The phase behaviour of lyotropic liquid crystals in linear alkylbenzene sulphonate (LAS) systems

Colloids and Surfaces A: Physicochemical and Engineering Aspects

Volumn 338, Issue 1-3, 2009, Pages 155-161

  Stewart, J A ^a   Saiani, A ^a   Bayly, A ^b   Tiddy, G J T ^c  

^a UNIVERSITY OF MANCHESTER   (United Kingdom)

^b PROCTER AND GAMBLE COMPANY   (United States)

^c UNIVERSITY OF MANCHESTER   (United Kingdom)

Author keywords

Lateral phase separation; Linear alkylbenzene sulphonate (LAS); Lyotropic liquid crystal

Indexed keywords

BINARY MIXTURES; CHEMICAL ANALYSIS; DIFFERENTIAL SCANNING CALORIMETRY; ISOMERS; LAMELLAR STRUCTURES; LIGHT SOURCES; LIQUID CRYSTALS; LITHIUM ALLOYS; MAGNETIC RESONANCE; MIXTURES; NEMATIC LIQUID CRYSTALS; NUCLEAR MAGNETIC RESONANCE; OPTICAL MICROSCOPY; PHASE DIAGRAMS; PHASE MODULATION; SURFACE ACTIVE AGENTS;

ATTRACTIVE FORCES; BI LAYERS; CO-EXISTING; ION INTERACTIONS; LAMELLAR PHASE; LAMELLAR PHASIS; LATERAL PHASE SEPARATION; LINEAR ALKYLBENZENE SULPHONATE (LAS); LOW TEMPERATURES; LYOTROPIC LIQUID CRYSTAL; MICELLAR PHASE; PHASE BEHAVIOURS; PHASE RULES; SCANNING CALORIMETRIES; SINGLE ISOMERS; STUDY SAMPLES; SURFACTANT SYSTEMS; SWELLING BEHAVIOURS; TEMPERATURE RANGES; X -RAY SCATTERINGS;

PHASE SEPARATION;

ALKYLBENZENESULFONIC ACID;

ARTICLE; CHEMICAL COMPOSITION; CHEMICAL INTERACTION; CHEMICAL STRUCTURE; DEUTERON NUCLEAR MAGNETIC RESONANCE; DIFFERENTIAL SCANNING CALORIMETRY; LIQUID CRYSTAL; PRIORITY JOURNAL; RADIATION SCATTERING; SYNTHESIS; TEMPERATURE MEASUREMENT;

EID: 60349125005     PISSN: 09277757     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.colsurfa.2008.06.021     Document Type: Article

References (27)

