromolecules 39 (2006) 2418-2422
28. Eyler R.W., Klug E.D., and Diephuis F. Determination of Degree of Substitution of Sodium Carboxymethylcellulose. Anal Chem 19 (1947) 24-27
29. Heinze T., and Pfeifer K. Studies on the synthesis and characterization of Carboxymethylcellulose. Angew Macromol Chem 266 (1999) 37-45
30. Ottiviani M.F., Montalti F., Turro N.J., and Tomalia D.A. Characterization of Starburst Dendrimers by the EPR Technique. Copper(II) Ions Binding Full-Generation Dendrimers. J Phys Chem B 101 (1997) 158-166
31. Balogh L, Tomalia DA. Poly(Amidoamine) Dendrimer-Templated Nanocomposites. 1. Synthesis of Zerovalent Copper Nanoclusters. J Am Chem Soc 1998;120:7355-7356. and references cited therein.
32. Arndt KF, Müller G. Polymercharakterisierung. München: Hanser Fachbuchverlag; 1996. p. 344.
33. Kulicke W.M., Kull A.H., Kull W., and Thielking H. Characterization of aqueous carboxymethylcellulose solutions in terms of their molecular structure and its influence on rheological behaviour. Polymer 37 13 (1996) 2723-2731
34. Tanford C. Physical chemistry of macromolecules (1961), John Wiley and Sons, New York
35. Ortega A., and García de la Torre J. Equivalent radii and ratios of radii from solution properties as indicators of macromolecular conformation, shape, and flexibility. Biomacromolecules 8 (2007) 2464-2475
36. Pavlov G.M., Rowe A.J., and Harding S.E. Conformation zoning of large molecules using the analytical ultracentrifuge. Trends Anal Chem 16 (1997) 401-405
37. Kratky O., and Porod G. Röntgenuntersuchung gelöster Fadenmoleküle. Recl Trav Chim Pays-Bas 68 (1949) 1106-1109
38. Tombs M.P., and Harding S.E. An introduction to polysaccharide biotechnology (1998), Taylor and Francis, London p. 14
39. Bushin S.V., Tsvetkov V.N., Lysenko J.B., and Emel'yanov V.N. Conformational properties and rigidity of molecules of ladder polyphenylsiloxane in solutions according the data of sedimentation-diffusion analysis and viscometry. Vysokomol Soedin A23 (1981) 2494-2503
40. Bohdanecky M. New method for estimating the parameters of the wormlike chain model from the intrinsic viscosity of stiff-chain polymers. Macromolecules 16 (1983) 1483-1493
41. Hearst J.E. Rotatory diffusion constants of stiff-chain macromolecules. J Chem Phys 38 (1963) 1062-1065
42. Stockmayer W.H., and Fixman M.J. On the estimation of unperturbed dimensions from intrinsic viscositiesxcin. J Polym Sci Part C 1 (1963) 137-141
43. Yamakawa H., and Fujii M. Translational friction coefficient of wormlike chains. Macromolecules 6 (1973) 407-415
44. Hearst J.E., and Stockmayer W.H. Sedimentation constants of broken chains and wormlike coils. J Chem Phys 37 (1962) 1425-1433
45. Patel T.R., Morris G.A., García de la Torre J., Ortega A., Mischnick P., and Harding S.E. Molecular Flexibility of Methylcelluloses of Differing Degree of Substitution by Combined Sedimentation and Viscosity Analysis. Macromol Biosci 8 (2008) 1108-1115