The spectroscopic characterization of the methoxy radical. II. Rotationally resolved à 2A1- X̃ 2E electronic and X̃ 2E microwave spectra of the perdeuteromethoxy radical CD3O

Journal of Chemical Physics

Volumn 130, Issue 7, 2009, Pages

  Liu, Jinjun ^a,d   Chen, Ming Wei ^a   Melnik, Dmitry ^a   Miller, Terry A ^a   Endo, Yasuki ^b   Hirota, Eizi ^c  

^a OHIO STATE UNIVERSITY   (United States)

^b UNIVERSITY OF TOKYO   (Japan)

^c GRADUATE UNIVERSITY FOR ADVANCED STUDIES   (Japan)

^d ETH ZURICH   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRONIC STATES; EMISSION SPECTROSCOPY; LASER PRODUCED PLASMAS; MICROWAVES; PUMPING (LASER);

ACTIVE MOLECULES; CONICAL INTERSECTIONS; EFFECTIVE HAMILTONIANS; EXPERIMENTAL EVIDENCES; GLOBAL FITTINGS; GROUND ELECTRONIC STATE; HIGH PRECISION; HYPERFINE; HYPERFINE STRUCTURES; JAHN TELLERS; LASER-INDUCED FLUORESCENCES; METHOXY; MICROWAVE REGIONS; MICROWAVE SPECTRUMS; MICROWAVE TRANSITIONS; MOLECULAR CONSTANTS; MOLECULAR PARAMETERS; PHYSICAL SIGNIFICANCES; ROTATIONAL CONSTANTS; ROTATIONAL SPECTRUM; SPECTROSCOPIC CHARACTERIZATIONS; SPIN ORBITS; STIMULATED EMISSION PUMPING; VIBRATIONAL CORRECTIONS;

HAMILTONIANS;

EID: 60749119471     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.3072105     Document Type: Article

References (29)

1. J. Liu, M. -W. Chen, D. Melnik, J. T. Yi, and T. A. Miller, J. Chem. Phys. 130, 074302 (2009). 0021-9606
2. T. Momose, Y. Endo, E. Hirota, and T. Shida, J. Chem. Phys. 0021-9606 10.1063/1.454593 88, 5338 (1988).
3. Y. -C. Hsu, X. Liu, and T. A. Miller, J. Chem. Phys. 0021-9606 10.1063/1.456258 90, 6852 (1989).
4. T. -Y. D. Lin, X. Q. Tan, T. M. Cerny, J. M. Williamson, D. W. Cullin, and T. A. Miller, Chem. Phys. 0301-0104 10.1016/0301-0104(92)80035-T 167, 203 (1992).
5. T. M. Cerny, X. Q. Tan, J. M. Williamson, E. S. J. Robles, A. M. Ellis, and T. A. Miller, J. Chem. Phys. 0021-9606 10.1063/1.465521 99, 9376 (1993).
6. R. Rubino, J. M. Williamson, and T. A. Miller, J. Chem. Phys. 0021-9606 10.1063/1.470476 103, 5964 (1995).
7. A. H. Blatt, Organic Synthesis II (Wiley, New York, 1963).
8. Y. Endo, S. Saito, and E. Hirota, J. Chem. Phys. 0021-9606 10.1063/1.447375 81, 122 (1984).
9. See EPAPS Document No. E-JCPSA6-130-016905 for 17 pages of auxiliary material including hyperfine resolved microwave data not involved in the hyperfine-free analysis, additional SRCD terms, hyperfine-free microwave, LIF, and SEP transition-frequency data used in global fits. For more information on EPAPS, see http://www.aip.org/pubservs/epaps.html.
10. B. E. Applegate, M. B. Pushkarsky, and T. A. Miller, J. Phys. Chem. 0022-3654 10.1021/jp984141n 103, 1538 (1999).
11. V. W. Laurie, J. Chem. Phys. 0021-9606 10.1063/1.1744218 28, 704 (1958).
12. V. W. Laurie and D. R. Herschbach, J. Chem. Phys. 0021-9606 10.1063/1.1733358 37, 1687 (1962).
13. J. S. Muenter and V. W. Laurie, J. Chem. Phys. 0021-9606 10.1063/1.1727694 45, 855 (1966).
14. X. Liu, L. Yu, and T. A. Miller, J. Mol. Spectrosc. 0022-2852 10.1016/0022-2852(90)90010-N 140, 112 (1990).
15. D. Melnik, J. Liu, M. -W. Chen, and T. A. Miller (to be published).
16. A. V. Marenich and J. E. Boggs, J. Mol. Struct. 780-781, 163 (2006). 0021-9606
17. U. Höper, P. Botschwina, and H. Köppel, J. Chem. Phys. 0021-9606 10.1063/1.480998 112, 4132 (2000).
18. T. Momose, Y. Endo, E. Hirota, and T. Shida, J. Chem. Phys. 0021-9606 10.1063/1.456703 90, 4636 (1989).
19. X. Liu, S. C. Foster, J. M. Williamson, L. Yu, and T. A. Miller, Mol. Phys. 0026-8976 10.1080/00268979000100251 69, 357 (1990).
20. S. C. Foster, P. Misra, T. -Y. D. Lin, C. P. Damo, C. C. Carter, and T. A. Miller, J. Phys. Chem. 0022-3654 10.1021/j100332a014 92, 5914 (1988).
21. J. K. G. Watson, J. Mol. Spectrosc. 0022-2852 10.1016/0022-2852(84)90152- 8 103, 125 (1984).
22. D. Papousek and M. R. Aliev, Molecular Vibrational-Rotational Spectra (Elsevier, Amsterdam, 1982).
23. T. A. Barckholtz and T. A. Miller, Int. Rev. Phys. Chem. 0144-235X 10.1080/014423598230036 17, 435 (1998).
24. T. A. Barckholtz and T. A. Miller, J. Phys. Chem. 0022-3654 10.1021/jp983829x 103, 2321 (1999).
25. M. S. Child and H. L. Strauss, J. Chem. Phys. 0021-9606 10.1063/1.1696289 42, 2283 (1965).
26. G. Herzberg, H. Lew, J. J. Sloan, and J. K. G. Watson, Can. J. Phys. 59, 428 (1981). 0008-4204
27. L. Halonen, J. Kauppinen, and G. L. Caldow, J. Chem. Phys. 0021-9606 10.1063/1.447926 81, 2257 (1984).
28. G. Graner, Mol. Phys. 0026-8976 10.1080/00268977600101441 31, 1833 (1976).
29. X. Liu, C. P. Damo, T. -Y. Lin, S. C. Foster, P. Misra, L. Yu, and T. A. Miller, J. Phys. Chem. 0022-3654 10.1021/j100343a016 93, 2266 (1989).