1. Laughlin R.G. The Aqueous Phase Behaviour of Surfactants. 1st ed. (1994), Academic Press, London
2. Kirk-Othmer. Encyclopaedia of Chemical Technology. 4th ed. vol. 23 (2001), Wiley, New York
3. Masters K. The Spray Drying Handbook. 4th ed. (1985), Longman, London
4. Sein A., Engberts J.B.F.N., Van der Linden E., and Van de Pas J.C. Lyotropic phases of dodecylbenzenesulfonates with different counterions in water. Langmuir 12 12 (1996) 2913-2923
5. Sein A., and Engberts J.B.F.N. Formation of a lamellar phase: rearrangement of amphiphiles from the bulk isotropic phase into a lamellar fashion. Langmuir 12 12 (1996) 2924-2931
6. Richards C., Tiddy G.J.T., and Casey S. Lateral phase separation gives multiple lamellar phases in a "binary" surfactant/water system: the phase behaviour of sodium alkyl benzene sulfonate/water mixtures. Langmuir 23 2 (2006) 467-474
7. Ockelford J., Timimi B.A., Narayan K.S., and Tiddy G.J.T. An upper critical-point in a lamellar liquid-crystalline phase. J. Phys. Chem. 97 26 (1993) 6767-6769
8. Sein A., and Engberts J.B.F.N. Micelle to lamellar aggregate transition of an anionic surfactant in dilute aqueous-solution induced by alkali-metal chloride and tetraalkylammonium chloride salts. Langmuir 11 2 (1995) 455-465
9. Sein A., Engberts J.B.F.N., Van der Linden E., and Van de Pas J.C. Salt-induced transition from a micellar to a lamellar liquid-crystalline phase in dilute mixtures of anionic and nonionic surfactants in aqueous-solution. Langmuir 9 7 (1993) 1714-1720
10. Blackmore E.S., and Tiddy G.J.T. Phase behaviour and lyotropic liquid crystals in cationic surfactant-water systems. J. Chem. Soc., Faraday Trans. 2 84 (1988) 1115-1127
11. Towns-Andrews E., Berry A., Bordas J., Grant G.R., Murray P.K., Roberts K., Sumner I., Worgan J.S., and Lewis R. Time-resolved X-ray diffraction station: X-ray optics, detectors, and data acquisition. Rev. Sci. Instrum. 60 7 (1989) 2346-2349
12. A.J. Gleeson, Calibration, Science and Technology Facilities Council 2004 [cited 08/01/2008]; available from: http://srs.dl.ac.uk/NCD/station161/useful.htm#Calibration.
13. M. MacDonald, Primary Beam Position and Aligning Crystals, Science and Technology Facilities Council 2001 [cited 08/01/2008]; available from: http://www.srs.ac.uk/px/manual14.1/verify.html.
14. Roe R.J. Methods of X-ray and Neutron Scattering in Polymer Science (2000), Oxford University Press, Oxford
15. Ma J.-G., Boyd B.J., and Drummond C.J. Positional isomers of linear sodium dodecyl benzene sulphonate: solubility, self-assembly, and air/water interfacial activity. Langmuir 22 (2006) 8646-8654
16. Waters J., and Garrigan J.T. An improved microdesulphonation/gas liquid chromatography procedure for the determination of linear alkylbenzene sulphonates in UK rivers. Water Res. 17 11 (1983) 1549-1562
17. Ramaraju S.M., Carroll B.J., Chambers J.G., and Tiddy G.J.T. The liquid crystalline phases formed by linear-dodecylbenzene sulphonic acid during neutralisation with sodium carbonate. Colloids Surf. A 288 (2006) 77-85
18. Israelachvili J.N., Mitchell D.J., and Ninham B.W. Theory of self-assembly of hydrocarbon amphiphiles into micelles and bilayers. J. Chem. Soc., Faraday Trans. 2 72 (1976) 1525-1568
19. Halle B., and Wennerstrom H. Interpretation of magnetic resonance data from water nuclei in heterogeneous systems. J. Chem. Phys. 75 4 (1981) 1928-1943
20. Mirau P.A. NMR characterisation of polymers. In: Hunt B.J., and James M.I. (Eds). Polymer Characterisation (1993), Blackie Academic and Professional, London
21. Harrison W.J., Mateer D.L., and Tiddy G.J.T. J-Aggregates and liquid crystal structure of cyanine dyes. Faraday Discuss. 104 (1996) 139-154
22. Khan A., Fontell K., Linblom G., and Lindman B. Liquid crystallinity in a calcium surfactant system. Phase equilibria and phase structures in the system calcium octyl sulfate/decan-1-ol/water. J. Phys. Chem. 86 (1982) 4266-4271
23. Dave P.C., Nusair N.A., Inbaraj J.J., and Lorigan G.A. Electron paramagnetic resonance studies of magnetically aligned phospholipid bilayers utilizing a phospholipid spin label: the effect of cholesterol. BBA - Biomembranes 1714 2 (2005) 141-151
24. Geppi M., Pizzanelli S., and Veracini C.A. Phenyl ring dynamics in a liquid crystal polymer through 2H NMR spectroscopy. Chem. Phys. Lett. 343 5-6 (2001) 513-519
25. Khan A., Jonsson B., and Wennerstrom H. Phase-equilibria in the mixed sodium and calcium di-2-ethylhexylsulfosuccinate aqueous system-an illustration of repulsive and attractive double-layer forces. J. Phys. Chem. 89 24 (1985) 5180-5184
26. Guldbrand L., Jonsson B., Wennerstrom H., and Linse P. Electrical double layer forces. A Monte Carlo study. J. Chem. Phys. 80 5 (1984) 2221
27. A.E. Bayly, J.A. Stewart, A. Saiani, G.J.T. Tiddy, unpublished data.