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13
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60849091571
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3S: C, 53.72 (53.61); H, 5.68 (5.75); N, 9.28 (9.13).
-
3S: C, 53.72 (53.61); H, 5.68 (5.75); N, 9.28 (9.13).
-
-
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14
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60849088210
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3S: C, 55.14 (55.34); H, 6.06 (6.09); N, 8.87 (8.87).
-
3S: C, 55.14 (55.34); H, 6.06 (6.09); N, 8.87 (8.87).
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15
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60849083771
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Characterization of 3. UV-vis (MeCN, λmax (εM) 348 (452, 382 (358, 394 (363, 406 (369, 424 (258, 438 (224, Anal. Calcd (found) for C29H32CrF9N 4O3S: C, 47.09 (47.12, H, 4.36 (4.36, N, 7.57 (7.45, b) For this synthesis, a 2:1 ratio of LiCCC6H4CF 3 to [Cr(cyclam)(OTf)2]OTf was used
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2]OTf was used.
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60849106930
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2) = 0.206.
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2) = 0.206.
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a value of more than 7 units lower than either ethynylbenzene or 4-ethynyltoluene. Böhm, S.; Parík, P.; Exner, O. New J. Chem. 2006, 30, 384-391.
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