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34548191707
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Unusual bonding to 'noble gases' has recently been reviewed: (a) Grochala W
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For older reviews see
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Unusual bonding to 'noble gases' has recently been reviewed: (a) Grochala W., Chem. Soc. Rev., 36, 1632 (2007). For older reviews see:
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Chem. Soc. Rev
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22
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0002326070
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Noble Gas and High Temperature Chemistry
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Springer Berlin
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Frenking, G.1
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24
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60649108349
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www.webelements.com , accessed Mar 27 (2008).
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www.webelements.com , accessed Mar 27 (2008).
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30
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0001792469
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Connections of He with singly or multiply charged cations are often called 'helides'. See for example: (a) Hotokka M., Kindstedt T., Pyykkö P. and Roos B.O., Mol. Phys., 52, 23 (1984);
-
Connections of He with singly or multiply charged cations are often called 'helides'. See for example: (a) Hotokka M., Kindstedt T., Pyykkö P. and Roos B.O., Mol. Phys., 52, 23 (1984);
-
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31
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0000614948
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33
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5444264490
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Reader is also referred to nice review on chemistry of helium: (d) Grandinetti F., Int. J. Mass Spectr., 237, 243 (2004).
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Reader is also referred to nice review on chemistry of helium: (d) Grandinetti F., Int. J. Mass Spectr., 237, 243 (2004).
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37
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0030984555
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+; the latter is known from the solid state: (a) Drews T. and Seppelt K., Angew. Chem. Int. Ed. Engl., 36, 273 (1997). Higher cationic oligomers have also been isolated:
-
+; the latter is known from the solid state: (a) Drews T. and Seppelt K., Angew. Chem. Int. Ed. Engl., 36, 273 (1997). Higher cationic oligomers have also been isolated:
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-
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38
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34548602904
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(a) Allen L.C., Erdahl R.M. and Whitten J.L., J. Am. Chem. Soc., 87, 3769 (1965). Compare:
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53
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33845627045
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See for example:, and references therein
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See for example: Niewa R., Zherebtsov D.A. and Hohn P., Z. Krist. New Cryst. Str., 218, 163 (2003), and references therein.
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35548961528
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59
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60649120679
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manuscript in preparation , The results were obtained in Apr
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Lundell J. and Grochala W., manuscript in preparation (2008). The results were obtained in Apr 2007.
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(2007)
-
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Lundell, J.1
Grochala, W.2
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60
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60649119505
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The results were obtained in Feb 2008.
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The results were obtained in Feb 2008.
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61
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0001172014
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We notice that at least three neutral systems containing He have been observed and/or proposed up to now: OBeHe, SBeHe and H3BOBeHe. However, in all these systems He serves as a hard Lewis base to-wards a rather naked metal cation, Be2, and the nature of this donor/acceptor bond in these species is very different from those which are discussed in this work (triplet state is not limiting their stability, Cf, a) Koch W, Collins J.R. and Frenking G, Chem. Phys. Lett, 132, 330 (1986);
-
2+, and the nature of this donor/acceptor bond in these species is very different from those which are discussed in this work (triplet state is not limiting their stability). Cf. (a) Koch W., Collins J.R. and Frenking G., Chem. Phys. Lett., 132, 330 (1986);
-
-
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64
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60649084335
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These results were first presented during ICM User Session, Mar 27
-
These results were first presented during ICM User Session, Mar 27 2008, Warsaw Poland.
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(2008)
Warsaw Poland
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-
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65
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60649090330
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See the Gaussian 03 tutorial.
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See the Gaussian 03 tutorial.
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-
-
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66
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0009158627
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-
Academic Press Inc, New York, N. Y
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Jørgensen C.K., "Inorganic Complexes," Academic Press Inc., New York, N. Y., 1963, p. 33.
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Inorganic Complexes
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Jørgensen, C.K.1
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68
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60649100574
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Recollect that HF is a classical case, where the inclusion of electronic correlation is indispensable for correct prediction of its dissociation energy. All molecules which contain the HeO moiety show a similar feature
-
Recollect that HF is a classical case, where the inclusion of electronic correlation is indispensable for correct prediction of its dissociation energy. All molecules which contain the HeO moiety show a similar feature.
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71
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0000601499
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See for example: a
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See for example: (a) Christe K.O., Wilson W. W., Wilson R.D., Bau R. and Feng J. A., J. Am. Chem. Soc., 112, 7619 (1990);
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J. Am. Chem. Soc
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Christe, K.O.1
Wilson, W.W.2
Wilson, R.D.3
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Feng, J.A.5
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72
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13944255376
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and related literature on new sources of 'naked' fluoride anions
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(b) Sun H.R. and DiMagno S.G., J. Am. Chem. Soc., 127, 2050 (2005), and related literature on new sources of 'naked' fluoride anions.
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Sun, H.R.1
DiMagno, S.G.2
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73
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0142037594
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and references therein. See
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See: Berski S., Lundell J., Latajka Z. and Leszczyński J., J. Phys. Chem. A, 102, 10768 (1998), and references therein.
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74
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60649097267
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4F]-like species is thought to be slowed down. Deuteration is another common trick which is worth considering.
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4F]-like species is thought to be slowed down. Deuteration is another common trick which is worth considering.
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75
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0035913344
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Shimizu K., Kimura T, Furomoto S., Takeda K., Kontani K., Onuki Y. and Amaya K., Nature, 412, 316(2001).
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Nature
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77
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60649103519
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+ 2.04 eV) and it follows Lewis basicity of noble gases which is reflected in their valence orbital energies.
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+ 2.04 eV) and it follows Lewis basicity of noble gases which is reflected in their valence orbital energies.
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81
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35348949003
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It has been claimed that all Ng2 molecules (Ng, He⋯Xe) except He2 and Ne2 exhibit chemical bonding if embedded inside the C60 fullerene: Krapp A. and Frenking G, Chem. Eur. J, 13, 8256 2007
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60 fullerene: Krapp A. and Frenking G., Chem. Eur. J., 13, 8256 (2007).
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34547895154
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Walker N.R., Wright R.R., Barran P.E., Cox H. and Stace A.J., J. Chem. Phys., 114, 5562 (2001).
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