Synthesis of chiral C2-symmetric palladium and rhodium SCS pincers

Bulletin of the Korean Chemical Society

Volumn 30, Issue 1, 2009, Pages 23-24

  Choi, Dae Hyuk ^a   Chon, Ji Yon ^a   Kang, Jahyo ^a  

^a Sogang University   (South Korea)

Author keywords

Asymmetric addition of alkyne to aldehyde; C2 Symmetry; Chiral bis(tetrahydrothiapyran); Pincers

Indexed keywords

EID: 60149110161     PISSN: 02532964     EISSN: 12295949     Source Type: Journal    
DOI: 10.5012/bkcs.2009.30.1.023     Document Type: Article

References (15)

1. Rybtchinski, B.; Milstein, D. Angew. Chem. Int. Ed. Engl. 1999, 38, 871.
2. Albrecht, M.; van Koten, G. Angew. Chem., Int. Ed. 2001, 40, 3750-3781.
3. van der Boom, M. E.; Milstein, D. Chem. Rev. 2003, 103, 1759-1792.
4. Takenaka, K.; Uozumi, Y Org. Lett. 2004, 6, 1833-1835.
5. Charette, A. B.; Beauchemin, A.; Marcoux, J.-F. J. Am. Chem. Soc. 1998, 120, 5114-5115.
6. 2Cl) to the dialdehyde 4.
7. Pu, L. Tetrahedron 2003, 59, 9873-9886.
8. Cozzi, P. G.; Hilgraf, R.; Zimmermann, N. Eur. J. Org. Chem. 2004, 4095-4105.
9. Farah, D.; Swami, K.; Kuivila, H. G. J. Organomet. Chem. 1992, 429, 311-334.
10. +), 333, 277, 101, 87, 57.
11. 2Sn: C, 55.54; H, 7.70; S, 12.89. Found: C, 55.42; H, 7.73; S, 12.25.
12. 2: C, 46.20; H, 5.62; S, 12.34 Found: C, 46.24; H, 5.59; S, 12.31
13. Fossey, J. S.; Richards, C. J. J. Organomet. Chem. 2004, 689, 3056-3059.
14. 2: C, 47.34; H, 5.76; S, 12.64 Found: C, 47.28; H, 5.72; S, 12.60.
15. Denmark, S. E.; Fu, J. Chem. Rev. 2003, 103, 2763-2794.