Ultra small-angle X-ray scattering studies on structural changes in micrometers upon uniaxial stretching of segmented polyurethaneureas

Polymer

Volumn 50, Issue 6, 2009, Pages 1566-1576

  Sakurai, Shinichi ^a   Yoshida, Hidekazu ^a   Hashimoto, Fumio ^a   Shibaya, Miaki ^a   Ishihara, Hideaki ^a   Yoshihara, Nori ^b   Nishitsuji, Shotaro ^c   Takenaka, Mikihito ^c  

^a KYOTO INSTITUTE OF TECHNOLOGY   (Japan)

^b TOYOBO CO LTD   (Japan)

^c KYOTO UNIVERSITY   (Japan)

Author keywords

Segmented polyurethaneureas; Ultra small angle X ray scattering; Uniaxial stretching

Indexed keywords

MICROMETERS;

MULTIPLE INTERFERENCES; POLYURETHANE UREA; SCATTERING INTENSITY PROFILE; STRETCHING DIRECTION; STRETCHING RATIOS; ULTRA SMALL ANGLE X RAY SCATTERING; ULTRA-SMALL ANGLE X-RAY SCATTERINGS; UNIAXIAL STRETCHING;

X RAY SCATTERING;

ELASTOMER; POLYURETHANE; STRETCH; STRUCTURAL ANALYSIS; TEMPERATURE EFFECT; X-RAY ANALYSIS;

EID: 60649117781     PISSN: 00323861     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.polymer.2008.12.050     Document Type: Article

References (32)

1. Cooper S.L., and Tobolsky A.V. J Appl Polym Sci 10 (1996) 1837
2. Bonart R. J Macromol Sci Phys B2 (1968) 115
3. Bonart R., Morbitzer L., and Hentze G. J Macromol Sci Phys B3 (1969) 337
4. Bonart R., Morbitzer L., and Muller E.H. J Macromol Sci Phys B9 (1974) 447
5. Ishihara H., Kimura I., Saito K., and Ono H. J Macromol Sci Phys B10 (1974) 591
6. Kimura I., Ishihara H., Ono H., Yoshihara N., Nomura S., and Kawai H. Macromolecules 7 (1974) 355
7. Ishihara H., Kimura I., and Yoshihara N. J Macromol Sci Phys B22 (1983-84) 713
8. Kotani T., Hayashi H., Ishihara H., and Matsui T. J Macromol Sci Phys B31 (1992) 65
9. Jun H.-W., and West J.L. J Biomed Mater Res Part B Appl Biomater 72B (2005) 131
10. Jun H.-W., and West J.L. J Biomater Sci Polym Ed 15 (2004) 73
11. Guan J., and Wagner W.R. Biomacromolecules 6 (2005) 2833
12. Demir M.M., Yilgor I., Yilgor E., and Erman B. Polymer 43 (2002) 3303
13. Shibayama M., Suetsugu M., Sakurai S., Yamamoto T., and Nomura S. Macromolecules 24 (1991) 6254
14. Sakurai S., Nokuwa S., Morimoto M., Shibayama M., and Nomura S. Polymer 35 (1994) 532
15. Lee H.S., Yoo S.R., and Seo S.W. J Polym Sci Part B Polym Phys 37 (1999) 3233
16. Sakurai S., Okamoto Y., Sakaue H., Nakamura T., Banda L., and Nomura S. J Polym Sci Part B Polym Phys 38 (2000) 1716
17. Jimenez G., Asai S., Shishido A., and Sumita M. Eur Polym J 36 (2000) 2039
18. Klinedinsta D.B., Yilgörb E., Yilgörb I., Beyerc F.L., and Wilkes G.L. Polymer 46 (2005) 10191
19. Yeh F., Hsiao B.S., Sauer B.B., Michel S., and Siesler H.W. Macromolecules 36 (2003) 1940
20. Blundell D.J., Eeckhaut G., Fuller W., Mahendrasingam A., and Martin C. Polymer 43 (2002) 5197
21. Blundell D.J., Eeckhaut G., Fuller W., Mahendrasingam A., and Martin C. J Macromol Sci Phys B43 (2004) 125
22. Shibayama M., Kawauchi T., Kotani T., Nomura S., and Matsuda T. Polym J 18 (1986) 719
23. Shibayama M., Ohki Y., Kotani T., and Nomura S. Polym J 19 (1987) 1067
24. Yamamoto T., Shibayama M., and Nomura S. Polym J 21 (1989) 895
25. Yamamoto T., Shibayama M., and Nomura S. Polym J 23 (1991) 311
26. Yagi N., and Inoue K. J Appl Crystallogr 36 (2003) 783
27. Shinohara Y., Kishimoto H., Inoue K., Suzuki Y., Takeuchi A., Uesugi K., et al. J Appl Crystallogr 40 (2007) s397
28. Hashimoto F., Shibaya M., Ishihara H., Ohara T., Iwasaka H., and Ota Y. J Textile Eng 52 (2006) 131 (in Japanese)
29. Note that this is the result for the EDA100% sample and such a streak was not discernible in the 2D Vv-SALS patterns for the PDA100% sample. However, we consider that these unfavorable results may be due to experimental error and it should be possible to obtain similar results even for the PDA100% sample, because Yoshihara et al. successfully observed the OM image with cross-hutched stripes for the PDA100% sample (unpublished results).
30. Shibayama M., and Hashimto T. Macromolecules 19 (1986) 740
31. Sakurai S., Okamoto S., Kawamura T., and Hashimoto T. J Appl Crystallogr 24 (1991) 679
32. Toda A., Tomita C., Hikosaka M., Hibino Y., Miyaji H., Nonomura C., et al. Polymer 43 (2002) 947