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Volumn 83, Issue 1, 2009, Pages 87-122

On chemical bonding between helium and oxygen

Author keywords

Density functional theory; Helium; Noble gases; Post Hartree Fock methods

Indexed keywords


EID: 60649113487     PISSN: 01375083     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article
Times cited : (34)

References (85)
  • 21
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    • Unusual bonding to 'noble gases' has recently been reviewed: (a) Grochala W
    • For older reviews see
    • Unusual bonding to 'noble gases' has recently been reviewed: (a) Grochala W., Chem. Soc. Rev., 36, 1632 (2007). For older reviews see:
    • (2007) Chem. Soc. Rev , vol.36 , pp. 1632
  • 22
    • 0002326070 scopus 로고
    • Noble Gas and High Temperature Chemistry
    • Springer Berlin
    • (b) Frenking G. and Cremer D., Noble Gas and High Temperature Chemistry ('Structure and Bonding' series), Springer Berlin (1990) p. 17;
    • (1990) Structure and Bonding' series , pp. 17
    • Frenking, G.1    Cremer, D.2
  • 24
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    • www.webelements.com , accessed Mar 27 (2008).
    • www.webelements.com , accessed Mar 27 (2008).
  • 30
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    • Connections of He with singly or multiply charged cations are often called 'helides'. See for example: (a) Hotokka M., Kindstedt T., Pyykkö P. and Roos B.O., Mol. Phys., 52, 23 (1984);
    • Connections of He with singly or multiply charged cations are often called 'helides'. See for example: (a) Hotokka M., Kindstedt T., Pyykkö P. and Roos B.O., Mol. Phys., 52, 23 (1984);
  • 33
    • 5444264490 scopus 로고    scopus 로고
    • Reader is also referred to nice review on chemistry of helium: (d) Grandinetti F., Int. J. Mass Spectr., 237, 243 (2004).
    • Reader is also referred to nice review on chemistry of helium: (d) Grandinetti F., Int. J. Mass Spectr., 237, 243 (2004).
  • 37
    • 0030984555 scopus 로고    scopus 로고
    • +; the latter is known from the solid state: (a) Drews T. and Seppelt K., Angew. Chem. Int. Ed. Engl., 36, 273 (1997). Higher cationic oligomers have also been isolated:
    • +; the latter is known from the solid state: (a) Drews T. and Seppelt K., Angew. Chem. Int. Ed. Engl., 36, 273 (1997). Higher cationic oligomers have also been isolated:
  • 59
    • 60649120679 scopus 로고    scopus 로고
    • manuscript in preparation , The results were obtained in Apr
    • Lundell J. and Grochala W., manuscript in preparation (2008). The results were obtained in Apr 2007.
    • (2007)
    • Lundell, J.1    Grochala, W.2
  • 60
    • 60649119505 scopus 로고    scopus 로고
    • The results were obtained in Feb 2008.
    • The results were obtained in Feb 2008.
  • 61
    • 0001172014 scopus 로고    scopus 로고
    • We notice that at least three neutral systems containing He have been observed and/or proposed up to now: OBeHe, SBeHe and H3BOBeHe. However, in all these systems He serves as a hard Lewis base to-wards a rather naked metal cation, Be2, and the nature of this donor/acceptor bond in these species is very different from those which are discussed in this work (triplet state is not limiting their stability, Cf, a) Koch W, Collins J.R. and Frenking G, Chem. Phys. Lett, 132, 330 (1986);
    • 2+, and the nature of this donor/acceptor bond in these species is very different from those which are discussed in this work (triplet state is not limiting their stability). Cf. (a) Koch W., Collins J.R. and Frenking G., Chem. Phys. Lett., 132, 330 (1986);
  • 64
    • 60649084335 scopus 로고    scopus 로고
    • These results were first presented during ICM User Session, Mar 27
    • These results were first presented during ICM User Session, Mar 27 2008, Warsaw Poland.
    • (2008) Warsaw Poland
  • 65
    • 60649090330 scopus 로고    scopus 로고
    • See the Gaussian 03 tutorial.
    • See the Gaussian 03 tutorial.
  • 66
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    • Academic Press Inc, New York, N. Y
    • Jørgensen C.K., "Inorganic Complexes," Academic Press Inc., New York, N. Y., 1963, p. 33.
    • (1963) Inorganic Complexes , pp. 33
    • Jørgensen, C.K.1
  • 68
    • 60649100574 scopus 로고    scopus 로고
    • Recollect that HF is a classical case, where the inclusion of electronic correlation is indispensable for correct prediction of its dissociation energy. All molecules which contain the HeO moiety show a similar feature
    • Recollect that HF is a classical case, where the inclusion of electronic correlation is indispensable for correct prediction of its dissociation energy. All molecules which contain the HeO moiety show a similar feature.
  • 72
    • 13944255376 scopus 로고    scopus 로고
    • and related literature on new sources of 'naked' fluoride anions
    • (b) Sun H.R. and DiMagno S.G., J. Am. Chem. Soc., 127, 2050 (2005), and related literature on new sources of 'naked' fluoride anions.
    • (2005) J. Am. Chem. Soc , vol.127 , pp. 2050
    • Sun, H.R.1    DiMagno, S.G.2
  • 74
    • 60649097267 scopus 로고    scopus 로고
    • 4F]-like species is thought to be slowed down. Deuteration is another common trick which is worth considering.
    • 4F]-like species is thought to be slowed down. Deuteration is another common trick which is worth considering.
  • 77
    • 60649103519 scopus 로고    scopus 로고
    • + 2.04 eV) and it follows Lewis basicity of noble gases which is reflected in their valence orbital energies.
    • + 2.04 eV) and it follows Lewis basicity of noble gases which is reflected in their valence orbital energies.
  • 81
    • 35348949003 scopus 로고    scopus 로고
    • It has been claimed that all Ng2 molecules (Ng, He⋯Xe) except He2 and Ne2 exhibit chemical bonding if embedded inside the C60 fullerene: Krapp A. and Frenking G, Chem. Eur. J, 13, 8256 2007
    • 60 fullerene: Krapp A. and Frenking G., Chem. Eur. J., 13, 8256 (2007).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.