An experimental study on the free-radical copolymerization kinetics with crosslinking of styrene and diwinylbemene in supercritical carbon dioxide

Macromolecular Reaction Engineering

Volumn 3, Issue 1, 2009, Pages 58-70

  García Moran, Pedro R ^a   Jaramillo Soto, Gabriel ^a   Albores Velasco, Martha E ^a   Vivaldo Lima, Eduardo ^a  

^a UNIVERSIDAD NACIONAL AUTÓNOMA DE MÉXICO   (Mexico)

Author keywords

Copolymerization; Crosslinking; Dispersion polymerization; Poly(styrene co divinyibenzene); Supercritical carbon dioxide

Indexed keywords

CARBON DIOXIDE; CHEMICAL REACTIONS; CORUNDUM; FREE RADICAL POLYMERIZATION; GELATION; METAL CASTING; POLYMERS; POLYSTYRENES; SAPPHIRE; SILICONES; STYRENE; SUPERCRITICAL FLUID EXTRACTION;

DISPERSION POLYMERIZATION; EXPERIMENTAL STUDIES; FREE-RADICAL COPOLYMERIZATION KINETICS; GEL CONTENTS; MONOMER CONVERSIONS; PARTICLE PROPERTIES; PARTICLE SIZE DISTRIBUTIONS; POLY(STYRENE-CO-DIVINYIBENZENE); POLYMER PRODUCTS; POLYMERIZATION RATES; PROCESS CONDITIONS; REACTING MIXTURES; SAPPHIRE WINDOWS; SOL FRACTIONS; SPHERICAL PARTICLES; SUPERCRITICAL CARBON DIOXIDE;

COPOLYMERIZATION;

EID: 60749083283     PISSN: 1862832X     EISSN: 18628338     Source Type: Journal    
DOI: 10.1002/mren.200800031     Document Type: Article

References (27)

1. I, A. Hyatt, J. Org. Chem. 1984, 49, 5097.
2. C. A. Eckert, B. L. Knutson, P. G. Debenedetti, Nature 1996, 373, 313.
3. W. Leitner, Nature 2000, 405, 129.
4. U. Michel, P. Resnick, B. Kipp, J. M. DeSimone, Macmmolecules 2003, 36, 7107.
5. J. Tiihonen, M. Laatikainen, I. Markkanen, E. Paatero, Ind. Eng. Chem. Res. 1999, 38, 4832.
6. M. Iborra, I. Tejero, F. Cunill, J. F. Izquierdo, C. Fité, Ind. Eng. Chem. Res. 2000, 39, 1416.
7. H. Li, Y. Jiao, M. Xu, Z. Shi, B. He, Polymer 2004, 45, 181.
8. E. Tuinman, N. T. McManus, M. Roa-Luna, E. Vivaldo-Lima, L M. F. Lona, A. Penlidis, J. Macromol Sci., Pure Appl. Chem. 2006, 43, 995.
9. F. C. Huang, I. C. H. Ke, C. Y. Kao, W. C. Lee, J. Appl Polym. Sci. 2001, 80, 39.
10. S. E. Shim, S. Yang, M. J. Jin, Y. H. Chang, S. Choe, Colloid Polym. Sci. 2004, 283, 41.
11. R. Okasha, G. Hild, P. Rempp, Eur. Polym. J. 1979, 15, 975.
12. G. Hild, R. Okasha, Makmmol. Chem. 1985, 186, 93.
13. G. Hild, R. Okasha, P. Rempp, Makmmol Chem. 1985, 186, 407.
14. G. L. Batch, C. W. Macosko, J. Appl. Polym. Sci 1992, 44, 1711.
15. B. T. Storey, J. Polym. Sci, Part A: Polym. Chem. 1965, 3, 265.
16. I. Malinsky, J. Klaban, K. Duse'k, J. Macromol. Sci., Chem. 1971, A5, 1071.
17. E. Vivaldo-Lima, P. E. Wood, A. E. Hamielec, A. Penlidis, J. Polym. Sei., Polym. Chem. 1998, 36, 2081.
18. F. H. Winslow, W. Matreyek, Ind. Eng. Chem. 1951, 43, 1108.
19. T. Balakrishnan, W. T. Ford, J. Appl. Polym. Sci. 1982, 27, 135.
20. D. E. Leng, G. J. Quarderer, Chem. Eng. Commun. 1982, 14, 177.
21. J. C. Watters, T. G. Smith, Ind. Eng. Chem. Process Des. Dev. 1979, 18, 591.
22. A. I. Cooper, W. P. Hems, A. B. Holmes, Macromol. Rapid Commun. 1998, 19, 353.
23. A. I. Cooper, W. P. Hems, A. B. Holmes, Macmmolecules 1999, 32, 2156.
24. S. D. Smith, J. M. DeSimone, H. Huang, G. York, D. W. Dwight, G. L. Wilkes, J. E. McGrath, Macmmolecules 1992, 25, 2575.
25. I. G. Zilliox, I. E. L. Roovers, S. Bywaters, Macmmolecules 19 75, 8, 573.
26. J. C. Saam, D. J. Gordon, S. Lindsey, Macmmolecules 1970, 3, 1.
27. P. I. Flory, I. A. Semlyen, J. Am. Chem. Soc. 1966, 88, 3209.